Livestock emissions Flashcards
- Define the terms “emission”, “transmission” and “immission”.
Emission: Release of pollutants from the source to the environment
Transmission: Distribution and conversion of pollutants during the atmospheric transport
Immission: Concentration and deposition of pollutants with impact on the places and creatures exposed
- Sketch/explain the influences on and processes of the formation and release of ammonia, nitrous oxide, methane
Ammonia formation:
(1)
Formation of ammonia is induced by catalytic breakdown of urea (urease)
–> CO(NH2)2 + H20 —> (urease) 2 NH3 + CO2
(2): Ammonia-Ammounium-Equilibrium in liquid
NH3+H2O –> (T,pH) NH4+ + OH-
The lower the temperature and pH the less solved as NH3 and the mote dissociated as NH4+
(3) : release: convection mass transfer from liquid to gasous phase–> Main promoting factors: high temperature, high air velocity, high turbulence of the air stream, size of the emitting surface, replenishment of potential NH3 pool
Nitrous oxide (N20) formation:
- Can be formed due to incomplete oxidation process (02 deficiency) by chemical decomposition of the intermediate hydroxylamine NH2OH within the nitrification process
- N20 is an obligate intermediate within the denitrification process
- also anamox reaction
Influences on Nitrous oxide formation:
- semi-optimal-oxy-conditions (straw cover on manure storage), slurry injections, in case of suboptimal process control and conditions, housing systems based on composting
Methane formation: manure from ruminants
Hydrolysis: Complex compounds (proteins, carbohydrates, lipids) are broken down into simpler compounds like amino acids, sugars, fatty acids by bacterial enzymes
Acidogenesis: The solutes are broken down into organic acids (butyric, propionic, acetic acids), lower alcohols, hydrogen etc. (stopped at low pH)
Acetogenesis: substances are further converted into acetic acid by acetogenic bacteria
Methanogenesis: acetic acids are split into methane, carbon dioxide and water. Hydrogen and carbon dioxide are reduced to methane and water.
Influences on methane formation:
Share of ruminants in livestock production.
- Give examples for main mitigation strategies to reduce emissions (formation and release; feeding; housing; ventilation; storage, application) or sketch the five major emission mitigation steps
Formation and release:
* inhibit the urease activity (ammonia formation)
* avoid suboptimal conditions for the conversion of N-bonds (nitrous oxide)
* reduce extensive cattle feeding (roughage) (methane)
feeding: low protein diets (ammonia), feed additives, dietary improvements, improving forage quality –> avoid N-surplus which can not be metabolized and will be excreted; adjusted rations to species and production stage, reduce extensive cattle feeding (roughage-methane)
housing: Air scrubbers, manure removal (avoid dirty surfaces), Güllekanalverengung, Kühlung, Cow-toilets
Velocity:
* reduce air velocity and temperature near emitting surfaces
* optimization of the balance between air flow rate, necessary air exchange, temperature needs
manure treatment: Anaerobic digesters, acidification
manure storage: storage covers
manure application: shallow injection , lower temperatures ad pH, fast incorporation into soil after application
- List six out of 11 measures investigated by the FAO report on the low emission pathways to 2050. Which measure seems to be the most “powerful”?
- Productivity increase (30 % emission reduction in livestock)
- selective Breeding
- improved animal health and welfare (higher productivity, growth rates)
- Carbon sequestration in grasslands (integration of trees
- Feed and nutrition improvements
- reducing food loss and waste
- What is the guiding idea of the environmental protection laws (e.g. BImSchG German federal pollution control bill).
- Protection against harmful effects on the environment or other hazards, considerable disadvantages and considerable nuisance to the general neighbourhood.
- Precautions to prevent harmful effects, in particular by such emission control measures as are appropriate according to the state of the art.
- Explain the term “Best available technique”, what is meant behind?
- “Best”: most effective protection of the environment as a whole (Best Techniques: Low emissions air, soil, water and efficiently use of energy and raw materials; Amount & quality of manure and waste; animal welfare)
- “Available”: possible/viable implementation in relevant sector, taking into consideration the costs and advantages (technical & economical application possible)
- “Techniques”: Technology itself & it’s application (Design, construction, maintenance, operation)