Manufacturing With Metals Flashcards
Why is the surface quality an important consideration for a manufacturing process?
Most failure begins at the surface of the component
List two ways a surface can be altered after manufacture.
Coating (corrosion/wear-resistant surfaces)
Altering surface structure (shot peening, carburising/nitriding etc)
What types of coatings can be applied to a surface after manufacture?
Corrosion resistant - paint, varnishes, metal (electrochemical - galvanising)
Wear resistant - CVD, PVD
How can the surface quality of a component be changed after manufacture?
Physically - shot peening
Chemically - carburising/nitriding (case hardening with residual compressive stress, improves fatigue/wear resistance)
How is surface roughness defined?
Ra, the sum of areas above and below the mean line divided by the length of the measured profile (L)
What are the two classifications of shape?
2D (continuous) - profile is constant across the length of the object (pipe, rod etc)
3D - everything else.
How is a hollow object defined?
Has significant cavities (bowls, containers etc)
How is a solid object defined?
No significant cavities
What are the six measures of process performance?
Cycle time - time to process one item
Quality - surface condition, dimensional accuracy, integrity (pores, voids), undesired anisotropy
Reliability - reproducibility or consistency
Flexibility - adaptable for more than one part
Material Utilisation - wastage
Operating costs - capital, tooling, labour, setup, running
Briefly summarise how a manufacturing process is selected.
1) Filter out process that cannot produce shape/process right materials
2) Find best using performance ratings
3) Subtract 3 from Process Performance Ratings, Combined Score = SUM(weightings) x (PPR-3)
4) Select process with highest CS
Briefly define casting
Material flows into a mould
Heat is transferred from the mould and the material solidifies in the shape of the mould
Solid product is removed from mould
What mould material is used to cast a metal with a low melting point?
A high melting point metal (called a die)
What material is used to cast a high melting point metal?
Ceramic moulds.
Tend to be expendable, remade for each cast
What are the key mould design considerations for casting?
Casting material
Component size
Component shape (complex shapes require mould made of several pieces, hollow components need core)
Quality
Quantity
What are the two basic classifications of casting processes?
Permanent Pattern
Permanent Mould
What are the two main types of permanent pattern casting?
Sand casting
Shell moulding
Briefly describe the sand casting process
1) Sand packed around moulding board (pattern)
2) Moulding board removes, leaving mould (drag)
3) If hollow, a core is inserted. Cope is fitted to the drag
4) Molten metal poured into sprue
5) When cooled, mould and core shaken off
6) Excess material (in sprue/risers) removed
In sand casting, where is the sprue and riser system?
In the cope
What is the sand mould made of?
Ceramic material with a binder
How can the sand mould be cured?
Thermosetting resin where reactants are combined and curing begins
Curing by heating (heat cured binder system)
Curing by passing a catalyst gas through the mixture (cold box)
Describe in more detail the heat-cured binder system
Liquid thermosetting binder and catalyst mixed with dry sand
When heated, catalyst releases acid that induced rapid cure
Pattern is removed
Mould post cured in an oven
What are the general advantages of sand casting?
Low cost mould material
Can cast high melting point alloys
Wide range of component sizes
Economical for low and large numbers of components
What are the general disadvantages of sand casting?
Poor dimensional accuracy/surface texture
Sand easily deforms
Final accuracy/surface finish achieved with machining after casting
Labour intensive
Slow
List the ways in which sand casting can be improved
Use a precision metallic pattern
Use fine sands or coatings to improve surface finish
Use thermally stable sand (Zircon, ZiSiO4)
How does shell moulding differ from sand casting?
Mould is a thin walled shell, not a cavity in a block
Shells are permeable to air
Briefly describe the process to manufacture using shell moulding
1) Pattern made
2) Pattern sprayed with parting agent, heated and placed into dump box
3) Sand/resin mixture dropped onto heated pattern. Resin next to mould cures, leaving a shell
4) Excess sand tipped away
5) Shell removed
6) Shell halves combined to make full mould
7) Mould placed in mould box packed with pellets to support it
8) Molten metal poured into mould and left to cool
9) Pellets removed and casting removed
What are the general advantages to shell casting?
Higher repeatability
Allows for intricate details
Less machining post casting
Uses less sand
What is ‘permanent pattern’ casting?
