M2 ,, Bonding And Structure Flashcards
Ionic bonding?
The electrostatic forces of attraction between oppositely charged ions formed by electron transfer
Physical properties of ionic compounds?
They have high melting points because there are strong electrostatic attractive forces between the oppositely charged ions in a molecule
When solid it doesn’t conduct electricity because ions are held together tightly in the lattice and cannot move so no charge is conducted
When molten/solution ions are free to move so charge can be carried
Solubility in water is generally good
Structure of ionic lattice?
Ions in ionic solids are arranged in giant ionic lattice
Sticks in diagram help show arrangement of ions, but they do not represent ionic bonds
What’s covalent bonding?
Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms
Dative covalent bonding?
Forms when the shared pair of electrons in the covalent bond come from only one of the bonding atoms, also called a co-ordinate bonding
Covalent bonding structure?
Simple molecular - with induced dipole-dipole, permanent dipole-dipole forces between molecules
Covalent bonding properties?
Bp/Mp is low because of weak intermolecular forces between molecules
Solubility in water is generall poor
Conductivity is low when solid because there’s no ions to conduct and ions are localised
When molten no conductivity cause there’s no ions
Mostly gases and liquids
Linear?
2 bonding pairs, no lone pairs
Bond angle 180*
Trigonal planar?
3 bonding pairs, 0 lone pairs
Bond angle 120*
Tetrahedral?
4 bonding pairs, 0 lone pairs
Bond angle 109.5*
Trigonal pyramidal?
3 bonding pairs, 1 lone pair
Bond angle 107*
Bent?
2 bonding angles, 2 lone pairs
Bond angle is 104*
Octahedral?
6 bonding pairs, 0 lone pairs
90*
Define electronegativity?
It is the relative tendency of an atom in a covalent bond in a molecule to attract electrons in a covalent bond to itself
Electronegativity across a period?
It increases as the number of protons increase and atomic radius decreases because electrons in the same shell are pulled in more