Mass Transfer Flashcards

1
Q

Mass transfer rate between two fluid phases does not necessarily depend on the __________ of the two phases.

A

chemical properties

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2
Q

In a solution containing 0.30 Kg mole of solute and 600 kg of solvent, the molality is

A

0.5

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3
Q

Fenske equation determines the

A

minimum number of theoretical plates.

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4
Q

The term “cooling range” in a cooling tower refers to the difference in the temperature of

A

hot water entering the tower and the cooled water leaving the tower.

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5
Q

Which of the following is the most suitable for extraction in a system having very low density difference?

A

Centrifugal extractor

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6
Q

Total reflux in a distillation operation requires minimum

A

number of plates

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7
Q

The amount of steam required per unit quantity of distillate in case of steam distillation will be reduced by

A

raising the temperature, lowering the total pressure.

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8
Q

The difference of wet bulb temperature and adiabatic saturation temperature of unsaturated mixture of any system is

A

(+)ve

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9
Q

Fenske’s equation for determining the minimum number of theoretical stages in distillation column holds good, when the

A

relative volatility is reasonably constant.

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10
Q

When the temperature and humidity of air is low, we usually use __________ draft cooling tower.

A

natural

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11
Q

Pick out the correct statement.
a. In case of liquid-liquid extraction, no separation is possible, if the
selectivity of the solvent used is unity.
b. With increase in temperature, the selectivity of the solvent used in
solvent extraction decreases.
c. The selectivity of solvent used in solvent extraction is unity at the
plait point.
d. all (a), (b) and (c).

A

all

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12
Q

__________ columns are used for liquid dispersion in a continuous gas phase.

A

Packed

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13
Q

Overall efficiency of the distillation column is

A

the ratio of number of ideal plates to actual plates.

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14
Q

On addition of solute in the solvent, the __________ of the solution decreases.

A

freezing point, vapour pressure

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15
Q

Which is the controlling factor for a drum drier?

A

Heat transfer

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16
Q

Drying operation under vacuum is carried out to

A

reduce drying temperature.

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17
Q

Air initially at 101. 3 kPa and 40°C and with a relative humidity of 50%, is cooled at constant pressure to 30°C. The cooled air has a

A

higher relative humidity

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18
Q

Separation of two or more components of a liquid solution can not be achieved by

A

absorption

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19
Q

Stefan’s law describes the mass transfer by

A

both ‘a’ & ‘b’

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20
Q

At minimum reflux ratio for a given separation

A

number of plates is infinity.

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21
Q

Relative humidity is the ratio of the

A

partial pressure of the vapour to the vapour pressure of the liquid at gas temperature.

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22
Q

In batch distillation with constant reflux, overhead product composition __________ with time.

A

decreases

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23
Q

Psychrometry deals with the properties of gas-vapor mixture. Humidity can be determined by the measurement of the __________ of a fibre.

A

electrical resistance

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24
Q

Heat in BTU necessary to increase the temperature of 1 lb of gas and its accompanying vapour by 1°F is called the