Pattern of final product used to make many expendable moulds
Mould destroyed after each casting
What is ‘permanent mould’ casting?
Same mould used to make large number of products
Mould opens to release component rather than by being destroyed
What is gravity die casting?
Gravity causes flow of molten liquid to enter cast iron or tool steel mould
What characteristics does a gravity die mould have?
Vertical split through die cavity
Running, feeding, venting systems in same plane
Die has locating pins, clamps and ejection systems built in
May need cores for hollow parts
May need to be made of several parts for more complex geometry
Briefly describe the gravity die casting process
1) Die preheated to 300-400 degrees (maintained)
2) Die coated with a dressing/lubricant
3) Molten metal slowly poured to prevent turbulence
4) Component must be ejected as soon as possible to allow cooling contraction
What are the general advantages of gravity die casting?
Close dimensional tolerances
Superior surface finish (compared to sand casting)
Faster cooling rates leads to finer microstructure and improved mechanical properties (highly conductive die)
What are the general disadvantages of gravity die casting?
Low melting point alloys only
High tooling costs
Limitation on shape
Coatings necessary
What generic components is gravity die casting best suited for?
High production volume
Uniform wall thickness
Limited undercuts/internal coring
Generally describe pressure die casting
Metal injected into die at high velocity
Solidifies under externally applied pressure
Short filling times
Complex, thin-walled castings can be solidified quickly
What types of pressure die casting are available?
Hot chamber
Cold chamber
Briefly describe hot chamber pressure die casting
Reservoir of molten metal held above melting point
Metal injected through gooseneck into die by piston
New shot of metal pulled into cylinder when piston withdraws
Minimal exposure to air, turbulence and heat losses
Piston does contact molten metal so could lead to contamination
What types of alloy are generally used for hot chamber pressure die casting?
Zinc
Magnesium
Briefly describe cold chamber pressure die casting
Molten metal held in a holding furnace
Metal loaded into chamber via an aperture
Piston forces metal into die at high pressure
Operation completed in a few seconds, minimising contamination problems
Lower metal temperatures allowed by higher pressures
Dies sprayed with lubricant
What are the general advantages of pressure die casting?
High precision from die rigidity
Smooth surface finish
Can cast thin and intricate features
Suitable for components with high surface area/volume ratio
High production rate with automation
Economical for large quantities
Describe the general disadvantages of pressure die casting
Size of casting limited by available pressure
Limited to low melting point metals
Very expensive tooling
Long lead times (need to make die)
Turbulent filling causes internal porosity
Castings cannot be further machined (would remove non-porous skin)
Subsequent heat treatment would cause distortion (expanding gas bubbles)
Lack of pressure tightness from porosity
Briefly explain the lost wax pattern process
1) Pattern made from low melting point material (any cores located before wax injection)
2) Separate patterns may be arranged into a cluster around a gating/feeding system, creating a wax tree
3) Mould is built around the pattern with slurries or liquid refractories. Multiple coats applied
4) Mould hardens
5) Pattern is melted and removed (may be some stressed from differential thermal expansion)
6) Mould fired and metal poured in
7) Mould destroyed to remove casting
What are the general advantages of the lost wax process?
Allows great complexity
Can use any castable alloy
Close tolerances
Jointless mould (reduced machining cost)
Inexpensive mould
Can prototype
Reliable
What are the general disadvantages of the lost wax process?
Long production cycle
Single use mould
What sort of defects can exist in castings?
Porosity (bubbles)
Inclusions
What is homogenous nucleation?
When the equilibrium melting/freezing point is reached, some atoms momentarily cluster into embryos
Embryo will grow if its critical radius is greater than r* (at this point it is energetically favourable to grow)
Need undercooling of 20-30% of Tm
What is undercooling and why is it necessary?
When the melt is cooled below the melting point to initialise solidification
When solidification occurs, latent heat is released which causes a temperature rise , thus reducing the likelihood of solidification
What is heterogenous nucleation?
Instead of a spherical embryo freely floating in the melt, solidification begins at a solid boundary (on a catalyst or other surface) and forms a cap with the same critical radius r*
Why is heterogenous nucleation more likely to occur than homogenous nucleation?
Fewer atoms are required to form a cap and less undercooling is required (only a few degrees)
What makes a good nucleating agent?
