Lipids Flashcards
which phospholipid has X=OH (attached to their phosphate)
phosphatidic acid
which phospholipid has X=O-CH2-CH2-NH2
attached to their phosphate
phosphatidylethanolamine (like cephalin)
which phospholipid has X=O-CH2-CH(NH2)-COOH
attached to their phosphate
phosphatidylserine
Which phospholipid as a sugar attached at the phosphate
phosphatidylinositol
which phospholipid has X=O-CH2-CH2-N+(CH2)3
attached to their phosphate
phosphatidylcholine (like lecithin)
what is this hydrocarbon: CH2=C(CH3)−CH=CH2
isoprene
terpenes classes
- Monoterpenes (2 isoprene units, 10C)
- Sesquiterpenes (3, 15C)
- Diterpenes (4, 20C)
- Sesterterpenes (5, 25C)
- Triterpenes (6, 30C)
Systematic and common name of 4:0, 6:0, 8:0 and 10:0
Butanoic acid, butyric acid
Hexanoic acid, caproic acid
Octanoic acid, caprylic acid
Decanoic acid, capric acid
Systematic and common name of 12:0, 14:0, 16: and 18:0
Dodecanoid acid, lauric acid
Tetradecanoic, myristic acid
Hexadecanoic acid, palmitic acid
Octadecanoic acid, stearic acid
Systematic and common name of 20:0, 22:0, 24:0, 26:0
Eicosanoid acid, arachidic acid
Docosanoic acid, behenic acid
Tetracosanoic acid, lignoceric acid
Hexacosanoic acid, cerotic acid
Which FA with odd numbers are present in milk?
- Pentadecanoic acids (15C)
2. Heptadecanoic (17C)
Name of: 18:1 (9c) and 18:1(9t)
oleic acid and elaidic acid
Name of 18:2 (9,12)
linoleic acid ** have 2 natural unconjugated bonds
Name of 18:3 (9,12,15)
linolenic acid
6 major FA with their proportions
- Myristic acid (14:0) 2%
- Palmitic acid (16:0) 11%
- Stearic acif (18:0) 4%
- Oleic acid (18:1 (9)) 34%
- Linoleic acid (18:2 (9,12) 34%
- Linolenic acid (18:2 (9,12,15) 5%
what is arachidonic acid
20:46 with 4 unconjugated double bonds
examples of omega 3 with nonconjugated FA double bonds
a-linolenic acid 18:3(9,12,15) Flaxseed, soybean, walnut, rapeseed oils
EPA 20:5 in fish, shellfish
DHA 20:6 in fish, shellfish,
examples of omega 6 with nonconjugated FA double bonds
arachidonic acid 20:4 In meat, liver lard and lipids of chicken eggs
Linoleic acid 18:2
Y-linolenic acid 18:3(6,9,12)
** omega 6 in corn oils, sunflower oil and safflower oil
examples of omega 9 with nonconjugated FA double bonds
Oleic acid 18:1
Erucic acid 22:1 present in the mustard family of seeds (brassicacecae)
Nervonic acid 24:1
** omega 9 in olive oil, avocados, peanuts, almonds
most common conjugated linoleic acid (CLA)
Cis-9, trans-11 isomer
2 FA with unconjugated TRANS double donds
elaidic acid
Linolelaidic acid
FA with conjugated double bonds
A-Elostearic acid
B-elostearic acid
Parinaric acid
fatty composition of cow milk
25-32% palmitic acid, C16
10-12% stearic acid, C18
30-40% oleic acid, C18:1
4-15% butyric acid and other short-chain FA (up to 10C)
example of trans fat not bad for health
vaccenic acid (11-octadeonic acid)
Nomenclature of rumenic acid and 11-octadecenoic acid
- Omega-7 trans fat. C18:2 (9c,11t)
2. 18:1(11t)
major FA in olive oil
- Oleic
- Palmitic (S)
- Linoleic (U)
- Stearic acid (2)
- Palmitoleic (M)
- Alpha linolenic acid (U)
Examples of oil in:
1. Lauric acid 2. Oleic-linoleic acid group 3. Linolenic acid 4. erucic acid
- From species of palm like oil palm (palm kernel oil), coconut and babasu- commonly know as tropical oils
- Cottonseed, sunflower, safflower, oilve, peanut and corn oil
- Soybean, linseed, castor, hempseed and perilla oils
- rapeseed oil (natural one contain 40-50% erucic acid), mustard oil
composition of animal fat depot group
- similar levels of unsaturated FA as the oils in the oleic-linoleic acid group:
- 50-60% oleic and linoleic acid
- 30-40% palmitic and stearic acid (C16 and C18)
- similar levels of unsaturated FA as the oils in the oleic-linoleic acid group:
crystal form of alpha, beta and beta prime and their space arrangment
alpha: hexagonal (angle de 120degree), vertical tunning fork
beta prime: orthorombic beta prime (angle 90), tilted tunning fork
beta: triclinic beta, stacked chair