Main group elements Flashcards

1
Q

Alkali metals 5 properties

A
  • Excellent reducing agents
  • Weak metallic bonding due to distance of valence electron from nucleus
  • unusually soft and can be cut with a knife
  • lower density than most metals
  • they form superoxides at larger atomic size
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2
Q

How do Alkali metals react with water

A

2M(s) +H2O—> 2M (aq) + 2OH- + H2(g)

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3
Q

Properties of alkaline earth metals

A
  • basic solutions
  • melt at extremely high temperatures
  • Strong reducing agents
  • very reactive
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4
Q

How do alkaline earth metals react with water?

A

they reduce water to form H2 gas

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5
Q

Boron family properties

A

All boron compounds are covalent!! Also something about hydride bridge bond

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6
Q

Pnictogens

A

-group 15

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7
Q

Nitrogen properties

A

a diatomic gas with a very low boiling point due to weak intermolecular forces

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8
Q

Phosphorous properties

A

exists mostly as a tetrahedral P4 molecule. Has stronger dispersion forces than N2, thus slightly higher boiling point

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9
Q

What are allotropes???

A

different crystalline or molecular forms of the same element

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10
Q

Chalcogens??? WHAT ARE THOOOSE

A

group 16 elements

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11
Q

Chalcogen properties????

A
  • Halides are formed by direct combination of a halogen and a chalcogen
  • Oxygen forms two hydrides: Water and hydrogen peroxide.
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12
Q

Halogen properties

A
  • Very reactive
  • oxidizing agents
  • display a wide range of electronegativities, but all behave as nonmetals
  • A halogen will either gain one electron to form a halide anion or share an electron pair with a non metal atom
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13
Q

What happens to halogens in water?

A

They undergo disproportionation (-> HX+ HXO)

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14
Q

What happens to halogens in an acqueous base?

A
  • form hypophalites at lower temperatures and halates at higher temperatures
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15
Q

What is the primary valence of a coordination compound

A

between complex and counter ions

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16
Q

What is the secondary valence of a coordination compound??

A

between metal center and ligands

17
Q

name the order of ligands from strongest to weakest field

A

CN-> NO2-> en> py~NH3> EDTA4-> SCN-> H2O >ONO-> ox2-> OH-> F-> SCN-> Cl-> Br-> I-

18
Q

Ionization Isomerism

A

switch counter ion/ligand

19
Q

Coordination Isomerism

A

swithc ligand on a metal center

20
Q

Linkage Isomerism

A

switch atom through which binding occurs

21
Q

Geometric Isomerism

A

different spatial arrangment about the metal atoms (Cis trans) occurs when MA2B2 and MA2B4

22
Q

Trend in ionization energy

A

increases across a period and up a group

23
Q

Trend in Metallic character

A

increases going down a group and to the left of a period

24
Q

Trend in Electron affinity

A

increases across a period and up a group

25
Q

Trend in atomic radius

A

increases down a group and to the left of a period

- not applicable for transition elements