A

specific heat

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25
To increase the absorption factor, (where, G = gas flow rate, S = solvent flow rate)
increase 'S' and decrease 'G'.
26
The mass diffusivity, the thermal diffusivity and the eddy momentum diffusivity are same for, NPr = NSc = __________
1
27
Dew point of a gas-vapour mixture
decreases with decrease in pressure.
28
In a packed absorption tower, if the equilibrium and operating lines are both straight lines, then the ratio, HETP/HTUOG __________ the absorption factor.
increases with increase in, is one at unity value of
29
Which of the following plays an important role in problems of simultaneous heat and mass transfer?
Lewis number
30
In case of an absorber, the operating
line always lies above the equilibrium curve.
31
As the reflux ratio in a distillation coloumn is increased from the minimum, the
total cost first decreases and then increases.
32
Absorption factor is defined as (where, S1 = slope of the operating line S2 = slope of the equilibrium curve)
S1/S2
33
A plait point is the point on the solubility curve, where the tie line reduces to a point. What is the number of plait point for a ternery system containing twopairs of partially miscible liquids?
0
34
Which of the following remains constant during sensible cooling process?
Specific humidity, Partial pressure of vapour
35
Physical absorption is
a reversible phenomenon, accompanied by evolution of heat
36
Make up water is required in a cooling tower to replace the water lost by
all
37
Which of the following quantities need not be fixed before starting the design of a co-current absorber?
Flow rate of entering liquid
38
Mass transfer co-efficient of liquid is
affected more by temperature than that for gases.
39
Absorption accompanied with chemical reaction is exemplified by the absorption of
SO2 in alkaline solution.
40
Which of the following unit operations makes use of Thiele-Geddes equation?
Multicomponent distillation.
41
Which of the following liquid-vapor contacting devices provides maximum contact surface area for a particular duty?
Wetted wall column
42
The equipment frequently used for adiabatic humidification-cooling operation with recirculating liquid is
spray chamber
43
Chemisorption (chemical adsorption) is
an irreversible phenomenon.
44
The rate of solid-liquid extraction is limited by the
all
45
Raoult's law applies to the
solvents.
46
In distillation columns, the number of bubble caps per tray primarily depends upon the
allowable gas and liquid velocities.
47
In distillation, overhead product contains
any number of components
48
With increase in pressure, the relative volatility for a binary system
decreases.
49
Low viscosity absorbent is preferred for reasons of
all
50
Mass transfer co-efficient (K) and diffusivity (D) are related according to film theory as
K ∝ D
51
The McCabe Δ L law states that the
linear crystal growth rate does not depend on the crystal size.
52
Bollman extractor
is used for extraction of oil from oilseed.
53
The relation, Sc = Pr = 1, is valid, when the mechanism of __________ ansfer is same.
heat and mass
54
A coalescer in a mixer-settler liquid-liquid extraction coloumn
all
55
For the same feed, feed quality and separation (in a distillation column), with the increase of total pressure, the number of ideal plates will
increase
56
Pick out the correct statement. a. Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of non-ideal binary system by distillation. b. A sharp decrease in pressure drop is an indication of flooding in a distillation coloumn. c. Solvent used in extractive distillation should be of high volatility. d. Flash distillation is suitable for separating components which have very close boiling temperature.
Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of non-ideal binary system by distillation.
57
When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of
vapour pressure of component A to that of component B.
58
The operation involved when the soluble material is largely on the surface of an insoluble solid and is merely washed off by the solvent is called
elutriation or elution
59
In the constant rate period of the rate of drying curve for batch drying,
surface evaporation of unbound moisture occurs.
60
It takes 6 hours to dry a wet solid from 50% moisture content to the critical moisture content of 15%. How much longer it will take to dry the solid to 10% moisture content, under the same drying conditions? (The equilibrium moisture content of the solid is 5%).
71 min
61
Agitator is provided in a crystalliser for
all
62
__________ diffusion is used for separating the isotopes of methane.
Thermal
63
Ordinary diffusion process is also called __________ diffusion.
concentration
64
Pick out the wrong statement. a. Different solids have different equilibrium moisture curves. b. Total condenser or reboiler is considered equivalent to one theoretical plate in McCabe-Thiele method of theoretical plate calculation for distillation column. c. Heat removal load on cooler remains constant, even with increase of the reflux ratio in a distillation column. d. Even a forced draft cooling tower can not cool water below the wet bulb temperature.
Heat removal load on cooler remains constant, even with increase of the reflux ratio in a distillation column.
65
Pick out the wrong statement pertaining to the rotary dryer.
Rotary dryer is suitable for drying sticky material.
66
The reason for preferring packed towers over plate towers in distillation practice is that the packed tower operation gives
low pressure drop and low hold up.
67
If the path of liquid across the plate is very long as in case of large diameter tower, Murphree efficiency can be __________ percent.
> 100
68
Compound A is extracted from a solution of A + B into a pure solvent S. A Co-current unit is used for the liquid-liquid extraction. The inlet rate of the solution containing A is 200 moles of B/hr.m2 and the solvent flow, rate is 400 moles of S/m2. hr. The equilibrium data is represented by Y = 3X2 , where Y is in moles of a A/moles of B and X is in moles A/moles of S. The maximum percentage extraction achieved in the unit is
0.5
69
Raoult's law is applicable to the
ideal solutions
70
Weeping in a distillation column
results due to very low gas velocity.
71
In case of binary distillation, increasing the reflux ratio above optimum does not result in the increase of
area between operating line and 45° diagonal x-y diagram.
72
Wetted wall tower experiment determines the
mass transfer co-efficient.
73
In McCabe-Thiele method, at infinite reflux ratio
the overhead product is minimum.
74
With decrease in the throughput (compared with the design capacity) for a bubble cap distillation column, its efficiency
increases
75
Plate towers are preferred to packed towers, when large temperature changes are involved, because of the reason that the
packing may be crushed due to thermal expansion/contraction of the components of the equipments.
76
The equilibrium liquid composition compared to the vapor composition in case of azeotropic mixture is
same
77
Out of the following gas-liquid contacting devices, for a given set of operating conditions, gas pressure drop is the least in __________ tower.
wetted wall
78
Pick out the system with minimum boiling azeotrope at 1 atm.
ethyl alcohol-water
79
Free flowing granular materials can be best dried in a __________ drier.
rotary
80
In case of an ideal solution, the total vapor pressure varies __________ with the composition expressed as mole fraction,
linearly
81
Corresponding to Nusselt number in heat transfer, the dimensionless group in mass transfer is the __________ number.
Sherwood
82
If the specific heats of a gas and a vapor are 0.2KJ/Kg.°K and 1.5 KJ/Kg.°K respectively, and the humidity is 0.01; the humid heat in KJ/°Kg. is
0.215
83
Liquid diffusivity is of the order of __________ cm2 /second.
10-5 to 10-6
84
The solvent used in liquid extraction should not have high latent heat of vaporisation, because
its recovery cost by distillation may be prohibitatively high.
85
At the same gas flow rate, the pressure drop in a packed tower being irrigated with liquid __________ that in dry packed tower.
is greater than
86
Molarity is defined as the number of gm moles of solute per __________ of solvent.
liter
87
The value of Lewis number (Le = Sc/Pr) for air-water vapour system is around
1
88
An aqueous solution of methanol is to be distilled in a tray column. High pressure steam is available as a source of heat. For a given reflux ratio and overhead composition, two options are being explored; (i) a reboiler is used and (ii) no reboiler is used but steam is fed directly to the bottom of the column. As compared to option (i), in option (ii)
less number of trays are required.
89
The partial pressure distribution of an ideal gas diffusing through another stagnant ideal gas at steady state follows a/an __________ law.
exponential
90
Which of the following binary systems is an example of a maximum boiling azeotrope?
Water-hydrochloric acid.
91
(NRe . NSc) is termed in mass transfer operation as the __________ number.
Peclet
92
The binary diffusivity in gases and liquids vary respectively as
T^3/2 and T
93
Pick out the correct statement. a. The slope of the stripping line is always less than unity. b. For a given separation in a binary distillation column, with increase in reflux ratio (above the minimum reflux ratio), the fixed cost of the distillation column first increases and then decreases. c. In Ponchon-Savarit method of no. of theoretical plate determination, the stripping and rectifying operating lines are vertical at total reflux. d. Kremsor-Brown-Souder's equation is used to calculate the efficiency of a plate tower.
In Ponchon-Savarit method of no. of theoretical plate determination, the stripping and rectifying operating lines are vertical at total reflux.
94
Pick out the correct statement. a. Dialysis process is used for the production of fresh water from brine. b. Electrodylsis is used in the manufacture of NaOH. c. Electrodylsis is used for the refin-ning/purification of petrol. d. both (b) and (c).
Electrodylsis is used in the manufacture of NaOH.
95
Pick out the correct statement. a. Bound moisture is removed during constant rate drying period. b. Free moisture is removed during falling rate drying period. c. The sum of free moisture and equilibrium moisture in a solid is called the critical moisture. d. The driving force for mass transfer in a wet solid is its free moisture content.
The driving force for mass transfer in a wet solid is its free moisture content.
96
Very tall packed towers are divided into series of beds to
avoid channelling
97
Moisture contained by a substance in excess of the equilibrium moisture is called the __________ moisture.
free
98
With increase in temperature, the solubility of gases in liquids, at fixed pressure
decreases
99
In most of the vacuum crystalliser, vacuum is generally produced by means of a
steam jet ejector with a barometric condenser
100
On moving the feed line (q-line) from saturated liquid feed (vertical position) to saturated vapor feed (horizontal feed), if the slope of both the operating lines are to be increased, then it will result in
increased reflux ratio
101
__________ column is the most suitable for achieving the best performance for mass transfer operations involving liquid with dispersed solids.
Plate
102
Deairation (removal of O2) of water is done by
ion-exchange
103
Make up water is supplied during cooling tower operation to compensate for water losses due to
all
104
Pick out the wrong statement. a. The mole fraction of solute is directly proportional to the molality of a 'dilute' solution. b. For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is nonlinear in the case of steady state unimolal unidirectional diffusion. c. Azeotropes obey Raoult's law at all temperature. d. The relative volatility of a binary mixture at the azeotropic composition is 1.
Azeotropes obey Raoult's law at all temperature.
105
A minimum boiling azeotrope is exemplified by
acetone-carbon disulphide
106
Which of the following solutions will follow Raoult's law most closely?
A solution of benzene, toluene and oxylene.
107
Use of raschig rings in place of crushed stones as packing in packed beds (other things being same)
decreases pressure drop, increases surface area.
108
Critical humidity of a solid salt means the humidity
above which it will always become damp, below which it will always stay dry
109
The assumption made in Elis method in distillation is that enthalpy concentration lines of vapor and liquid are
both parallel and straight
110
As complete saturation of an adsorbent is approached, the differential heat of adsrop-tion approaches
that of normal condensation.
111
Absorption with chemical reaction' is involved in the removal of
carbon dioxide from gaseous stream using alkaline solution.
