Material_Science_Flashcards copy
atomic Levels of Structure
Atomic, Crystalline, Nanostructure, Microstructure, Macrostructure
Bonding Principles
Valence electrons participate in bonding; forces exist when atoms are close together
Bonding Energies
Minimum energy required for separation; larger bonding energies result in higher melting points
Ionic Bonding
Elements give up valence electrons (e.g., NaCl - Na donates electron to Cl)
Covalent Bonding
Sharing valence electrons (e.g., Hâ‚‚O - Oxygen shares electrons with two hydrogen atoms)
Bond Hybridization
Combining orbitals causing overlap (e.g., in carbon)
Metallic Bonds
Electrons drift throughout structure acting as ‘glue’; results in good conductivity
Van der Waals Bonds
Exist in all molecules, particularly non-polar molecules; very weak
Hydrogen Bonding
Special bonds with hydrogen
Point Defects
4
Vacancy (atom missing), Self-Interstitial (atom overlaps another), Impurity (different atom), Cation Interstitial (cation overlaps another cation)
Linear Defects
Edge Dislocation (shifting of plane causing gaps), Screw dislocation, Burger Vector (denotes change in molecule)
Planar Defects
3
Twin (straight parallel axis), Stacking Fault (stacking sequence of close-packed planes), Grain Boundary (separates two small grains)
Defect Structures in Ceramics
Electron Neutrality (equal positive and negative charges), Frenkel Defect (cation in wrong spot), Schottky Defect (missing cation-anion pair)
Diffusion Types
Interdiffusion (between different atoms), Self-diffusion (same type of atom)
Diffusion Mechanisms
Vacancy diffusion (atoms move into vacant sites), Interstitial diffusion (atoms squeeze between other atoms)
Ficks First Law
J = -D(dC/dx) for constant diffusion
Ficks Second Law
Concentration gradient changes with time
Temperature Effect on Diffusion
D = De^(-Q/RT); higher temperature means faster diffusion
Crystal Structures - FCC
4 total atoms per unit cell, APF = 0.74, Coordination number = 12
Crystal Structures - BCC
2 total atoms per unit cell, APF = 0.68, Coordination number = 8
Crystal Structures - HCP
APF = 0.74, Coordination number = 12
Crystallographic Directions
Specified as [uvw] (e.g., [100], [110])
Crystallographic Planes
Specified as (hkl) (e.g., (100), (110))
Braggs Law
nλ = 2d*sinθ¸ (X-ray diffraction)