Materials Flashcards
Biocompatibility
applicable materials must not lead to any adverse secondary effects; material must be stable; material must not be harmful
Types of biomaterials
Metals, ceramics, polymers
Metals
Stainless steel, titanium, cobalt chromium
Stainless steels
316, 316LS; min 10.5% Cr; high stiffness, strength, very good corrosion resistance
Titanium alloy
Grades 5 and 23; lightweight, stiff, strong, good corrosion resistance; 6% Al, 4% V; high compatibility with the human body
Cobalt Chromium (CoCrMo)
Vitalium (65% Co, 30% Cr, 5% Mo)
Advantages of metals
High impact tensile strength, resistance to wear, strain energy absorption
Disadvantages of metals
Low biocompatibility, corrosion in physical environments, mismatch of mechanical properties with bio-tissues, high density (heavy)
Metal applications
Screws, pins, wires, rods, implants
Ceramics
Aluminum oxides, calcium oxides, titanium oxides
Advantages of ceramics
good bio-compatibility; good corrosion resistance
Disadvantages of ceramics
Low impact tensile strength, difficult to fabricate, low mechanical reliability, lack of resistance, high density
Applications of ceramics
Hip prostheses, teeth implants for phalanges
Polymers
Nylon, PMMA, Teflon, PP, PE, UHMWPE, Silastic rubber, PEEK, Copoly
Nylon
Absorbs water (0.1-13.5%) and irritates tissue; loses tensile strength
PMMA
In cement form: high generation of heat during polymerization; in rigid form: susceptible to crazing, abrasion, loss of strength by heating
Teflon
Very high resilience
PP
up to 5400 psi UTS, 0.01-1% water absorption
PE
very low water absorption (0.05-0.5%); UHMWPE up to 7740 psi UTS compared to 4100 psi
Advantages of polymers
very good resilience; easy to fabricate, low density
Disadvantages of polymers
Low impact tensile strength, time degradation polymers are viscoelastic
Applications of polymers
Artificial arteries, veins, small joints, wear surfaces
Typical properties
Young’s modulus: 10MPa to 4GPa for polymers, 50MPa to 400GPa for metals; UTS: 10MPa to 100MPa for polymers, 100MPa to 10GPa for metals; elongation: 1000% for polymers, <100% for metals
Plastic polymer modeling
Plastic polymers are highly nonlinear; use the secant modulus, plastic yield stress, Poisson ratio (0.4-0.45); can use nonlinear Mooney-Rivlin model; can use curve fitting process
Secant modulus (Es)
obtained at a predetermined value of strain by finding the slope of a line (typically 0.2% strain is used); often described in a percentage of E