112
The-relative volatility for separation of a non-ideal binary mixture by distillation should be
> 1
113
Pick out the wrong statement: a. Reboiler is not used in open steam distillation. b. The separation of solutes of different molecular sizes in a liquid solution by use of a suitable membrane is called dialysis. c. Freeze drying is used for the drying of fish. d. Fenske-Underwood equation is used for calculating theoretical number of plates in a distillation column at normal operating reflux condition.
Fenske-Underwood equation is used for calculating theoretical number of plates in a distillation column at normal operating reflux condition.
114
In paper industry, paper is dried in a __________ dryer.
heated cylinder
115
Pick out the wrong statement. a. Critical moisture content is not a property of the material itself. b. A sharp increase in pressure drop gives an indication of the flooding in a distillation column. c. Separation of components is not possible in liquid extraction, if selectivity is unity. d. Dehydration of ethyl alcohol is most economically done by molecular distillation at very high vacuum.
Dehydration of ethyl alcohol is most economically done by molecular distillation at very high vacuum.
116
Only small amount of evaporation of water produces large cooling effects because of its
large latent heat
117
The most common packing used in industrial operations is __________ rings.
raschig
118
When the feed to a distillation column is a saturated liquid, slope of the feed line is
infinity
119
Leaching of sugar from sugar beets is done by
hot water
120
Absorption factor method is used to calculate the number of ideal stages, when
both operating and equilibrium lines are parallel.
121
Flights in a rotary dryer are provided to
lift and shower the solids thus exposing it thoroughly to the drying action of the gas.
122
If f = moles of vapour present per mole of feed, then the slope of feed line is (Mcabe-Thiele method)
-1/f
123
If the solubilities of different components (in a liquid-liquid extraction system) increase with rise in temperature, then the temperature above which they dissolve completely is known as the critical solution temperature (CST or consolute temperature). If solubilities increase with decrease in temperature, then CST is the temperature below which they dissolve completely. If a binary system has no critical solution temperature, it implies that
on heating, a vapor phase will appear ; while on cooling, a solid phase will appear.
124
The rate of mass transfer is not dependent upon the
none of these.
125
At equilibrium the concentration of water in vapour phase (C*)in kg/m3 of air space and the amount of water (m) adsorbed per kg of dry silica gel are related by, C* = 0.0667m. To maintain dry conditions in a room of air space 100m3 containing 2.2 kg of water vapour initially, 10 kg of dry silica gel is kept in the room. The fraction of initial water remaining in the air space after a long time (during which the temperature is maintained constant) is
0.4
126
Dry bulb temperature of unsaturated air is more than its __________ temperature.
dew point, wet bulb
127
For the case of flow of air past a wet bulb thermometer (air water vapour system), the approximate value of h2/ky.Cz is around
1
128
The reciprocal of stripping factor is termed as
absorption factor
129
Ponchan-Savarit method analyses the fractional equipment based on
both enthalpy and material balances.
130
The binary diffusivity in gases at atmospheric conditions is about
10^-1 cm2/sec
131
Percentage saturation is __________ the relative saturation.
always smaller than
132
In case of a desorber (stripper), the
operating line always lies below the equilibrium curve.
133
What is the reflux ratio at total reflux?
Infinity
134
Under conditions of flooding in packed tower, the gas pressure drop
is maximum
135
For achieving rapid drying rate in a spray dryer, the diameter of the particles in the feed should be in the range of __________ microns (1 mm = 1000 microns).
10-60
136
For absorbing a sparingly soluble gas in a liquid
liquid side mass transfer co-efficient should be increased.
137
Channelling in a packed tower results from the
maldistribution of liquid, non-uniformity of packing
138
The change in enthalpy per unit weight of adsorbed gas when adsorbed on gas free or "outgassed" adsorbent to from a definite concentration of adsorbate is called its
integral heat of adsorption.
139
The minimum number of theoretical plates is required for achieving a given separation in distillation column with
total reflux
140
A good solvent used for absorption should not have very high
all
141
In a counter-current liquid extractor
only one of the liquids may be pumped at any desired rate.
142
Which of the following is an undesirable property for an absorbing solvent ?
None of these
143
The wetted wall tower is used to determine
individual mass transfer co-efficient (M.T.C.) in gaseous system.
144
Weight of 1 m3 of humid air as compared to 1 m3 of dry air, under the same conditions, is
less
145
Positive deviation from Raoult's law means a mixture whose total pressure is
greater than that computed for ideality.
146
With increase in gas rate, the number of transfer units, NtoG, for a fixed degree of absorption by a fixed amount of solvent
increases
147
Schmidt number is given by
μ/ρDAB
148
The caking of crystals can be prevented by
maintaining high critical humidity, coating the product with inert material
149
Prandtl number for water at 20°C is about
7
150
Boiling point diagram is
affected by pressure.
151
When acetone is added in a two layer mixture of methyl isobutyl ketone and water at 30°C, the acetone distributes between the two layers and the composition of the layer follows two solubility curves. For this system,
all
152
Steam distillation is used to
avoid thermal decomposition of a component.
153
Freundlich equation applies to the adsorption of solute from
dilute solutions, over a small concentration range.
154
For ethanol-water system, the lowering of distillate quality from 95% to 92% will cause __________ plate requirement.
marginal decrease in the number of
155
The apex of an equilateral-triangular coordinate (in ternary liquid system) represents a/an
pure component
156
The diffusivity (D) in a binary gas mixture is related to the pressure (P) as
D ∝ 1/P
157
A slurry is to be dried to produce flaky solid. Which dryer would you recommend?
Spray dryer
158
Which of the following psychrometric processes is followed by water vapour laden unsaturated air, when it is passed through solid or liquid adsorbent?
Heating and dehumidification at almost constant wet bulb temperature.
159
In gas-liquid contact operation, the number of ideal stages, https://www.indiabix.com/_files/images/chemical-engineering/mass-transfer/331-646-1.png . This is true when the stripping factor 'S' is (see picture)
S > 1
160
The cooling effect in a cooling tower can not be increased by
none of these.
161
The value of NA/(NA + NB) for steady state molecular diffusion of gas 'A' through non-diffusing gas 'B' is
1
162
The humid volume may be increased by increasing the
temperature at constant humidity, humidity at constant temperature.
163
Pick out the wrong statement a. Co-current absorbers are usually used, when the gas to be dissolved in the liquid is a pure substance. b. In case of gas absorption, HETP is equal to HTU, when both the operating line & the equilibrium lines are parallel. c. Hatta number is important in case of gas absorption with chemical reaction. d. In actual practice, absorption is an en-dothermic process, while stripping is an exothermic process
In actual practice, absorption is an en-dothermic process, while stripping is an exothermic process.
164
When the mixture to be distilled has a very high boiling point and the product material is heat sensitive, the separation technique to be used is __________ distillation.
steam
165
Large scale drying of wheat is done in a __________ dryer.
spouted bed
166
Azeotropic distillation is employed to separate
constant boiling mixture.
167
The drying time between fixed moisture content within diffusion controlled 'falling rate period' is proportional to (assuming that drying occurs from all surfaces of the solid) (where, T = thickness of the solid)
T^2
168
At the boiling point of the liquid at the prevailing pressure, the saturated absolute humidity becomes
169
Use of natural draft cooling tower is practised, when the air has low
humidity, temperature
170
Pressure drop through plate tower as compared to that through packed tower, for the same duty will be
more
171
Dimension of mass diffusivity is the same as that of
kinematic viscosity
172
Dorr thickener is an equipment used for
sedimentation
173
Steam distillation is used to separate
high boiling substances from nonvolatile impurities.
174
In distillation where q is defined as the moles of liquid flow in the stripping section per mole of feed introduced, for saturated liquid feed
q = 1
175
Which of the following is an undesirable property in a tower packing?
Large weight of liquid retained.
176
Water entrained by circulating air in cooling towers is termed as
drift
177
A 25 cm x 25 cm x 1 cm flat sheet weighing 1.2 kg initially was dried from both sides under constant drying rate conditions. It took 1500 seconds for the weight of the sheet to reduce to 1.05 kg. Another 1m x 1m x 1cm flat sheet of the same material is to be dried from one side only.Under the same constant drying rate conditions, the time required for drying (in seconds) from its initial weight of 19.2 kg to 17.6 kg is
1000
178
With increase in temperature, the rate of leaching increases, because the
diffusivity of solute increases.
179
Humidity chart is useful for the solution of problems concerning condensation, vaporisation and air conditioning. At a given dry bulb temperature, value of humidity obtained from the humidity chart directly, is in terms of __________ humidity. molal
molal
180
The Kundsen diffusivity is proportional to (where, T = absolute temperature)
sqrt(T)
181
In case of constant underflow extraction operation, the __________ at all solute concentration.
solids are drained to the same extent, ratio of the insoluble to solution is constant
182
In an absorption coloumn, the flooding velocity for random packing is __________ that for stacked/regular packing.
smaller than
183
The relation among various mass transfer co-efficients (M.T.C) for ideal gases is given by (where, Kc & Km are M.T.C. for equimolar counter diffusion with concentration & mole fraction respectively as the driving force. and, Kp = M.T.C. for diffusion of a gas through a stagnant inert gas with pressure as driving force.)
Kc = Kp . RT = Km . RT/p
184
With increase in temperature, the leaching rate increases because of the
increased diffusivity, decreased viscosity of liquid
185
Leaching of uranium ore and gold ore is done in
Pachuka tanks
186
Blowdown in a cooling tower
means discarding a small fraction of circulating water to prevent and limit the concentration of salt and impurities.
187
During constant rate period, the rate of drying decreases with the
decrease in air temperature, increase in air humidity
188
Antibiotics are best handled in a
Podbielniak extractor.
189
The fixed cost of a distillation column at minimum reflux ratio is
infinite
190
__________ extractor uses centrifugal force for separating the two phases.
Podbielniak
191
In a binary distillation column, if the feed contains 40 mole % vapour, the q line will have a slope of
-1.5
192
Pick out the wrong statement. a. Mechanical agitation is required, if the system has low interfacial tension. b. Seive tray towers are generally used for systems having low interfacial tension. c. When Henry's law constant is very small, then the mass transfer rate is controlled by the gas film resistance. d. Taylor-Prandtl analogy for heat and mass transfer considers the transfer through both laminar and turbulent layers.
Mechanical agitation is required, if the system has low interfacial tension.
193
Acetic acid will be most economically separated from a dilute solution of acetic acid in water by
solvent extraction
194
Design calculation for multiple component distillation is done by
tray to tray calculations.
195
To get high tray efficiency
interfacial surface between liquid and gas phase should be large.
196
The mass transfer co-efficient for a solid sphere of radius 'a' dissolving in a large volume of quiescent liquid, in which D is the diffusivity of solute, is
dependent on the Reynolds number
197
Pick out the wrong statement. Generally for physical adsorption, a gas of
none of these.
198
In most of the mechanically agitated liquid-liquid extractors, baffles or horizontal compartmental plates are provided, which helps in
all
199
In a vapor-liquid contacting equipment, the overall gas phase mass transfer co-efficient (M.T.C), KG is related to individual co-efficients (KG and KL) as
