M3 Flashcards
This is the larges source of energy all over the world
Coal
Petroleum
Natural Gas
Synthetic gas
Coal
Coal can serve a potential source of?
synthetic fuel
coke production
Fine chemicals (now derived from petroleum and natural gas)
Other feedstocks produced from coal are?
gasification
to synthesis gas
to oil (Fischer-tropsch)
to methanol
to plastic
It is a carbonaceous solid black or brownish black sedimentary rock matter.
Natural gas
Petroleum
Coal
Synthetic gas
Coal
Coal is mainly composed of what element?
Hydrogen
Natural Gas
Coke
Carbon
Carbon
What are the other elements in coal?
(H) Hydrogen
(O) Oxygen
(N) Nitrogen
(S) Sulphur
Moisture and non-combustible inorganic matter:
(Si) Silica
(Fe) Iron
(Ca) Calcium
(Mg) Magnesium
(Hg) Mercury
How is coal made?
from accumulation of partially decomposed vegetation
What are the factors that affect the deposits of coal?
Biological changes
Temperature
Pressure
The first published record of coal used in Greece is used for?
Cooking
Burning
Heating
Energy source
Heating
Coal is adopted in China as a?
Energy source
Heat source
Transportation
Cooking
Heat source
Why did the Great Britain switches to coal at the start of industrial revolution?
They ran out of wood
Coal provides ________ of world energy source as dependence on petroleum grows.
20%
30%
40%
50%
30%
Empirical formula for Bituminous coal.
C240H90O4NS
C137H97O9NS
C137H97O9NS
Empirical Formula for a High grade anthracite
C240H90O4NS
C137H97O9NS
C240H90O4NS
Coal is a 3D cross-linked ___________ and_____ with a small amount of _______
Polymer (Aromatic rings)
Alkane Linkers
Inorganic contanimants
Coal is divided into 4 ranks:
- Anthracite
- Bituminous
- Sub-bituminous
- Lignite
The inorganic constituents in coal are from?
Original plant materials
Minerals leached from surrounding sediments
What are the Inorganic constituents in coal?
Na, Ca, Mg, K salts
Al, Si, Fe, S oxides
Coal also contains small amounts of ___ and ____ which are important for modern electronics industry
Ni, Ne
Ga, Ge
Fe, K
Au, Ag
Ga, Ge
Unlike petroleum, coal can’t be separated into individual products. It must be:
reformed into smaller FW materials (Synthetic fuels)
Combusted (for heat)
Great pressure from the environment creates what type of coal?
Anthracite
Bituminous
Sub-bituminous
Lignite
Bituminous coal
Bituminous coal are also called
Soft Coal
Hard Coal
Brown Coal
Soft coal
The heating value of this coal is higher than Lignite and sub-bituminous, but less than anthracite
Sub-bituminous
Lignite
Bituminous
Bituminous coal
Bituminous coal is commonly used for?
Heating
Cooking
Energy Power Generation
Electric Power generation
Electric power generation
Where is Bituminous coal usually mine?
Midwest and Appalachia
This type of coal is often called Hard coal.
Bituminous
Sub-bituminous
Anthracite
Lignite
Anthracite
How is Anthracite formed?
from Bituminous coal when great pressure developed in limited geographic areas
Where do Anthracite usually forms?
Appalachian region of Pennsylvania
This type of coal has the highest energy content of all coals.
Bituminous
Sub-bituminous
Anthracite
Lignite
Anthracite
Due to it having the highest energy content, this type of coal is used for making coke which is used as a fuel for?
Steel foundry ovens
This type of coal is a dense, hard rock with jet-black color and metallic luster.
Bituminous
Sub-bituminous
Anthracite
Lignite
Anthracite
This type of coal contains between 86% and 98% carbon by weight.
Bituminous
Anthracite
Sub-bituminous
Lignite
Anthracite
This type of coal burns slowly, with a pale blue flame and very little smoke
Bituminous
Sub-bituminous
Anthracite
Lignite
Anthracite
This type of coal contains between 69% and 86% carbon by weight
Bituminous
Sub-bituminous
Anthracite
Lignite
Bituminous coal
This type of coal contains less carbon, more water and is less efficient source of heat
Bituminous
Sub-bituminous
Anthracite
Lignite
Sub-bituminous
This type of coal is also called brown coal.