The smaller the contact angle of the nucleating cap, the better the nucleating agent (fewer atoms required)
A good nucleating agent has a small interfacial energy between catalyst and nucleating solid.
How is a low interfacial energy between catalyst and nucleating solid achieved?
The nucleating agent has at least one crystal dimension similar to that of the solid being nucleated. (eg TiB2 used to nucleate Al castings)
Why is the nature of nucleation important for casting?
Affects grain size/shape that influence the mechanical properties of the casting
How does porosity arise in castings?
Evolution of dissolved gases (microporosity)
Inadequate liquid supply to compensate for contraction (macroporosity)
In more detail, describe how microporosity arises in castings
From air trapped in the metal when poured
Chemical reactions
Thermal dissociation of water vapour (leads to hydrogen absorption and embrittlement)
Why is it important to prevent gases being in a melt?
When the metal solidifies, gas solubility drops significantly, promoting gas evolution
How can microporosity be prevented when casting?
Venting and minimising turbulence to prevent air being trapped
Minimise moisture levels
Degassing (flushing with insoluble gas or vacuum degassing)
Make pore nucleating more difficult
When nucleating gas bubbles, which type of nucleation is more likely?
Heterogenous
What are good gas nucleating sites in a casting?
Poorly wetted inclusions
Is undercooling necessary for solidification?
Yes, the greater the undercooling, the faster the rate of solidification
How can undercooling be controlled?
By the rate at which latent heat of solidification is removed
Briefly describe the cooling process for a PURE metal
Temperature at solid-liquid interface is lower than the bulk of the liquid (heat removed through the mould)
Nucleation begins at the mould wall
Positive temperature gradient develops into liquid
A planar solidification front is stable with a positive temperature gradient and growth progresses
Why is a planar growth front stable with a positive temperature gradient?
Any instabilities the protrude into the liquid are advancing into a higher temperature region, so the growth rate at that location slows, allowing the rest of the growth front to catch up
Why is the growth front generally unstable in single phase alloys?
As nucleation occurs, the lower melting point constituent of the alloy is rejected into the melt, thus concentration of the melt changes.
This affects the liquid freezing temperature, increasing it above the melt temperature.
As a consequence, constitutional undercooling occurs and there is a negative temperature gradient.
Any disturbances in the growth front will grow faster due to this negative gradient.
Dendritic structures grow favourably in these conditions
What type of interface is formed with a high, positive temperature gradient?
Stable, planar interface
What effect does decreasing the temperature gradient have on the planar stability of the growth front?
Decreasing Gl increases undercooling, decreasing stability
What sort of structure results from a small amount of undercooling?
Cellular; small instabilities may form primary stems in a parallel array
What type of structure is formed with a high level of undercooling?
Dendritic; high instability of the growth front allows any disturbance to rapidly grow
What conditions are likely to cause constitutional undercooling?
High solidification rate (less time for diffusion to reduce concentration profile)
Low temperature gradient
Steep liquidus line, m, and lo value of distribution coefficient
High constitution of secondary alloying element
Explain the problems caused by dendritic growth
Generally leads to porosity
Very small interdendritic channels are difficult to feed during solidification shrinkage, high stress concentrations
Cause solidification cracking (hot tears)
Dendrites begin to interfere with each other at vf = 50%, causes higher melt viscosity (harder to fill mould)
What is the freezing range of alloys?
Range of temperature over which the metal fully solidifies (difference in temperature between solidus and liquidus line)
What problems are associated with a longer freezing range?
Alloys with a longer freezing range are more susceptible to constitutional undercooling
Have a longer semi-solid region, more prone to dendritic growth
More likely to have shrinkage porosity/cracking
Give some examples of popular, short freezing range alloys
Zn-4%Al
Al-11%Si
Cast Irons
What is microsegregation in castings?
In alloy systems with constitutional undercooling and dendritic growth, last liquid to solidify is in the interdendritic region.
High conc of lower melting point alloy
Inclusions are swept into these regions by the solidification front
Microsegregation is this varying composition between dendrites
What controls the grain size in a casting?
Number of nucleation sites
What controls the scale of dendritic growth in castings?
Solidification rate
What two features of a dendritic structure form barriers to dislocation motion?