1/KG = 1/KG + m/KL
200
Solvent extraction is the terminology applied to the liquid-liquid extraction, which is preferred for the separation of the components of liquids, when
one of the liquid components has very high affinity towards the solvent.
201
Inside the distillation column, the
driving force for the vapour flow is the pressure drop.
202
Diffusivity in concentrated solutions differs from that in dilute solutions, because of the changes in
viscosity with concentration, degree of ideality of the solution
203
Occurrence of 'case hardening' during drying of a high moisture solid cake __________ the drying rate.
decreases
204
Which of the following is not a continuous drier?
Tray drier
205
Humidification involves mass transfer between a pure liquid phase and a fixed gas, which is
insoluble in the liquid
206
__________ is the temperature at which a gas-vapor mixture becomes saturated, when cooled at constant total pressure out of contact with a liquid.
Dew point
207
Rate of leaching increases with increasing
temperature
208
An azeotropic mixture is a __________ mixture.
constant boiling point
209
Pick out the wrong statement. a. In the McCabe-Thiele diagram for binary distillation, vertical feed line represents saturated liquid feed and horizontal feed line represents saturated vapour feed. b. In small columns, local efficiency is larger than Murphree efficiency; in large columns local efficiency is smaller than Murphree efficiency. c. For Laminar flow over a plate of length L, the local mass transfer co-efficient at a distance L from the leading edge is 1.5 x 10-2m/s. Then the average mass transfer co-efficient for the plate is 2 x 10- 2m/s. d. The concentration and hydrodynamic boundary layers over a flat plate are of equal thickness, if Schmidt number is equal to unity
For Laminar flow over a plate of length L, the local mass transfer co-efficient at a distance L from the leading edge is 1.5 x 10-2m/s. Then the average mass transfer co-efficient for the plate is 2 x 10-2m/s.
210
Molecular seives are regenerated by heating to __________ °C.
200-330
211
In continuous distillation, the internal reflux ratio (Ri) and the external reflux ratio (Re) are related as
Ri = Re/1+Re
212
In a counter-current extractor, as the axial mixing increases, the extraction efficiency
decreases
213
Heat sensitive materials like certain pharmaceuticals and food stuffs can be dried in a/an __________ dryer.
freeze
214
In extractive distillation, solvent is
added to alter the relative volatility of the mixture.
215
Radioactive nuclear waste is treated in
pulsed column extractor
216
Large scale drying of sugar is done in a __________ dryer.
rotary
217
__________ temperature is the steady state temperature attained by a small amount of liquid evaporating into a large quantity of unsaturated gas-vapor mixture.
Wet bulb
218
The drying time between fixed moisture contents within the 'constant rate period' is proportional to (assuming that drying occurs from all surfaces of the solid) (where, T = thickness of the solid)
T
219
__________ equation applies to diffusivities in liquids.
Gilliland
220
A packed tower compared to a plate tower for a particular mass transfer operation
incurs smaller pressure drop.
221
Which of the following is the most commonly used leaching solvent in vegetable oil industry?
Hexane
222
In an absorber, HETP does not vary with the
none of these
223
Large quantity of silica gel is normally dried in a __________ dryer.
through circulation
224
For the same system, if the same liquid used in an absorber is decreased, the tower height will
increase
225
Hydrogenation of oil is carried out in a/an __________ in Vanaspati manufacturing plant.
agitated vessel
226
Sides of equilateral-triangular co-ordinates (on which ternary liquid system is plotted) represent
a binary mixture.
227
In distillation column design, the McCabe-Thiele procedure is inadequate and a Ponchan-Savarit procedure is needed, when
a total condenser is used.
228
In an interphase mass transfer process, the lesser the solubility of a given solute in a liquid, the higher are the chances that the transfer process will be
gas phase resistance controlled.
229
As the reflux ratio decreases, the
number of plates increases.
230
Which of the following equipments is not used for gas dispersion?
Spray towers
231
One mole feed of a binary mixture of a given composition is flash vaporised at a fixed P and T. If Raoult's law is obeyed, then changing the feed composition would effect
the fraction vaporised but not the product composition.
232
The equation, https://www.indiabix.com/_files/images/chemical-engineering/mass-transfer/315-483-1.png is for (see attached picture)
steady state equimolar counter diffusion
233
With increase in the liquid flow rate at a fixed gas velocity in a randomly packed counter current gas-liquid absorption column, the gas pressure drop
increases
234
The equation, https://www.indiabix.com/_files/images/chemical-engineering/mass-transfer/314-467-1.png is for (see attached ppicture)
stready state diffusion for stagnant case.
235
Which of these columns incurs the lowest pressure drop?
Packed column (with stacked packing)
236
In the desorption of highly soluble gas from the liquid, the main resistance will be in the __________ phase.
liquid
237
If G = insoluble gas in gas stream and L = non-volatile solvent in liquid stream, then the slope of the operating line for the absorber is
L/G
238
Which of the following remains constant during evaporative cooling process with recirculated water supply?
Wet bulb temperature
239
For stripping of a gas in a counter current stripper, the operating line
can lie above or below the equilibrium curve.
240
Which of the following same diameter columns gives lowest pressure drop per unit height?
Packed column (stacked)
241
Diffusion in concentrated solutins differs from that in dilute solutions, because of the change in the __________ with the concentration of the solution.
degree of ideality, viscosity
242
Stage efficiency in a leaching process depends on the
time of contact between the solid and the solution, rate of diffusion of the solute through the solid and into the liquid
243
Operating velocity in a packed tower is usually __________ the flooding velocity.
half
244
The Knudsen diffusivity is dependent on the
molecular velocity and por radius of the catalyst.
245
Minimum possible diameter of a packed coloumn is decided mainly by the
flooding
246
Solvent used in extractive distillation
forms a low boiling azeotrope.
247
Capacity of a rotary dryer depends on its
r.p.m, inclination with ground surface
248
The cooling effect in a cooling tower can be speeded up by
all
249
The following plot gives the saturated humidity (He) versus temperature (T).Line joining (H1, T1) and (H2, T2) is the constant enthalpy line. Choose the correct one from among the alternatives A, B, C and D. The following plot gives the saturated humidity (He) versus temperature (T).Line joining (H1, T1) and (H2, T2) is the constant enthalpy line. Choose the correct one from among the alternatives A, B, C and D. https://www.indiabix.com/_files/images/chemical-engineering/mass-transfer/335-677-1.png
T1-Dry bulb temp; T2-Wet bulb temp; T3-Dew point temp.
250
When both the fluids flow concurrently in an absorber, the slope of the operating line is
- ve
251
The percentage humidity is less than the relative humidity only at __________ percent humidity.
both zero and hundred
252
Back-trapping in a distillation column
decreases tray efficiency.
253
Flooding in a vapor-liquid contacting equipment occurs in a tray, when the pressure drop through a tray is __________ the liquid head available in the downcomer.
more than
254
Milk is dried usually in a __________ dryer.
spray
255
At a given equilibrium pressure, with increase in temperature, the concentration of adsorbed gas on solid adsorbant
decreases
256
Which of the following adsorbent is used to decolourise yellow glycerine?
Activated carbon
257
In a distillation column, with increase in the reflux ratio, the heat removed in the cooler
increases.
258
Pick out the wrong statement. a. Constant pressure distillation can not separate an azeotropic mixture. b. Relative volatility of a binary mixture changes appreciably with the minor change in temperature. c. The relative volatility of a binary mixture at azeotropic composition is unity. d. Flash distillation is practised on wide spread scale in petroleum refinery.
Relative volatility of a binary mixture changes appreciably with the minor change in temperature.
259
Which of the following is not a unit of mass transfer co-efficient?
None of these
260
The falling rate period in the drying of a solid is characterised by
increasing temperatures both on the surface and within the solid.
261
In which of the following unit operations, the selectivity is an important parameter?
Solvent extraction
262
Which of the following is an undesirable characteristic for the solvent used in gas absorption?
None of these
263
Which of the following equipments is not used for liquid dispersion?
Agitated vessels
264
Diameter of raschig rings used in packed tower in industry is normally around __________ inches.
2
265
The diffusion co-efficient in m2 /s. of acetic acid in benzene (liquid in liquid) is
2.09 x 10-9
266
Pick out the wrong statement. a. The Reynolds analogy for mass transfer is given by Lewis relation and is applicable, when Schmidt number is one. b. Sherwood number for flow in pipes can be expressed as the ratio of the concentration gradient at wall to the overall concentration difference. c. According to film theory for equimolar counter diffusion, the mass transfer coefficient is given by DAB(b)P - 3, Q - 2 d. The z-component of the total mass flux of a component A in binary mixture of A and B is given by - Dab'.dCA/dz.
According to film theory for equimolar counter diffusion, the mass transfer coefficient is given by sqrt(DAB)(b)P - 3, Q - 2
267
In case of non-ideal gases and liquids, the molal diffusivity
is independent of pressure.
268
Condensation of a vapour-gas mixture just begins, when (where, p = partial pressure of the vapour P = vapour pressure of the liquid)
p = P
269
__________ number indicates the ratio of the rates of the heat and mass transfer incase of a cooling tower.
Lewis
270
The expression, y(1 - x)/x(1 - y) is for
relative volatility
271
In physical terms, Schmidt number means
momentum diffusivity/mass diffusivity.
272
In case of liquids, the binary diffusivity is proportional to (where, T = temperature)
T
273
The diffusivity, DAB (for component A diffusing in B) is equal to the diffusivity DBA (for component B diffusing in A) for a binary mixture of
ideal gases
274
Mass transfer co-efficient is directly proportional to DAB0.5, according to __________ theory.
penetration
275
Sand is dried in foundaries in a___drier.
fluidised bed
276
Which of the following employs an accessory known as 'drift eliminator'?
Mechanical draft cooling tower.
277
Pick out the correct statement. a. Higher hold up of the solid in the rotary dryer results in better exposure of the solids to the gas. b. The 'Hatta number' is important in problems involving gas absorption without chemical reaction. c. For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is linear in the case of steady state equimolal counter-diffusion. d. Total reflux in case of distillation operation requires infinite number of plates for a binary system separation.
For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is linear in the case of steady state equimolal counter-diffusion.
278
Pick out the correct statement. a. For identical gas flow rates, less pressure drop occurs through a plate tower than through a packed tower. b. Plate column can handle greater liquid loads without flooding than packed column, but the liquid hold up is more in the case of plate column. c. For the same duty, plate columns weigh less than packed columns. d. all (a), (b) and (c).
all
279
Humid volume is the total volume in m3 of 1 kg of
gas plus its accompanying vapour at 1 atm. and gas temperature.
280
Diameter to height ratio for a rashig ring is
1
281
The equipment used in the extraction of highly corrosive radio active liquids is
pulse column
282
Advantage of continuous drying over batch drying is that the
all
283
With increase in temperature, the rate of extraction in leaching (solid-liquid extraction system)
increases
284
In a packed bed absorption column, the channelling will be noted by the
sharp drop in pressure drop.
285
Gaseous diffusivity at atmospheric pressure is of the order of __________ cm2/second.
1
286
In liquid-liquid extraction, the number of phases at plait point is
1
287
In a liquid-liquid extraction, 10 kg of a solution containing 2 kg of solute C and 8 kg of solvent A is brought into contact with 10 kg of solvent B. Solvent A and B are completely immiscible in each other whereas solute C is soluble in both the solvents. The extraction process attains equilibrium. The equilibrium relationship between the two phases is Y* = 0.9X, where Y* is the kg of C/kg of B and X is kg of C/kg of A. Choose the correct answer.
The entire amount of C is transferred to solvent B.
288
The surface renewal frequency in Danckwerts' model of mass transfer is given by (KL: mass transfer co-efficient)
sqrt(KL2.DA)
289
If Rm is the minimum reflux ratio, the optimum reflux ratio may be around __________ Rm.
1.2 to 1.5
290
During dehumidification of unsaturated air wet bulb temperature & partial pressure of vapor are not constant. However, during evaporative cooling process with recirculated water supply, the __________ remains constant.
wet bulb temperature
291
In case of absorption, both the operating and equilibrium lines will be straight for
dilute solutions and isothermal operation.
292
Mass transfer co-efficient varies as DAB0.5, according to the __________ theory.
surface renewal
293
For an absorber, both equilibrium and operating line will be straight for
dilute solution and isothermal operation.
294
A distillation column separates 10000 kg/hr of a benzene-toluene mixture as shown in the figure below: https://www.indiabix.com/_files/images/chemical-engineering/mass-transfer/335-680-1.png In the figure xF, xD and xW represent the weight fraction of benzene in the feed, distillate and residue respectively. The reflux ratio is
0.6
295
Unsaturated air (with dry bulb and wet bulb temperatures being 45°C and 25°C respectively) is passed through a water spray chamber maintained at 23°C. The air will be cooled and
humidified with wet bulb temperature decreasing.
296
Humid volume, at a given temperature is a/an __________ function of humidity.
linear
297
The Schmidt number which is defined as, μ/ρ D, is the ratio of the
momentum diffusivity to the mass diffusivity.
298
If f is defined as above, then which of the following applies to a feed at dew point ?
f = 1
299
Perforated plate towers are unique for solvent extraction because, they provide
repeated coalescence & redispersion of the drop phase.
300
In case of absorption & stripping, the interface of the liquid & gas phases are present in equilibrium, when the diffusional resistance of __________ is zero.
interface
301
Pick out the wrong statement pertaining to the analogy between equations of heat and mass transfer operations.
Reynolds number in mass transfer is analogous to Grashoff number in heat transfer.
302
The slope of the operating line for a single component co-current absorber when plotted in terms of mole ratio units is
(-) ve
303
The individual mass transfer co-efficients (moles/m2 . s) for absorption of a solute from a gas mixture into a liquid solvent are, KL = 4.5 and KG = 1.5. The slope of the equilibrium line is 3. Which of the following resistance (s) is (are) controlling?
gas side
304
Pore size of the molecular seive 5A is __________ mm.
0.5
305
Swenson-Walker crystalliser is a __________ unit
continuous
306
According to the Fenske equation, what will be the minimum number of plates required in a distillation column to separate an equimolar binary mixture of components A and B into an overhead fraction containing 99 mol% A and a bottom fraction containing 98 mol% B ? Assume that relative volatility (αAB = 2) does not change appreciably in the coloumn.
12
307
Absorption (liquid-gas system) with evolution of heat as compared to isothermal absorption results in
all
308
With increase in temperature, the mutual solubility of two liquids
increases
309
Pick out the wrong statement. a. In solvent extraction, the distribution co-efficient should be as large as possible for solvent economy. b. With increase in pressure, the solubility of gases in solvent increases at a fixed temperature. c. Decrease in Murphree plate efficiency is an indication of entrainment in distillation coloumn. d. The capacity of a distillation coloumn is maximum at total reflux.
The capacity of a distillation coloumn is maximum at total reflux.
310
The relative volatility of a binary mixture at the azeotropic composition is
1
311
Relative volatility varies with the concentration of component for an ideal solution. The relative volatity of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when
Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law.
312
Bound moisture is that liquid which exerts an equilibrium vapor pressure __________ that of the pure liquid at the given temperature.
less than
313
Lewis number (Le) is
Sc / Pr
314
Which of the following is not a continuous leaching equipment?
Pachuka tank
315
__________ extractor is used for the concentration of radioactive nuclear waste.
Pulsed column
316
Moisture content of a substance when at equilibrium with a given partial pressure of the vapour is called the __________ moisture.
equilibrium
317
All moisture in a non-hygroscopic material is the __________ moisture.
unbound
318
Pick out the correct relationship. (where, Ri = internal reflux ratio Ro = external reflux ratio.)
(1 + Ro) = Ro/Ri
319
Separation of __________ employs gaseous diffusion process.
isotopes of uranium
320
For water-ethanol system, the minimum reflux ratio
is computed from the slope of the upper operating line that is tangent to the equilibrium curve.
321
The interfacial area per unit volume of dispersion, in a gas-liquid contactor, for fractional hold up of gas = 0.1 and gas bubble diameter = 0.5 mm is given by (in m2/m3)
500
322
Though, theoretically the adsorption & desorption isotherms is expected to coincide but sometimes at least a part of the isotherms does not coincide and this phenomenon is known as adsorption hysterisis. In such cases, the desorption equilibrium pressure is __________ that obtained for adsorption.
lower than
323
Experimental determination of __________ is done by wetted wall column method.
mass transfer co-efficient
324
Pick out the wrong statement: a. Absorption factor is constant, when the equilibrium and operating lines are straight. b. In case of a stripper, the equilibrium curve is always below the operating line. c. In case of an absorber, the operating line is always above the equilibrium curve. d. In the absorption of low solubility gases, the liquid film is the controlling resistance.
In case of a stripper, the equilibrium curve is always below the operating line.
325
In liquid extraction, if the selectivity is unity, then
no separation will occur.
326
Paper industry employs __________ driers.
cylinder
327
Which of the following has the same dimension as mass diffusivity?
Kinematic viscosity, Thermal diffusivity
328
Pick out the wrong statement pertaining to the cooling towers.
Effectiveness of a mechanical draft cooling tower is reduced with increase in air wet-bulb temperature.
329
Experiments were conducted to determine the flux of a species A in a stagnant medium across a gas-liquid interface. The overall mass transfer co-efficient based on the liquid side for dilute systems for the above was estimated to be 4 x 10-3 kg mole/m2.s. The equilibrium data for the system is given as y = 2x. The flux across the interface (in kg mole/m2 .s) for bulk concentrations of A in gas phase and liquid phase as y = 0.4 and x = 0.01 respectively is
8.5 x 10-4
330
Leaching of coarse solid lumps is also termed as
percolation
331
The main reason for dividing a tall packed tower into series of small towers is to
avoid channeling.
332
Co-current absorbers are usually used when the gas to be dissolved in the liquid is
a pure substance
333
At what percentage (by volume) of alcohol composition, it forms an azeotrope with water?
95
334
Measurement of the interfacial area of mass transfer is achieved easily & accurately in case of a __________ coloumn.
wetted wall
335
With the lowering of equiliDrium pressure, at a given temperature, the amount of ad-sorbate on the adsorbent
decreases.
336
Mass transfer co-efficient is defined as
Co-efficient = Flux/concentration difference.
337
When an unsaturated air-water mixture is heated at constant pressure, then
the relative humidity decreases.
338
During sensible cooling process
relative humidity increases, wet bulb temperature decreases
339
At a fixed pressure, the humidity depends upon the partial pressure of vapor in the mixture. Humidity of a vapour free gas is __________ percent.
0
340
In case of physical adsorption, the difference between heat of adsorption and heat of normal condensation is
equal to the heat of wetting.
341
Pick out the wrong statement: a. Change in barometric pressure does not affect the relative humidity. b. In case of a packed tower, the operating velocity is about half of the flooding velocity, generally. c. 'Elution' means the desorption of the adsorbed solute by a solvent. d. The equilibrium moisture content of the solid can be reduced by increasing the absolute humidity.
The equilibrium moisture content of the solid can be reduced by increasing the absolute humidity.
342
The value of L/mG ratio for economical absorption operation ranges from
1.25 to 2.0
343
Large scale usage of flash distillation is practised in
petroleum refinning
344
High pressure at the bottom of a distillation tower handling heat sensitive materials results in
thermal decomposition of bottoms.
345
Alcohol is dehydrated using __________ distillation.
azeotropic
346
Separation of two volatile liquids by distillation makes use of their
relative volatility
347
Which of the following increases during evaporative cooling process with recirculated water supply?
Relative humidity, Partial pressure of vapour
348
Dried finished product sampled from various parts of a __________ dryer exhibits non-uniformity in the moisture content.
tray
349
__________ is used as an 'entrainer' for the separation of acetic acid-water mixture by distillation.
Butyl acetate
350
Rotary dryers cannot handle __________ materials.
sticky
351
Pick out the correct statement. a. Diffusivity decreases with increase in temperature. b. Diffusivity increases with increase in molecular weight. c. Diffusivity increases with the size of the individual molecule. d. none of these.
none of these.
352
An example of elution is
separation of uranium oxide from its ore by H2SO4 in a Pachuca tank.
353
The operating line for an absorber is curved, when plotted in terms of
partial pressure
354
Relative volatility does not change appreciably with the change in
temperature
355
Boiling point diagram is not affected by the ambient
humidity, temperature
356
The dew point of a saturated gas phase equals the __________ temperature.
gas
357
A solid material shows case hardening properties while drying. Which of the following should be controlled to control the drying process?
Temperature of the solid
358
In case of liquid-liquid binary diffusion, diffusivity of one constituent into another is not dependent on the
none of these
359
For continuous drying of grannular or crystalline material, the dryer used is the __________ dryer.
rotary
360
When adsorption hysteresis is observed, the desorption equilibrium pressure is __________ that obtained by adsorption.
always lower than
361
Moisture in a substance exerting an equilibrium vapour pressure less than that of pure liquid at the same temperature is called the __________ moisture.
bound
362
For a binary mixture with low relative volatility, continuous rectification to get pure products will require
high reflux ratio
363
The efficiency of a plate column will be maximum, when the flow is ideal __________ the plate.
across, above
364
Heat load in a cooling tower
means the amount of heat thrown away (KCal/hr.) by the cooling tower, is equal to the number of kg, of water circulated times the cooling range.
365
In case of absorption with exothermic reaction, for fluids having
Pr = Sc; percentage change in heat and mass transfer flux will be the same for a given change in the degree of turbulence, Pr = Sc = 1; total mass, momentum and thermal diffusivity will be the same
366
Detergent solution is dried to a powder in a
spray dryer
367
Which of the following mixtures does not form an azeotrope at atmosheric pressure?
None of these
368
During bottling of cold drinks (e.g. Pepsi), the main resistance to mass transfer for the absorption of carbon dioxide in water lies in the
liquid film
369
The overall mass transfer co-efficient for the absorption of SO2 in air with dilute NaOH solution can be increased substantially by
increasing the gas film co-efficient.
370
Flooding results in
low tray efficiency
371
For the air water system under ambient conditions, the adiabatic saturation temperature and the wet bulb temperature are nearly equal, because
water has a high latent heat of evaporation.
372
In an operating distillation column, the
driving force for the vapor flow is the pressure drop, as the pressure decreases gradually from the bottom to the top of the column.