Bituminous
Sub-bituminous
Anthracite
Lignite
Lignite
This type of coal is a very soft coal that contains up to 70% water by weight. Emits more pollution then other coals
Bituminous
Sub-bituminous
Anthracite
Lignite
Lignite
This coal component consists of aliphatic carbon atoms or aromatic hydrocarbons and mineral matter
Ash
Volatile Matter
Moisture
Carbon Content
Volatile matter
This coal component consists of inorganic matter from the earth’s crust: limestone, iron, aluminum, clay, silica, and trace elements
Ash
Volatile Matter
Moisture
Carbon Content
Ash
Each type of coal have a set of parameters which are mostly controlled by:
Moisture
Volatile content
Carbon content
Designating a group of organic chemical compounds (carbon compounds) where carbon atoms are linked in open chains
Aromatic
Aliphatic
Hydrocarbon
Aliphatic
Containing one or more six-carbon rings characteristic of benzene series
Aromatic
Aliphatic
Hydrocarbon
Aromatic
Numerous organic compounds, like benzene and methane, that only have carbon and hydrogen
Aromatic
Aliphatic
Hydrocarbon
Hydrocarbon
Carbon forms more than _______ by weight, and more than ______ by volume of coal
40%, 80%
80%, 60%
50%, 70%
55%, 65%
50%
70%
The higher the rank of the coal the _____ the hydrogen, oxygen and nitrogen until 95% purity of carbon is achieved
Less
Formed from coal. This is the end product of the thermal and diagenetic conversion of plant matter into pure carbon
Ash
Volatile Matter
Moisture
Graphite
Graphite
It is a process of chemical & physical change in deposited sediment during its conversion to rock
Diagenetic Conversion
Volatile Matter
Moisture
Carbon Content
Diagenetic conversion
It is a material that’s driven off when coal is heated to 950degC in the absence of air under specified conditions
Diagenetic Conversion
Volatile Matter
Moisture
Carbon Content
Volatile matter
This consist of a mixture of gases, low-boiling point organic compounds that condense into oils upon cooling, and tars
Diagenetic Conversion
Volatile Matter
Moisture
Carbon Content
Volatile matter
As the rank of the coal increases, volatile matter ___
decreases
Range of class of volatile matter
102-900
101-902
103-905
100-900
101-902
The class of volatile matter of Anthracites is?
101
301
902
601
101
The class of volatile matter of prime cooking coals is?
101
301
902
601
301
The class of volatile matter of non-coking coals is?
101
301
902
601
902
What are the two forms of sulfur in coal?
Pyritic Sulfur (sulfur is linked with iron)
Organic sulfur ( Chemically bound to carbon atoms)
Coal types can also be classified according to its organic debris called?
Ash
Macerals
Graphite
Macerals
What are macerals?
a microscopic organic constituents found in coal
How are macerals identified?
Microscopically by reflected light
What is the purpose of classifying coal according to the macerals?
To determine its best uses.
The degree of _________ or _______ undergone by a coal has an important bearing on its physical and chemical properties and is referred to as the rank of the coal.
Metamorphism
Coalification
high moisture content, volatile matter, hydrogen, oxygen, nitrogen is the criteria of __________ coal
Low rank
The _______ is measured by determining the loss of weight of the heated coal
Diagenetic Conversion
Volatile Matter
Moisture
Carbon Content
Volatile matter
Moisture content ( ranges from 1-40%) increases as the rank of coal ______
decreases
This is the carbon found in the material after the volatile materials are driven off
Diagenetic Conversion
Volatile Matter
Moisture
Fixed Carbon
Fixed carbon
This value measured in Btu is the amount of chemical energy stored in a coal that’s release as thermal energy in combustion.
Diagenetic Conversion
Volatile Matter
Calorific Value
Fixed Carbon
Calorific value
As the rank of coal increases, the calorific value _______
Increases
This is a type of maceral.
