Mass Spectrometer Flashcards
What is mass spectrometer
Where it separates atoms/ions according to their mass
Stage 1
Stage 1: Ionisation
The atom or molecule is ionised by knocking one or more electrons off to give a positive ion.
stage 2
Stage 2: Acceleration
The ions are accelerated so that they all have the same kinetic energy.
stage 3
Stage 3: Deflection
The ions are then deflected by a magnetic field according to their masses. The lighter they are, the more they are deflected.
The amount of deflection also depends on the number of positive charges on the ion
stage 4
Stage 4: Detection
The beam of ions passing through the machine is detected electrically.
Why does it need a vacuum
It’s important that the ions produced in the Ionisation chamber have a free run through the machine without hitting air molecules.
What is ionisation energy
Ionisation energy is the energy required to remove one mole of electrons from one mole of gaseous atoms or ions of an element. endothermic reaction
What is atomic energy levels
Atomic energy levels are the energies of electrons in atoms
Sheilding
is an effect of inner electrons which reduces the pull of the nucleus on the electrons in the outer shell of an atom
Factors that affect ionisation energy
- Charge of the nucleus
- distance of the electron from the nucleus
- the number of electrons in an atom
- whether the electrons are paired up