Secondary phases in the interdendritic region
Grain boundaries
What effect on the dendrite structure does increasing the solidification rate have?
Secondary dendrite arm spacing is reduced
What effect on mechanical properties does increasing the rate of solidification have?
Increases mechanical properties
May also increase porosity
How is the rate of solidification increased?
By removing excess heat from the melt and latent heat of solidification
What thermal resistances exist in a typical casting?
In liquid
In Solid
Solid/mould interface (air gap maybe)
In mould
At mould/environment interface
What problems arise from gravity pouring into a mould to cast?
Turbulent flow (air entrapment)
Impurities (oxides forming, erosion damage to mould)
How can turbulent flow be avoided in casting?
Well designed running/gating systems
Introduce liquid at lowest point in casting (liquid slowly rises through mould)
Tapered sprue prevents liquid pulling away from sides
How can inclusions be avoided when casting?
Dross trap catches first metal entering mould (contains most oxides)
Avoid melt contact with air
Describe the Cosworth Process
Bottom filled Zircon sand mould
Vertical fill tube in middle of holding furnace only feeds cleanest metal at a controlled rate
Reduced turbulence, minimal inclusions
What benefits does Zircon sand offer compared to Silica sand?
Better thermal stability, so better dimensional accuracy
Better conductivity, so faster solidification, finer microstructure
What is grey cast iron?
Iron with a graphitic microstructure
On cooling, graphite precipitates
What affects the porosity of grey cast iron?
Grey cast iron expands on solidification, reducing porosity
What effect on the mechanical properties of grey cast iron does the graphite have?
Graphite in flake form
Internal stress raisers make the structure brittle
How can grey cast iron be made tougher?
Add magnesium
Forms nodular graphite (or spheroidal graphite, SG cast iron)
What function do feeder heads perform in casting?
Provide reservoir of molten material to compensate for solidification shrinkage
What causes macroporosity?
Large cavities in the casting as a result of insufficient feeding
What is meant by directional solidification?
Getting the casting to solidify first at the furthest point from the feeder head and the progress closer to the head
What is Huevers construction?
Circles inscribed on casting section must increase in diameter in direction of the feeder head
Briefly describe forming?
Shaping materials in the solid state by plastic deformation
What are “bulk” workpieces?
Objects with small surface area to volume ratio
How are bulk workpieces usually deformed in forming processes?
Triaxial compressive loading
For cold temperature forming, describe the mechanism that causes an increase in yield stress with plastic strain
Work-hardening
Dislocation density increases with the plastic strain, thus increasing the yield stress
How can the effects of work-hardening be reversed?
Annealing
Describe the annealing process, including relevant stages and temperatures
At 0.3-0.5Tm, recovery occurs; some strain fields annihilate each other and some rearrange into low angle boundaries. Ductility increases and yield stress decreases
0.5Tm and above, recrystallisation occurs; new, relatively dislocation free grains nucleate and grow from the old grains. Mechanical properties return to pre work-hardened state
At even higher temperatures or longer times, grain growth occurs; increased strength and ductility of metal. Poor surface finish from orange peel effect
What effect does increasing temperature have on the mechanical properties of most metals?
Increases ductility
Increases toughness
Lowers E
Lowers yield stress
Lowers tensile strength
Decreases strain hardening exponent
While increasing the temperature may mean lower forming forces are required, what is the main disadvantage?
Oxidation of the workpiece increases
Why are softening processes (recovery, recrystallisation and grain growth) time and temperature dependant?
They rely on diffusion
What effect on mechanical properties does a higher strain rate during forming have?
Increased yield stress, due to not enough time for diffusion to redistribute stresses
What is forging?
Workpiece deformed plastically using compressive forces
Describe open die forging
Solid, cylindrical workpiece is compressed between two platens (upsetting)
What is the “friction hill” in forging?
The distribution of forging pressure across the width of the billet. Highest in the centre and decreases towards the edges. Due to there being less material to push outwards the further from the centre you go
How can the upsetting force be calculated for forging?
Integrating the area under the tooling pressure curve (friction hill)
Why is forging pressure higher with friction compared to without friction?
Horizontal displacement means work is done to overcome the frictional resistances
What is the main consequence of sticking friction?
Barrelling
What is barrelling?
Non uniform horizontal displacement of the workpiece