Vitrinite
Volatile Matter
Moisture
Fixed Carbon
Vitrinite
This can be used as an indicator of maturity in hydrocarbon source rocks for coal production
Diagenetic Conversion
Volatile Matter
Moisture
Vitrinite reflectance
Vitrinite reflectance
As the rank of coal increases, the Vitrinite reflectance ___________
increases
This type of coal is greater than 25 mm or approximately equal to 1 inch
Small coal
Coarse coal
Fine coal
Ultra fine coal
Coarse coal
The size of this type of coal is 25-3 mm
Small coal
Coarse coal
Fine coal
Ultra fine coal
Small coal
This type of coal is less than 3 mm or .12 inch
Small coal
Coarse coal
Fine coal
Ultra fine coal
Fine coal
This type of coal is less than .15 mm or .006 inch
Small coal
Coarse coal
Fine coal
Ultra fine coal
ultra fine coal
A process where the coal is heated at moderate temperature wherein the thermal decomposition of the organic material releases small amounts of flammable gas
Diagenetic Conversion
Volatile Matter
Coal Carbonization
Vitrinite reflectance
Coal carbonization
Carbonization is carried out at
~ 400degC
The products if carbonization are
O2, coke
N2, H2
CO2, CH4
H2, CH4
H2 and
CH4 (Methane)
What process is used as a large source of Methane (CH4) which was used for lighting in the early 20th century
Diagenetic Conversion
Volatile Matter
Carbonization
Vitrinite reflectance
Carbonization
In coal Coal gasification, the Conversion of coal into methane equation is:
CO + 3H2 > CH4 + H2O + 206.3 kJ
C + 2H2 > CH4 + 74.9 kJ
C + 2H2 > CH4 + 74.9 kJ
What is the reaction equation for the efficient route to methane:
CO + 3H2 > CH4 + H2O + 206.3 kJ
C + 2H2 > CH4 + 74.9 kJ
CO + 3H2 > CH4 + H2O + 206.3 kJ
Refers to a series of physical and chemical changes that occur when coal is heated under an isolated atmosphere or inert atmosphere. used to produce char, tar, and gas.
Diagenetic Conversion
Coal Pyrolysis
Coal Carbonization
Vitrinite reflectance
Coal Pyrolysis
Production of Methanol equation
C + H2O > CO + H2
CO + 2H2 = CH3OH
CO + H2O > CO2 + H2
CO + 2H2 = CH3OH
Feed stock of CO and H2. This equation is also labeled as Steam Reforming
C + H2O > CO + H2
CO + 2H2 = CH3OH
CO + H2O > CO2 + H2
C + H2O > CO + H2
Feed stock of CO and H2. This reaction is also labeled as Water gas shift reaction
C + H2O > CO + H2
CO + 2H2 = CH3OH
CO + H2O > CO2 + H2
CO + H2O > CO2 + H2
In theory, one can convert coal to methane with energy of only
74.9
15.1
206.3
15.1 kJ
This process is done by reacting products of coal gasification to form larger FW hydrocarbon
Diagenetic Conversion
Coal Pyrolysis
Coal Carbonization
Indirect liquefaction
Indirect liquefaction
This process can produce synthetic gasolines but is not yet economically viable
Diagenetic Conversion
Coal Pyrolysis
Coal Carbonization
Indirect liquefaction
Indirect liquidification
Products of gasification of coal
Moisture, Volatile Gases
Carbonized Coal, water
Moisture, Carbonized coal
Carbonized coal, Volatile Gases
Volatile gases
Carbonized coal
Carbonized coal is also called
Carbon dioxide
Coke
Ash
Sludge
Coke
Coal carbonization carried out in low temperature (lower than 750 degC) is commonly used for:
Small-scale industries
Coal carbonization carried out in high temperature produces a major contributor to air pollution which is ________
Coke
Ash
Smoke
Tar
Smoke
These ovens were built in a beehive like hemispherical shape and them covered with earth
Beehive oven
Typical cooking time for coke in oven is
17 Hrs
Coal carbonization also produces a small amount of sticky, black liquid called ____
Coke
Ash
Smoke
Tar
Tar
Tar contain low FW aromatic compounds and is distilled to produce ___, _____, _____,and ___ which are important petrochemicals feedstocks
Benzene
Toluene
Xylene
Corresponding alcohols
______ was, for an extended time, an unwanted by product of oil production
Synthetic Gas
Natural Gas
Blue gas
Natural gas
Hydrocarbon natural gases other than Methane
Ethane
Propane
Butane
Pentane
Non-hydrocarbon components natural gases
Water vapor
Carbon dioxide
Nitrogen
Helium
Hydrogen sulfide
These two Non-hydrocarbon components can corrode pipelines, and are highly toxic and are also significant sources of air pollution
Ne, He
CO2, H2O
CO2, H2S
Ne, H2S
CO2
H2S
Gases with high level of H2S and CO2 are also called ________
Sour Gas
Conventional Gas
Tight Gas
Shale Gas
Sour gases
This refers to resources accumulated in a reservoir in which buoyant forces keep hydrocarbons in place below sealing cap rock
Sour Gas
Conventional Gas
Tight Gas
Shale Gas
Conventional gas
What are the two types of conventional gas reservoir
Isolated (non-associated)
Associated with oil (Freed gas or solution gas)
It is a natural gas trapped in a relatively impermeable reservoir rock like sandstone or limestone formation
Sour Gas
Conventional Gas
Tight Gas
Shale Gas
Tight gas
It is a tight gas processing that involves creating cracks in the rock through which the gas can flow to the wells
Diagenetic Conversion
Hydraulic Fracturing
Coal Carbonization
Vitrinite reflectance
Hydraulic fracturing
It is a fine-grained, fissile, sedimentary rock formed by the consolidation of clay and slit-sized particles into think, relatively impermeable layers
Sour Gas
Conventional Gas
Tight Gas
Shale Gas
Shale gas
In this reservoir, the gas is generated in place, the shale acts as both the source rock and the reservoir
Gas shales
It is generated during the formation of coal and is contained to varying degrees within the coal microstructure.
