List questions Flashcards

1
Q

Name the main atmospheric pollutants and their danger.

A
  • Carbon monoxide - Poisonous gas.
  • Carbon dioxide - Causes green house effect
  • NO is a respiratory irritant.
  • NO2 reacts with unburnt hydrocarbons to produce low level ozone.
  • Sulfur dioxide - A contributor to acid rain.
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2
Q

Give ways of dealing with polymer waste.

A
  • Sorting polymers and recycling them(through reclamation).
  • Use waste polymers as a fuel source to generate electricity.
  • Turning polymers into synthesis gas which can be used as chemical feedstock for conversion into useful products.
  • Making polymers from renewable material which break down naturally in the environment to form CO2and water.
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3
Q

Give uses of alcohols.

A
  • Ethanol used in alcoholic drink,aftershaves and perfumes.
  • Ethanol blended with petroleum to increase octane rating.
  • Methylated spirits - Mix of ethanol with small amounts of methanol and dye to produce methylated spirits which is used as a solvent for removing paint or as spirit burners in camping.
  • Methanol can be used as a clean burning fuel.
  • Methanol used in the feedstock industry.
  • Methanol can be formed from biomass, so can be a carbon neutral fuel.
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4
Q

In order to perform controlled tests in hydrolysis what should remain the same.

A
  • Use equal amounts,in mol, of each halogenoalkane.
  • Use halogenoalkanes of the same chain length.
  • Use water bath to ensure constant temperature .
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5
Q

Name the uses of CFC’s that now can’t be done with CFC’s.

A
  • Refrigerants
  • Propellants
  • Blowing agents
  • Solvents( for the dry-cleaning industry)
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6
Q

Name the molecules that have now replaced CFC’s.

A
  • HFC’s - hydrofluoroalkanes.
  • HCFC’s hydrofluorohydrocarbons .
  • butane - (flammable though)
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7
Q

Give reasons why 100% percentage yield is usually not achieved.

A
  • Reactions may be at equilibrium and never go to completion.
  • Other side reactions may occur, leading to by-products.
  • Reactants may not be pure.
  • Some products/reactants left in apparatus.
  • Seperation and purification may result in loss of product.
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8
Q

What factors does the amount of vibration of a molecule after absorbing infrared radiation depend on?

A
  • Bond length
  • Bond strength
  • The mass of each atom involved in each bond.
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9
Q

List the applications of infrared spectroscopy.

A
  • Forensic science
  • monitoring the degree of unsaturation in polymers.
  • quality control in perfume manufacture
  • drug analysis.
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10
Q

List the uses of mass spectrometry.

A
  • Identifying unknown compounds.
  • To determine the abundance of each isotope in an element.
  • Detecting banned substances such as steroids in athletics.
  • Analysing molecules in space.
  • Detecting traces of toxic chemicals in contaminated marine life.
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11
Q

State factors which cause the experimental value of enthalpy of combustion to be less than the true value?

A
  • incomplete combustion
  • heat loss to surroundings.
  • specific heat capacity of apparatus not calculated.
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12
Q

What can affect the rate of a chemical reaction?

A
  • Catalyst
  • Concentration
  • Temperature
  • Pressure
  • Surface area
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13
Q

List the advantages of using a catalyst in industrial processes:

A
  • Saves energy and therefore costs as well as fuel being burnt.
  • Allow processes to occur with less by-products formed hence there is less waste for the companies and less costs in seperation techniques.

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14
Q

What are the advantages of enzymes over catalysts?

A
  • Enzymes work at milder conditions such low temperatures and pressures and an optimum pH.
  • Enzymes are biodegradable while some catalysts are quite toxic at the end of their industrial lifes.
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15
Q

State the conditions for the ammonia process.

A
  • Iron catalyst.
  • Temperature of 400 *C.
  • Pressures of 200 atmospheres.
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16
Q

What are the top three greenhouse gases?

A

1) H2O
2) CO2
3) Methane

17
Q

What are some strategies to combat climate change?

A
  • Cleaner cars.
  • International coorperation ( through agreements to reduce pollution by a certain date/ awerness to public/ have scientists share their ideas.)
  • CCS ( carbon capture and storage )
  • Alternative energy sources ( solar/wind)
18
Q

Give different uses of CCS.

A
  • Store CO2 in old oil and gas fields.
  • Store as carbonates (react CO2 with metal oxide)
  • Store CO2 in porous rocks and seafloor.
19
Q

Write out all the steps from the formation of ozone to the destruction of ozone.

A
  • O2 —> 2O
  • O + O2 –> O3 + heat
  • O3 + (Uv <320nm ) –> O2 + O

Overall: O3⇔ O2 + O

  • O + O3 –> 2O2
20
Q

List the types of catalytic converters and their uses.

A
  • Oxidation catalysts, used in diesel cars. Oxidise carbon monoxide to CO2 and sure hydrocarbons fully react with oxygen.
  • Three-way catalysts - fitted into petrol engines:

2NO + 2CO –> 2CO2 + N2