Macromolecules Flashcards
What are the four types of macromolecules?
Lipids
Proteins
Nucleic Acids
Carbohydrates
What are macromolecules?
Polymers made up of covalently-bonded monomers
What is a dehydration reaction?
Removal of water to form new bonds (shorter polymer bonds to a monomer to form a longer polymer)
What enzyme catalyzes dehydration?
Polymerase
What is hydrolysis?
Adding water to break down bonds into smaller polymers or monomers
What enzyme catalyzes hydrolysis?
Hydrolase
What are the 1. Monomer 2. Polymer 3. Covelant Bond of a Carbohydrate?
- Monosaccharide
- Polysaccharide
- Glycosidic Linkage
What are the 1. Monomer 2. Polymer 3. Covelant Bond of a Proteins?
- Amino Acids
- Polypeptides
- Peptide Bond
What are the 1. Monomer 2. Polymer 3. Covelant Bond of a Nucleic Acids?
- Nucleotides
- (Poly) Nucleic Acids
- Phosphodiester Linkage
What are the 1. Monomer 2. Polymer 3. Covelant Bond of a Lipids? *Are lipids true polymers?
- Fatty acids and Glycerol
- Fats, Steroids, and Phospholipids
- Ester Linkage
* Not true polymers
What is another name for monosaccharide?
Simple Sugar
What is the general makeup of the chemical formula for monosaccharides?
CH2O
What is the most common form of monosaccaride?
Glucose
What are the two factors that help classify monosaccharides?
- The location of the carbonyl group {C = O with two single bonds to other atoms} (determines if it is aldose or ketose)
- The number of carbons in the carbon skeleton
What is a carbonyl group?
Carbon double bond to oxygen with two other single bonds
What is pentoses?
Five- carbon sugars
What is hexoses?
six- carbon sugars
Monosaccarides (glucose) are found in what kind of structure?
Ring form (Most stable)
What is the function of monosaccarides?
Energy/Fuel for cells
What are disaccharides?
Joining of two monsaccarides
What is the covelent bond found in carbohydrates?
Glycosidic Linkage
What are the three forms of disaccharides?
Sucrose (table sugar), Lactose (milk), Maltose (beer)
What is the linkage between disaccharides?
1-4 glycosidic linkage
What are polysaccharides?
Multiple ( >2) monosaccarides
What is the function of polysaccharides?
Storage and Structure
What are the most common forms of polysaccharides?
Starch, Cellulose, and Glycogen
Where is starch stored?
Plants
What is the monomer of starch?
Glucose
Where is the surplus of starch stored?
Granules in plants
What is the simplist form of starch?
Amylose
What is the linkage of starch molecules?
1-4 linkage; branches at 1-6 linkages
What is the name of the form of starch created by the 1-6 linkage?
Amylopectin (somewhat branches)
Where is glycogen stored?
Animals
What is the monomer of glycogen?
Glucose
Where is glycogen mainly stored?
Liver and muscle cells
What process breaks down glycogen when glucose in needed in the body?
Hydrolysis
What is the linkage in glycogen molecules?
1-4 linkage; branches at 1-6 linkages
What is the name of the form of glycogen created by the 1-6 linkage?
Glycogen (extensivley branched)
Where can cellulose be found?
Plant cell walls
What is the monomer for cellulose?
Glucose
What is the linkage for cellulose?
1-4 linkages ONLY
What is the ring form for cellulose?
Beta glucose ring structure
What is the ring form for starch?
Alpha glucose ring structure
Cellulose is known as ________ __________ becasue hydrolyses can not hydrolyze beta linkages in cellulose.
Insoluble fibers
Why are lipids condsidered macromolecules even though they are not true polymers?
- Have monomeric like covalent bonds
2. Unifying feature (hydrophobic)
What do lipids mainly consist of that makes them hydrophobic?
Hydrocarbon regions
What are the three categories of lipids?
- Fats
- Phospholipids
- Steriods
Steroids consist of a carbon skeleton with _____ fused rings.
4
What is the role of cholesterol?
- Component in animal cell membranes
2. Precursor for other steroids
All steroids have a ______ _______ in its sturctural makeup
Cholesterol Chain
What can high cholesterol in blood lead to?
Cardiovascular disease
What is the good form of cholesterol? Why?
HDL (High Density Lipoprotein)
Removes cholesterol from the blood and brings it to the liver to be metabolized
What is the bad form of cholesterol? Why
LDL (Low Density Lipoprotein)
Takes cholesterol from the liver and moves in through the blood
What is the major function of fats?
Energy Storage
Where are fats stored?
Adipose tissue
What is the role of adipose tissue?
Cushions vital organs and insulates the body
Fat molecules are known as what?
Triacylglycerol
What makes up fat?
Glycerol and Fatty Acids
What is glycerol?
3C alcohol with hydroxyl group attached to each C
What is fatty acid?
Carboxyl group attached to a long carbon skeleton
What is the name of the linkage between glyerol and fatty acid?
Ester Linkage
Fatty acids with no double bonds are known as what?
Saturated Fat
Fatty acids with one or more double bonds are known as what?
Unsaturated Fat
True of False… Saturated fats are liquid at room temperature.
FALSE
Saturated fats have the (minimum/maximum) number of H atoms possible.
Maximum
True or False… Unsaturated fats are liquid at room temperature.
TRUE
Unsaturated fats have a double bond known as ____ which makes the moleucular structure bend.
Cis
Does unsaturated fat have the maximum number of H atoms?
No, this allows for the double bond to form
What is the difference between monounsaturated fats and polyunsaturated fats?
Mono= 1 double bond Poly= 2 or more double bonds
Diets rich in ______ fats contribute to cardiovascular disease?
Saturated
It is recommended to reduce total dietary fat to ___ and reduce saturated fat to ______ of total calories.
30%
10%
What are trans fats?
Synthetic fats
What is hydrogenation?
Converts unsaturated fats to saturated fats by adding hydrogen
Trans fats remove what from unsaturated fats?
Cis (Double bond) bend
Where can you find phospholipids?
Outer membrane of cells
What does it mean if something is hydrophilic? What part of the phospholipid is considered this?
Water loving- attracted to water (head of the phospholipid is polar)
What does it mean if something is hydrophobic? What part of the phospholipid is considered this?
Water fearing- repelled by water (Tail of the phospholipid is nonpolar)
What is the assembly of phospholipids in the cell membrane?
Phospholipid bilayer
What is the function of phospholipids?
Structure (create a semi-permeable barrier)