373
In a forced draft cooling tower, water is cooled from 95 to 80°F by exposure to air with a wet bulb temperature of 70°F. In this case, the
range is 15°F, approach is 10°F
374
The diffusivity (D) in a binary gas mixture is related to the temperature (T) as
D ∝ T^1.5
375
For which of the following unit operations, Lewis number is of significance?
Humidification
376
Tray spacing in a distillation column of dia 10-12 ft. used in petroleum refinery may be around __________ inches.
30
377
If a1 and a2 are the relative volatilities when the pressure in the distillation column is 1 and 2 atm respectively. Pick out the correct statement.
none of these
378
The dimension of diffusivity is same as that of the
kinematic viscosity
379
The temperature to which a vapour gas mixture must be cooled (at varying humidity) to become saturated is called the __________ temperature.
none of these
380
Entrainer used in azeotropic distillation should
form a low boiling azeotrope with one of the constituents of the mixture.
381
In case of steam distillation, the steam leaving the liquid is not completely saturated with distillate vapour, because
mixing of steam with the material being vaporised is not so intimate as to result in equilibrium condition.
382
Pick out the wrong statement. a. The operating line always lies above the equilibrium solubility curve in case of a single component absorber. b. The operating line always lies below the equilibrium solubility curve in case of a single component stripper. c. The operating pressure in solvent extraction system should be below vapor pressures of all components. d. The solubility of a particular gas in ideal solution in any solvent is always the same.
The operating pressure in solvent extraction system should be below vapor pressures of all components.
383
Leaching of coffee from coffee beans is done by
hot water
384
For contacting a highly soluble gas with a liquid
bubble the gas through liquid.
385
During drying operation, it is easier to remove the __________ moisture.
unbound
386
With increase in solvent rate, the number of transfer units, NtoG, for a fixed degree of absorption from a fixed amount of gas
decreases
387
Ion exchange process is similar to
adsorption
388
A distillation column with N plates is being operated under normal conditions. At some point of time, the operation is shifted to total reflux condition (i.e., no product and residue are being withdrawn and feed to the column is stopped). At the new steady state,
the top and bottom compositions correspond to the maximum enrichment available.
389
Dryer widely used in a textile industry is __________ dryer.
conveyor
390
Solvent used in extractive distillation
changes the relative volatility of the original components.
391
Air at a particular humidity is heated in a furnace. The new dew point
increases
392
In a packed tower, the value of HETP equals HTUOG, when the equilibrium and the operating lines are (where, HETP = height equivalant to a theoretical plate HTUOG = overall gas phase height of a transfer unit)
straight, parallel
393
The vapour pressure exerted by the moisture contained in a wet solid depends upon the
all
394
The absorption factor is defined as (where, L = liquid flow rate, G = gas flow rate and, m = slope of the equilibrium line)
L/mG
395
Smoke is an example of
solid dispersed in gas
396
Which of the following adsorbant is used in the refinning of sugar?
Bone charcoal
397
Stacked packing compared to dumped packing
provides poorer contact between the fluids, gives lower pressure drop.
398
In McCabe-Thiele method of theoretical plate calculation for a distillation column, the operating lines of stripping and rectifying sections coincide with the diagonal at __________ reflux.
total
399
Which of the following parameters remains constant during chemical dehumidification?
Dry bulb temperature
400
Drying of a solid involves __________ transfer.
both heat and mass
401
Mechanism of moisture removal in case of freeze drying of food stuff is by
sublimation
402
The dew point of an unsaturated gas-vapor mixture does not depend upon the __________ of the mixture.
temperature
403
Which is not concerned directly with mass transfer?
Froude number
404
Removal of __________ exemplifies an adsorption unit operation.
water from petrol
405
Can the efficiency of a plate in the distillation tower be greater than 100%?
Never
406
With increase in the mass velocity of the gas, the rate of drying during the constant rate period __________ , if the conduction and radiation through the solid are negligible.
increases
407
For gas absorption, low viscosity solvents are preferred, because of their
all
408
To remove all the moisture from a wet solid it requires exposure to __________ air.
perfectly dry
409
The operating cost of a distillation column at minimum reflux ratio is
minimum
410
The reflux to a distillation column is 100 moles/hr, when the overhead product rate is 50 moles/hr. The reflux ratio is
2
411
Molecular diffusivity of a liquid
increases with temperature.
412
The wet and 'dry bulb temperature for a vapour-gas mixture are 25°C and 30°C respectively. If the mixture is heated to 45°C at constant pressure, the wet bulb temperature will be __________ °C.
> 25
413
Henry's law states that the
partial pressure of a component over a solution is proportional to its mole fraction in the liquid.
414
Ammonia present in the coke oven gas is removed by washing with
dilute ammoniacal liquor
415
With increase in temperature, the leaching rate increases due to
decreased liquid viscosity, increased diffusivity
416
Which of the following processes is not an example of adsorption applied to gaseous separations?
Decolouration of yellow glycerene.
417
The critical moisture content in case of drying indicates the __________ rate period.
beginning of falling
418
Pick out the wrong statement a. A horizontal line on the humidity chart indicates the temperature changes at constant molal humidity. b. When water is cooled from 80 to 70°C by exposure to the air with a wet bulb temperature of 60°C, then both the approach & the range would be 10°C. c. For unsaturated air-water vapor mixture at atmospheric conditions, the wet bulb temperature & adiabatic cooling lines are the same. d. Relative saturation of unsaturated mixture of water vapor & air can not be increased by either reducing the mixture temperature or by increasing the total pressure.
Relative saturation of unsaturated mixture of water vapor & air can not be increased by either reducing the mixture temperature or by increasing the total pressure.
419
According to Poiseuille's law, the permeability for gas flow through a capillary is proportional to (where, μ = gas viscosity)
1/μ
420
For a binary mixture distillation process, the degree of freedom is 2. However, if the pressure is fixed in this process, the number of independent variables in this process will be
1
421
H2S is being absorbed in a gas absorber unit. The height of the transfer unit based on the overall mass transfer coefficient on the gas side is 0.4 m. The equilibrium data is given by, y = 1.5 x. The bulk concentration of H2S has to be reduced from 0.05 to 0.001 mole fraction in the gas side. The height of the tower (in metres) corresponding to an operating line given by, y = 5x + 0.001 is
2
422
Packed column distillation is limited to the column __________ metres.
height < 6, diameter < 0.6
423
For the flow of gases through a capillary, with increase in temperature, the permeability __________ as per Knudsen law.
increases
424
Which of the following is directly concerned with psychrometry?
Lewis relationship
425
Plate efficiency in a distillation column is reduced due to the __________ of liquid.
all
426
The most efficient cooling tower out of the following is
induced draft
427
Sodium bicarbonate is produced during soda ash manufacture using a __________ tower.
baffle
428
Powdery materials can be guarded against caking tendency on storage by
none of these.
429
In case of cooling towers, the ratio of the rates of heat and mass transfer is indicated by the __________ number.
Lewis
430
Which one of the following devices is not used for both the absorption as well as the liquid-liquid extraction processes?
Wetted wall columns
431
The temperature of water cooled in cooling tower is always __________ temperature of entering air.
more than the wet bulb
432
Which of the following processes is followed by unsaturated air (with dry bulb temperature 12°C and relative humidity 47%) passing through water spray washer (temperature of water being constant at 40°C?
Both heating and humidification
433
Mass transfer co-efficient is directly proportional to DAB according to the __________ theory.
film
434
The relative volatility of a binary mixture at constant temperature __________ the total pressure.
decreases with increase in
435
Tower diameter may be decreased by
use of increased tray spacing.
436
Rayleigh's equation applies to __________ distillation.
differential
437
Steady state equimolal counter diffusion is encountered in
separation of a binary mixture by distillation.
438
Which of the following is considered equivalent to one theoretical stage in Mc-Cabe Thiele's method?
Total condenser, Reboiler
439
Polar organic compounds are normally used as separating agents for the azeotropic and extractive distillation. Which of the following is the most important factor to be considered for the choice of the separating agent for extractive distillation?
Selectivity
440
As the reflux ratio increases, the slope of the operating line for rectifying section
increases
441
Cox chart, which is useful in the design of distillation column particularly for petroleum hydrocarbons, is a plot of (where, P = vapor pressure, T = temperature)
log P vs . T
442
The unit of volumetric diffusivity is
cm2/sec
443
For a ternery mixture, in which equilateral triangular co-ordinate is used in leaching and extraction, a __________ of the equilateral triangular co-ordinates.
pure component is represented by the apex.
444
Steady state temperature reached by a small amount of liquid evaporating into a large amount of unsaturated vapour-gas mixture is called the __________ temperature.
wet-bulb
445
The Reynolds number of the liquid was increased 100 fold for a laminar falling film used for gas-liquid contacting. Assuming penetrating theory is applicable, the fold increase in the mass transfer co-efficient (Kc) for the same sytem is
10
446
The slope of 9-line is determined by the
thermal condition of the feed
447
In steam distillation, the
product must be immiscible with water.
448
Which of the following can be calculated theoretically using steam table and Dalton's law of partial pressure; if the relative humidity and dry bulb temperature of moist air is known?
Wet bulb temperature
449
Steam distillation is used for separation of high boiling
substances from non-volatile impurities, volatile impurity from still higher boiling substances
450
The feed to fractionating column is changed from saturated vapour to saturated liquid. If the separation and reflux ratio remains unchanged, the number of ideal stages will
increase
451
Rose oil is extracted from rose leaves using __________ distillation.
steam
452
Hypersorption refers to a __________ process.
moving bed adsorption
453
Extraction of coffee from its seed is done by
leaching.
454
In azeotropic mixture, the equilibrium vapour composition is
same as liquid composition.
455
With lapse of time, the overhead composition of light component in case of batch distillation with constant reflux
decreases
456
Lewis number, which is important in problems involving simultaneous heat and mass transfer, is the ratio of
thermal diffusivity to mass diffusivity.
457
According to the film theory of mass transfer, the mass transfer co-efficient is proportional to (where, D = molecular diffusivity)
D
458
Dry bulb temperature of the gas is __________ the wet bulb temperature.
more than
459
Decoction refers to the use of solvent
at its boiling point
460
Flash distillation is suitable for separating the constituents of a binary system, which
have very wide boiling points.
461
The ratio of Murphree plate efficiency to point efficiency is 1 in a __________ flow model.
perfectly mixed
462
The rough value of diffusion co-efficient of water vapor into air at 25°C may be about __________ cm2/sec.
0.25
463
Flooding in a column results due to
high pressure drop
464
Which of the following gas-liquid contacting devices incurs the least pressure drop for a particular duty?
Wetted wall tower
465
A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%. m-xylene (all percentages in w/w). Which of the following statements would be true in respect of this mixture?
The mixture exhibits an azeotrope at 101.3 kPa.
466
Unsaturated air (with dry bulb temperature and dew point being 35°C and 18°C respectively) is passed through a water spray chamber maintained at 15°C. The air will be cooled