Monoethanolamine
Coalbed Methane
Liquid Propane
Liquid Butane
Coalbed Methane (CBM)
_____ production is associated with extensive production of water. water must be removed to reduce pressure within the reservoir, making the process complex and costly.
Monoethanolamine
Coalbed Methane
Liquid Propane
Liquid Butane
CBM
What is the schematic of natural gas processing
- Separate oil & condensate
- remove water
- Remove contaminants (CO2,H2S,etc.)
- Extract natural gas liquids
What is the most widely used solvent for gas purification by aliphatic amine absorption process
Monoethanolamine
Coalbed Methane
Liquid Propane
Liquid Butane
Monoethanolamine
It is made by passing air and steam through a bed of hot coal or coke
Producer gas
Water gas
Synthetic Gas
Natural Gas
Producer gas
Producer gas was used primarily as an industrial fuel for:
Iron and steel manufacturing
Mechanical power for gas engines
This is often called blue gas
Producer gas
Water gas
Synthetic Gas
Natural Gas
Water gas
This gas produces blue flame when burned
Producer gas
Water gas
Synthetic Gas
Natural Gas
Water gas
Due to its low heating value, this may be atomized into hot gases to produce _______
Carbureted water gas
Water gas
Synthetic Gas
Natural Gas
Carbureted water gas
It is a carbon monoxide (CO)-Hydrogen (H2)- containing gas mixture.
Producer gas
Water gas
Synthesis Gas
Natural Gas
Synthesis gas (syngas)
Synthesis gas is produced by what process
Gasification Process
oil gasification
Hydraulic Fracturing
Gasification process
Three types of gasifier used in producing syngas
(L, H, E)
Lurgi dry ash gasifier
High temperature Winkler gasifier
Entrained gasifier
Among the three types of gasifier used in producing syngas which one has the highest capacity per unit volume
Lurgi dry ash gasifier
High temperature Winkler gasifier
Entrained gasifier
Entrained gasifier
Gas produced formerly known as synthetic gas are now called ____
Producer gas
Water gas
Synthesis Gas
Substitute Natural Gas
Substitute natural gas
This process used mix naphtha with steam in a 1;2 ratio to gasify the mixture
Gasification Process
oil gasification
Hydraulic Fracturing
Oil gasification
It is a super-pressurized gas stored in a liquid form in tank, canister or bottle
LPG
CBM
Liquid Propane
Liquid Butane
LPG
These two are employed as standby and peak load supplement in systems using natural and manufactured gas
Monoethanolamine
Coalbed Methane
Liquid Propane
Liquid Butane
Liquid propane and butane
What sedimentary deposits is used for producing Potassium
Limestone
Evaporite
Sylvinite
Sylvinite
The Chemical formula for Sylvite is:
KCl
NaCl
KSO4
KO2
KCl
Sylvinite is a mixture of:
Sylvite, Coal
Sylvite, Halite
Halite, Limestone
Halite, Salt
Sylvite, Halite
Chemical Formula of Halite is:
KCl
NaCl
KSO4
KO2
NaCl
Chemical Formula of Langbeinite (another source of potassium):
K2SO4*2MgSO4
NaCO3
NaB4O7
KNO3
K2SO4*2MgSO4
Langbeinite (another source of Potassium) is processed to make:
Potassium Sulfate
Potassium Sulfide
Potassium Chloride
Potassium Sulfate
Sylvinite is mined and processed to produce:
Potassium Sulfate
Potassium Sulfide
Potassium Chloride
Potassium Chloride
Deposits of solid sodium salts permeated by a saturated complex brine is processed to create: