lipids Flashcards

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1
Q

What is a triglyceride and how do they form

A

Lipid molecule consisting in 1 glycerol and 3 fatty acids. They are non polar and hydrophobic
condensation reaction between 1 molecule of glycerol and 3 fatty acids which form ester bonds
They have 3 ester bonds

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2
Q

contrast saturated and unsaturated fatty acids

A

saturated
- contain only single bonds
- straight chain molecules have many contact points
higher melting point = solid at room temperature
found in animal fats
unsaturated
- contain C=C double bonds
- kinked molecules have fewer contact points
lower melting point = liquid at room temperature
- found in plant oils

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3
Q

What are the function of lipids

A

Energy source for respiration
thermal insulation
Electrical insulation
Protection
Membrane structure
Steroid hormones

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4
Q

are phospholipids and triglycerides polymers

A

no they are not repeating units they are macromolecules

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5
Q

describe the structure and function of cholesterol

A

steroid structure of 4 hydrocarbon rings
hydrocarbon tail on one side, hydroxyl group (-OH) on the other side
adds stability to cell surface phospholipid bilayer by connecting molecules
at low temps cholesterol increases membrane fludiity to stop the membrane solidifying - packs less closely togather

structure
what does it do to the phospoholipid bilayer

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6
Q

type of bond formed when fatty acids bond with glycerol

A

ester bond

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7
Q

phospholipid is therefore made up of what two parts

A
  1. hydrophilic ‘head’ which interacts with water but no fat
  2. hydrophobic ‘tail’ which orients itself away from water but mixes readily with fat
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8
Q

describe how triglycerides may differ from each other

A

the glycerol molecule in all fatty acids is the same
the difference in fats and oils comes from variation in the fatty acid - saturated or unsaturated

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9
Q

contrast the difference from phospholipids and triglycerides

A

triglycerides have 3 fatty acids and 3 ester bonds whereas phospholipids have 2 fatty acids and 2 ester bond

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10
Q

Define lipid

A

A group of substances that are soluble in alcohol rather than water due to fewer -OH groups
They include phospholipids, glycolipids, and cholesterol

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11
Q

Are lipids soluble in water + why

A

They are insoluble in water
They are not polar molecules

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12
Q

Structure of glycerol

A

Three carbon backbone with an alcohol -OH attached to each carbon

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13
Q

Structure of fatty acids

A

They have a carboxylic acid group -COOH and a variable ‘R’ group

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14
Q

How do lipids act as an energy source

A

Can be broken down in respiration to generate energy and release ATP by hydrolysing the ester bonds and the glycerol and fatty acids until completely broken down into carbon dioxide and water
Insoluble in water so can be stored in cells without affecting the water potential - no osmotic effect

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15
Q

How do lipids act as an thermal insulation

A

adipose tissue is a storage location for lipids in mammals acting as a heat insulator.

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16
Q

how does lipids act as an electrical insluation

A

nerve fibres are suurounded by a fatty mylein sheath

17
Q

how do lipids act as a steriod hormones

A

steriod hormones are all made from the lipid cholesterol

18
Q

how do lipids help with buoyancy

A

because fat is less dense than water - used by aquatic animals to help them float

19
Q

how do lipids help with protection

A

human have a fat around delicate organs such as the kidneys to act as a shock absorber. the peptidoglycan cell wall of some bacteria is covered in a lipid rich outer coat

20
Q

What is the structure of a phospholipid

A

Glycerol
2 fatty acids
A phosphate group

21
Q

what sort of reaction forms a phosopholipid

A

condensation

22
Q

what type of bond is there between a phosophate group and a glycerol in a phosopholipid

A

Ester bond

23
Q

how do phosopholipids interact with water molecules

A

Hydrophilic head and a hydrophobic tail

24
Q

What type of molecule is a phospholipid

A

Amphipathic

25
Q

what is the usage of lipid normally means its amphipathic

A

Membrane lipids

26
Q

how do phosopholipids react when in contact with water

A

tails stick up with head forming layer of the surface or might form a micelle (ball with heads on the ouside and tails on the inside

27
Q

what structure do phosopholipids form when forming a membrane

A

A bilayer

28
Q

what gives a phosopholipid membrane bilayer its stability

A

individual phosopholipids are free to move around in their layer but will not move to any position that exposes the hydrophobic tails

29
Q

what allows the membrane to be selectively permeable

A

it is only possible for small, non-polar molecules to move through the bilayer

30
Q

Contrast cholesterol to phospholipids/triglycerides

A

Cholesterol is not made up of glycerol and fatty acids
phospholipids and triglycerides are made up of glycerol and fatty acids

31
Q

What is cholesterols role in the membrane

A

Regulates the fluidity of the membrane

32
Q

What is cholesterol made

A

In the liver of animals

33
Q

phospholipid molecules are similar to triglycerides but they also contain the element phosphorus as part of the phosphate group
explain how the structure of phospholipids allows them to form the bilayer of a plasma membrane
(3 marks )

A

hydrophilic head and hydrophobic tails (1)
hydrophobic part / tails, repelled, by water (1)
head / hydrophilic part, forms H bonds with water (1)
idea that medium outside / inside plasma membrane is aqueous (1)
idea that hydrophobic nature of tails results in their facing towards each other (10

34
Q

state two roles of cholesterol in living organisms

A

regulates fluidity of / stabilises phospholipid bilayer
converted to a steroid
making bile
making vitamin D

35
Q

phospholipid molecules also contain fatty acids
explain how the fatty acids in phospholipids allow the formation of membrane

A

fatty acids are hydrophobic so do not interact with water
form a phospholipid bilayer
hydrophobic nature causes the fatty acid tails to orientate towards the middle of the bilayer

36
Q

what do carbon-carbon double bonds do to the number of hydrogens

A

decreases the number of hydrogens