and dehumidified with decrease in wet bulb temperature.
467
The process employing desorption of the absorbed solute by a solvent is called
elution
468
If the overall efficiency and Murphree plate efficiency are equal, then both the equilibrium and operating lines are
straight, parallel
469
Which of the following operations does not involve leaching?
Removing nicotine from its water solution by kerosene.
470
The recovery of pencillin from the acidified fermentation broth is done by
liquid extraction
471
Unit operation involved in the prilling of urea is
drying. Crystallisation
472
Molecular seives are porous
synthetic zeolites crystals/metal alumino-silicates.
473
Calcium ammonium nitrate (a fertiliser) is dried in a __________ dryer.
rotary
474
A binary mixture of benzene and cyclohexane is separated by
extractive distillation
475
Component A is diffusing in a medium B. The flux NA relative to a stationary point is equal to the flux due to molecular difusion, if
there is equimolar counter diffusion.
476
Cox chart is useful in the design of
distillation column
477
Dew point of an air-water vapor mixture
all
478
Can a cooling tower cool water below the wet bulb temperature of inlet air?
no
479
The solvent used in liquid-liquid extraction should have __________ less than one.
neither
480
The suitable evaporator for concentration of foaming liquids is a __________ evaporator.
long tube
481
The ratio of Murphree plate efficiency to point efficiency is always > 1 in a __________ flow model.
plug
482
Tea percolation employs
leaching
483
Which of the following assumes constant molal vaporisation and overflow?
McCabe-Thiele method
484
Absorption factor, for a fixed degree of absorption from a fixed amount of gas should be
> 1
485
Selectivity of the solvent used in solvent extraction should be
> 1
486
Pick out the wrong statement pertaining to leaching.
Fine solids can not be leached in a Pachuka tank.
487
Wet bulb and dry bulb temperatures becomes identical at __________ percent saturation curve.
100
488
NSc/NPr is called the
Lewis number
489
McCabe-Thiele method
uses molal units for material and energy balance.
490
The film penetration model of mass transfer was enunciated by
Toor and Marchello
491
The most economical range of absorption factor is
1.25 to 2
492
Channelling is most severe
in towers packed with stacked packing.
493
Out of two equilibrium curves, first one lies above the diagonal and the second lies below the diagonal in the x-y plot. It means that separation by distillation is
more readily done in the second case compared to first one.
494
ADDUCTS' and 'CLATHRATES' are used in case of
crystallisation.
495
Adsorption is an unit operation which generally involves __________ systems.
fluid-solid
496
In case of __________ distillation, a solvent is added to alter the relative volatility of the mixture to be separated.
extractive
497
Separation of the isotopes of helium for scientific investigations is done by
thermal diffusion
498
In a binary system, separation is very efficient, when the relative volatility is
> 1
499
Fenske-Underwood equation used for calculating the minimum number of theoretical plates in distillation column is valid for
all
500
The binary diffusivity in gases does not depend upon the
none of these
501
Berl saddle made of carbon cannot be used for
oxidising atmosphere
502
1 kg of a saturated aqueous solution of a highly soluble component A at 60°C is cooled to 25°C. The solubility limits of A are (0.6 kgA/kg water) at 60°C and (0.2 kgA/kg water) at 25°C. The amount in kg of the crystals formed is
0.2
503
During drying of a solid, the critical moisture content increases with
increased thickness of the solid, increased drying rate
504
Priming in a distillation column
is characterised by the presence of foam throughout the space between trays.
505
The commonly used solvent in supercritical extraction is
carbon dioxide.
506
When the liquid over a plate is of uniform concentration, then
Murphree efficiency = point efficiency.
507
In saturated gas, the
vapour is in equilibrium with the liquid at the gas temperature.
508
As per Gilliland's equation, the diffusivity is
all
509
Pick out the wrong statement. a. When the concentration difference for the mass transfer becomes zero at the bottom of the gas absorption tower, then the upper end of the operating line touches the equilibrium curve. b. The average distance between the operating line and equilibrium line is large, when the liquid-gas ratio is also large in case of a counter current gas absorption tower. c. The operating line lies above the equilibrium curve in case of a gas desorber. d. With decrease in the liquid flow rate for a fixed gas flow rate, the slope of the operating line decreases, in case of gas absorption process.
The operating line lies above the equilibrium curve in case of a gas desorber.
510
A mixture of 10% C6H6 vapour in air at 25°C and 750 mm Hg has a dew point of 20°C. Its dew point at 30°C and 700 mm Hg will be around __________ °C.
18.7
511
Which of the following is not fixed by the process requirements, in the design of absorbers?
None of these.
512
If the amount of the steam used in steam distillation is increased, the temperature of distillation
decreases
513
Moisture in a solid exerting an equilibrium vapour pressure equal to that of the pure liquid at the same temperature is called the __________ moisture.
unbound
514
Inside the distillation columns, the
driving force for the liquid flow is its weight.
515
When the psychometric ratio is __________ then the adiabatic saturation temperature and wet bulb temperature becomes equal.
1
516
Desirable value of absorption factor in an absorber is
> 1
517
Refractory bricks are usually dried in a __________ dryer.
tunnel
518
For __________ drying, the effects of velocity, temperature and humidity of the gas and the thickness of the solid are the same.
unsaturated surface, constant rate
519
What is the degree of freedom of an absorption process in which only one component is transferred between phases?
3
520
Sticky material can be dried in a __________ dryer.
tray
521
Langmuir equation is associated with
adsorption
522
During the constant rate period of drying of a solid,
surface evaporation of unbound moisture occurs.
523
At a fixed total pressure, humidity depends only on the
partial pressure of vapour in the mixture.
524
If moisture content of solid on dry basis is X, then the same on wet basis is
X/X+1
525
Flash distillation is
used for multicomponent systems like crude refining.
526
__________ developed the film theory.
Higbie
527
For absorbers, high pressure drop results in
high operating cost.
528
Which of the following parameters remains almost constant during adiabatic saturation of unsaturated air?
Wet bulb temperature
529
Coffee is prepared from coffee beans by leaching with
hot water
530
Gaseous diffusion co-efficient increases with increase in the
temperature
531
With increase in absolute humidity, the dew point of an unsaturated mixture of air and water vapor (at constant pressure and temperature)
increases
532
Pick out the wrong statement. Raoult's law does not apply, when the
component molecules are nonpolar.
533
Water-ethyl alcohal solution can be concentrated (in respect of alcohal concentration) by __________ distillation.
vacuum
534
L/mG is the expression for
absorption factor
535
Extraction of pencillin employs a __________ extraction coloumn.
centrifugal
536
In case of gases, the binary diffusivity is proportional to (where, P = pressure)
1/P
537
When the gas to be dissolved in liquid is a/an __________ then normally co-current adsorber are used.
pure gas
538
Corresponding to Prandtl number in heat transfer, the dimensionless group in mass transfer is the __________ number.
Schmidt
539
If a two phase system is in physical equilibrium; then it means that, the
all
540
McCabe-Thiele method of binary distillation does not assume that the
none of these
541
(NSh/NRe.NSc) is termed in mass transfer operation as the
Stanton number
542
The Hatta number is important in
gas absorption with chemical reaction.
543
When a multistage tray tower uses a minimum reflux ratio, it implies
infinite trays and minimum reboiler heat load.
544
CO2 can be absorbed by
heated charcoal
545
For the same process conditions, the reflux ratio of an unlagged distillation column
increases in winter
546
An ideal tower packing should not
hold up large amount of liquid in the packing.
547
Which of the following is a suitable absorbent for removal of H2S from natural gas?
Monoethanol amine (MEA)
548
Acetone is to be removed from air in an isothermal dilute absorber using pure water as solvent. The incoming air contains 5 mole% of acetone (yin = 0.05). The design equation to be used for obtaining the number of trays (N) of the absorber is, N+2 = 6 log (yin/yout).For 98% recovery of acetone, the number of trays required is/are
9
549
Schimdt number and Lewis number for pure air at atmospheric conditions are respectively
< 1 and ≈ 1
550
Below is given an equilibrium moisture curve of a substance. State which regions represent free moisture and unbound moisture respectively. https://www.indiabix.com/_files/images/chemical-engineering/mass-transfer/292-170-1.png
II, III
551
Molecular diffusion is caused by the
thermal energy of the molecules.
552
At __________ reflux, theoretical number of plates in a distillation coloumn is calculated using Fenske-Underwood equation.
total
553
Separation of a mixture of two gases by absorption in the liquid solvent depends upon the difference in their
solubility
554
Components, having widely different boiling point in a binary mixture, can be separated using __________ distillation.
simple
555
Which of the following equipments is not used in liquid-liquid extraction?
Pachuka tank
556
Pick out the wrong statement. a. Packed towers are preferred for vacuum operation, because the pressure drop through the packing is less and they (packings) also lessen the possibility of tower wall collapse. b. Packed towers are preferred over plate towers for handling corrosive and foamy liquids. c. Diameter of randomly packed tower is normally more than 1.2 metres. d. Due to uneven supply and improper distribution of liquid, problem of channeling, loading & flooding is generally encountered in packed towers.
Diameter of randomly packed tower is normally more than 1.2 metres.
557
Equilibrium-moisture curves of different solids
are different
558
Azeotropism for ethyl alcohol-water system disappears by
decreasing pressure
559
Degree of freedom for leaching and solvent extraction process is
3
560
Diffusion co-efficient generally depends upon the temperature, pressure & the nature of the components of the system. Its dimension is not the same as that of the
mass transfer co-efficient.
561
Equilibrium moisture of a solid is equal to the total moisture minus free moisture. Which of the following substances will have maxi-mum equilibrium moisture?
Bamboo
562
In the absorption of ammonia in water, the main resistance to absorption is by the __________ phase.
gas
563
Drying of refractory is normally carried out in a __________ dryer.
truck/tunnel.
564
The expression, ln(F/W) = https://www.indiabix.com/_files/images/chemical-engineering/mass-transfer/314-454-1.png is
differential distillation equation
565
Heat sensitive materials with very high latent heat of vaporisation may be economically separated using
liquid extraction
566
When the solvent dissolves very little of solute, then
large quantity of solvent is required to extract the solute.
567
An alkaline solution is used to reduce the concentration of carbon dioxide in a stream from 10% to 0.1% by absorption with irreversible chemical reaction. The overall number of transfer units based on gas phase is
4.605
568
HETP is numerically equal to HTU, only when the operating line
and equilibrium lines are parallel.
569
In a distillation operation, what is the effect of the temperature of the reflux stream (given below) on the condenser and reboiler loads ? Reflux conditions: (i) Reflux stream is completely liquid and is at its bubble point. (ii) Reflux stream is below its bubble point.
Both condensor and reboiler loads are higher in case (ii) as compared to case (i).
570
Steady state equimolal counter diffusion occurs in case of
binary phase distillation
571
JD factor for mass transfer is a function of Reynolds number. Mass transfer by molecular diffusion from a single drop to surrounding still air is given by
Nsh = 2
572
The relative saturation of an unsaturated mixture of gas and vapor is independent of the
none of these.
573
The adiabatic saturation curve for a vapour-gas mixture is
slightly concave upward.
574
