Material_Science_Flashcards copy

1
Q

atomic Levels of Structure

A

Atomic, Crystalline, Nanostructure, Microstructure, Macrostructure

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2
Q

Bonding Principles

A

Valence electrons participate in bonding; forces exist when atoms are close together

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3
Q

Bonding Energies

A

Minimum energy required for separation; larger bonding energies result in higher melting points

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4
Q

Ionic Bonding

A

Elements give up valence electrons (e.g., NaCl - Na donates electron to Cl)

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5
Q

Covalent Bonding

A

Sharing valence electrons (e.g., Hâ‚‚O - Oxygen shares electrons with two hydrogen atoms)

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6
Q

Bond Hybridization

A

Combining orbitals causing overlap (e.g., in carbon)

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7
Q

Metallic Bonds

A

Electrons drift throughout structure acting as ‘glue’; results in good conductivity

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8
Q

Van der Waals Bonds

A

Exist in all molecules, particularly non-polar molecules; very weak

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9
Q

Hydrogen Bonding

A

Special bonds with hydrogen

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10
Q

Point Defects

4

A

Vacancy (atom missing), Self-Interstitial (atom overlaps another), Impurity (different atom), Cation Interstitial (cation overlaps another cation)

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11
Q

Linear Defects

A

Edge Dislocation (shifting of plane causing gaps), Screw dislocation, Burger Vector (denotes change in molecule)

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12
Q

Planar Defects

3

A

Twin (straight parallel axis), Stacking Fault (stacking sequence of close-packed planes), Grain Boundary (separates two small grains)

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13
Q

Defect Structures in Ceramics

A

Electron Neutrality (equal positive and negative charges), Frenkel Defect (cation in wrong spot), Schottky Defect (missing cation-anion pair)

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14
Q

Diffusion Types

A

Interdiffusion (between different atoms), Self-diffusion (same type of atom)

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15
Q

Diffusion Mechanisms

A

Vacancy diffusion (atoms move into vacant sites), Interstitial diffusion (atoms squeeze between other atoms)

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16
Q

Ficks First Law

A

J = -D(dC/dx) for constant diffusion

17
Q

Ficks Second Law

A

Concentration gradient changes with time

18
Q

Temperature Effect on Diffusion

A

D = De^(-Q/RT); higher temperature means faster diffusion

19
Q

Crystal Structures - FCC

A

4 total atoms per unit cell, APF = 0.74, Coordination number = 12

20
Q

Crystal Structures - BCC

A

2 total atoms per unit cell, APF = 0.68, Coordination number = 8

21
Q

Crystal Structures - HCP

A

APF = 0.74, Coordination number = 12

22
Q

Crystallographic Directions

A

Specified as [uvw] (e.g., [100], [110])

23
Q

Crystallographic Planes

A

Specified as (hkl) (e.g., (100), (110))

24
Q

Braggs Law

A

nλ = 2d*sinθ¸ (X-ray diffraction)

25
Metals
Dense, stiff, strong, ductile, good conductors (e.g., Iron, aluminum, copper, nickel)
26
Ceramics
Stiff, hard, brittle, insulating (e.g., Aluminum oxide, silicon dioxide, carbides)
27
Polymers
Low density, ductile, insulating, poor temperature resistance
28
what are the Polymer Structures | 4
Linear, Branched, Crosslinked, Network
29
Polymer Configurations on a chain
Isotactic (zigzag), Syndiotactic (alternating), Atactic (random)
30
Polymer Geometric Isomers
Cis (rubbery), Trans (rigid)
31
how are Copolymers assorted
Random, Alternating, Block
32
Composites
Combination of two or more materials for specific properties
33
Thermal Properties
Heat Capacity (absorbs heat), Thermal Expansion (ΔL = αLΔT), Thermal Conductivity (q = -k(dT/dx))
34
Material Analysis Techniques
Microscopy, Electron Microscopy
35
Sample Preparation Process
Sectioning, Grinding/Polishing, Etching