Pick out the wrong statement. a. Cellulose acetate membranes are used in dialysis process. b. Elutriation process refers to when the soluble material is largely concentrated on the surface of an insoluble solid and is simply washed off by the solvent. c. 'Cascade' means a group of stages interconnected so that various streams flow from one to another. d. Zirconia probe is used for the humidity measurement.
Zirconia probe is used for the humidity measurement.
575
The value of NA/(NA + NB), for steady state equimolal counter diffusion of two gases 'A' and 'B' is
576
Drift in a cooling tower is
the water entrained by the circulating air.
577
With increase in the concentration of the adsorbate, the integral heat of adsorption
decreases.
578
Small dia distillation column can be a
packed column
579
If mass diffusivity in a mixture is equal to the thermal diffusivity, then the Lewis number is
1
580
An air-water vapour mixture has a dry bulb temperature of 60°C and a dew point temperature of 40°C. The total pressure is 101.3 kPa and the vapour pressure of water at 40°C and 60°C are 7.30 kPa and 19.91 kPa respectively.The humidity of air sample expressed as kg of water vapour/kg of dry air is
0.152
581
__________ column is used in gas absorption process.
Packed
582
Nitrobenzene (boiling point = 210.6°C) is steam distilled at 1 atm pressure.Nitrobenzene will distill off __________ °C.
at < 100
583
Pick out the wrong statement. a. With decrease in feed temperature, the number of plates required for binary distillation decreases for a given L/V ratio. b. The extraction per unit of total height for a short packed column is more effective than for a tall column, in case of liquid-liquid extraction. c. Natural draft cooling towers are made of ferro-concrete and its cross-section is wider at the bottom. d. Vanderwall adsorption is also called chemisorption.
Vanderwall adsorption is also called chemisorption.
584
At what value of reflux ratio, number of theoretical plates in a distillation column is minimum?
585
Batch tray dryers suffers from the disadvantage of
high labour cost & low heat economy.
586
In a moderately sized packed absorption tower, channeling (which is most severe with stacked packings) can be minimised by taking the ratio of tower diameter to packing diameter
> 8:1
587
__________ column is preferred to be used, when a high liquid hold up is required in a reactor for gas-liquid reaction.
Bubble
588
The 'shanks system' of leaching (i.e., counter-current multiple contact leaching) is used for
recovery of tannis from the tree barks and woods, leaching sodium nitrate from Chilean nitrate bearing rock.
589
Penetration model (theory) for mass transfer was enunciated by
Higbie
590
Surface renewal model of mass transfer was enunciated by
Danckwerts
591
When the __________ the relative humidity of air decreases, despite an increase in the absolute humidity.
temperature rises
592
For turbulent mass transfer in pipes, the Sherwood number depends on the Reynolds number as
Re^0.83
593
The relative humidity of air decreases in-spite of an increase in the absolute humidity, when the
temperature rises.
594
Unit of molal diffusivity is
gm moles/cm. sec
595
The term "approach" in a cooling tower refers to the difference in the temperature of the
cold water leaving the tower and the wet bulb temperature of the surrounding air.
596
Binary distillation involves the mass transfer by __________ at the gas-liquid interface.
a counter diffusion at an almost equal molar rate
597
In a gas-liquid absorption coloumn, for obtaining the maximum absorption efficiency
both gas as well as liquid streams should be distributed uniformly.
598
Reverse osmosis is also called
ultrafiltration.
599
Which of the following is not a batch drier?
Fluidised bed drier
600
Steam distillation is not recommended to be used, if the
azeotropic mixture is to be separated and the final product is miscible with water.
601
Rayleigh equation applies to __________ distillation.
differential
602
Mass transfer co-efficient 'K' according to penetration theory varies with mass dif-fusivity as
D^0.5
603
Most important factor to be considered in the selection of packings for absorbers is the __________ of packing.
porosity
604
__________ is the separation technique used for desalination of sea water.
Reverse osmosis
605
The relative saturation of a partially saturated mixture of vapour and gas can be increased by __________ of the mixture.
increasing the total pressure, reducing the temperature
606
Danckwerts developed the __________ theory.
surface renewal
607
Molecular distillation is
for heat-sensitive materials, very low pressure distillation
608
Drying of a wet solid under constant drying conditions means the exposure of the wet solid to the air of constant
all
609
Which of the following provides maximum contact surface for a liquid-vapour system?
Packed tower
610
For experimental determination of mass transfer co-efficient by wetted wall tower, the mass transfer area is
known
611
In stripping section of continuous distillation column, the
liquid is enriched with high boiler.
612
Molality is defined as the number of gm moles of solute per __________ of solvent.
Kg
613
__________ is concerned with the adsorption equilibria.
Freundlich equation
614
Fractional solvent extraction
employs two solvents
615
In the layout plan for a vacuum distillation unit, operating at 60 mm Hg, supported by a barometric condenser, the appropriate place for the location of vacuum drum for collecting the distillate will be
at ground level.
616
Raschig ring made of procelain cannot be used for treating concentrated
alkalis
617
H2S present in naphtha reformed gas is removed by absorbing with
ethanolamine
618
During constant rate drying period, vaporisation rate per unit drying surface area
does not change with time,
619
Pick out the wrong statement. a. Mass transfer co-efficient does not account for gase-liquid diffusion. b. Diffusion co-efficient and mass transfer co-efficient are not same in any mass transfer operation. c. Contacting cold vapor-gas mixture with hot liquid exemplifies humidification process. d. Contacting cold liquid with warm vapor-gas mixture exemplifies dehumidification process.
Mass transfer co-efficient does not account for gase-liquid diffusion.
620
In rectifying section of a continuous distillation column, the
vapour is enriched with high boilers.
621
For a fixed number of ideal stages in a distillation column, as the reflux ratio is increased, the difference in composition between the top and bottom product streams
increases
622
According to Chilton-Colburn analogy for mass transfer, NSt.NSc2/3 is equal to
f/2
623
A pure drug is administered as a sphere and as a cube. The amount of drug is the same in the two tablets. Assuming that the shape and size do not influence the mass transfer, the ratio of rate of dissolution in water at t = 0 for the cubic to spherical tablet is
1.24
624
Minimum reflux ratio in a distillation column results in
maximum condenser size.
625
Flooding in a distillation column is detected by a sharp
increase in pressure drop.
626
In extraction, as the temperature increases, the area of hetrogeneity (area covered by binodal curve)
decreases
627
Pick out the wrong statement. a. The mass diffusivity, the thermal diffusivity and the eddy momentum diffusivity are the same for NSc = NPr = 1. b. 1 Nm3 of dry air is lighter than 1Nm3 of humid air. c. The Lewis number of a mixture is unity, when the thermal diffusivity is equal to the mass diffusivity. d. An azeotropic mixture of two liquids has boiling point higher than either of them, when it shows negative deviation from Raoult's Law
1 Nm3 of dry air is lighter than 1Nm3 of humid air.
628
In case of an unsaturated mixture of gas and vapor, the percentage saturation is __________ its relative saturation.
lower than
629
At constant pressure, with increase of temperature, the dew point will
increase
630
For a single component absorber, the operating line is straight only when plotted in term of __________ units.
mole ratio
631
In case of unsaturated air
dew point < wet bulb temperature, wet bulb temperature < dry bulb temperature
632
For a binary mixture with low relative volatility,
an azeotrope may be formed during distillation.
633
Plate efficiency
is a function of the mass transfer between liquid and vapour.
634
Absorption accompanied by heat evolution results in
decrease in equilibrium solubility.
635
Even though bubble cap towers are very effective for humidification operation, they are not used commonly in industries, because of the
high pressure drop of the gas.
636
For a distillation column operating at minimum reflux, the
number of plates required will be maximum.
637
A solid is being dried in the linear drying rate regime from moisture content Xo to XF. The drying rate is zero at X = 0 and the critical moisture content is the same as the initial moisture Xo. The drying time for M = (Ls/ARc) is (where, L = total mass of dry solid, A = total surface area for drying Rc = Constant maximum drying rate per unit area X = moisture content (in mass of water/mass of dry solids))
MXo ln(Xo/XF)
638
Flash distillation is suitable for the separation of components
having very wide boiling points.
639
In Mcabe-Thiele method, at infinite reflux ratio
both the operating lines coincide with the diagram.
640
Leaching rate is independent of the
none of these
641
Use of packed towers for distillation is generally limited to the
small sizes.
642
Pick out the wrong statement. a. The binary diffusivity in liquids is of the order of 10-5 cm2 /sec. b. Molecular diffusion in solid is much faster than that in liquids. c. Particles movement from higher concentration to lower concentration takes place in diffusion process. d. According to Poiseuille's law, the permeability decreases with increase in temperature for flow of a gas through a given capillary.
Molecular diffusion in solid is much faster than that in liquids.
643
Which of the following decreases during evaporative cooling process with recirculated water supply?
None of these
644
Laboratory determination of the dif-fusivity of vapor is done by __________ method.
Winkel mann's
645
The minimum liquid rate to be used in an absorber corresponds to an operating line
tangential to the equilibrium curve
646
Unsaturated air (with dry and wet bulb temperatures being 35 and 25°C respectively) is passed through water spray chamber maintained at 35°C. The air will be
humidified
647
For absorbing a sparingly soluble gas in a liquid, the
liquid side coefficient should be increased.
648
A natural draft cooling tower is filled with wooden grids, which covers about __________ percent of the tower height.
45580
649
The boiling points of pure components of a binary system __________ with increase in total pressure of the system.
increases
650
The change in enthalpy, when a unit quantity of gas is absorbed by relatively large quantity of adsorbent (on which a definite concentration of the adsorbed gas already exists) is termed as the
differential heat of adsorption.
651
Penetration theory relates the average mass transfer co-efficient (K) with diffusivity (D) as
K ∝sqrt(D)
652
Desulphurisation of petrol is done in a
rotating disc extractor
653
Chemisorption compared to physical absorption has
increased utilisation of stagnant zones of the liquid phase.
654
Rate of adsorption increases as the
temperature decreases.
655
Pick out the system with maximum boiling azeotrope at 1 atm.
acetone chloroform
656
At 750°K and 1 atm, the approximate value of Schmidt number for air is
0.1
657
Calculation of mass transfer co-efficient is mostly/normally done using __________ theory.
film
658
The velocity, concentration and temperature boundary, for the boundary layer development on a flat plate during connective mass transfer will be same, if
NSc = NPr = NLe
659
For the gas absorption, the height of a transfer unit, based on the gas phase is given by (G: superficial molar gas velocity, L: superficial molar liquid velocity, FG:mass transfer co-efficient, mols/m2 , a: in-terfacial area per unit volume of tower)
G/FG.a
660
Which of the following is used for the concentration of rubber latex?
Agitated film evaporator
661
As the reflux ratio, in a continuous counter-current extraction is increased, the number of stages
decrease
662
In triangular co-ordinates, the ternery composition point falls __________ of the triangle.
inside
663
In a single stage extraction process, 10 kg of pure solvent S (containing no solute A) is mixed with 30 kg of feed F containing A at a mass fraction xf = 0.2. The mixture splits into an extract phase E and a raf-finate phase R containing A at xB = 0.5 and xR = 0.05 respectively. The total mass of the extract phase is (in Kg)
8.89
664
Penetration theory states that the mass transfer co-coefficient is equal to (where, De is diffusivity and 't' is time)
(4De/πt)^1/2
665
Reboiler is considered as one theoretical plate, because
of the assumption that vapour and liquid leaving the reboiler are in equilibrium.