Lipid Classification Flashcards

1
Q

_____ have no double bonds (carbons have a maximal single bonds)

A

Saturated Fatty Acids

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2
Q

____carbons have 1 or more double bonds (mono-or polyunsaturated)

A

Unsaturated Fatty Acids

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3
Q

In unsaturated fatty acids, the double bonds: (3 things)

A
  1. are in the cis conformation (not trans)
  2. cause fatty acid bends “kinks”
  3. Are spaced at 3-C intervals
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4
Q

What are the effects on melting temperature and fluidity?

A

a) introduction of double bonds REDUCES Tm and INCREASES fluidity
b) . increasing chain length INCREASES Tm, DECREASES fluidity
c) . Membrane phospholipids typically have LCFAs and thus contain double bonds to IMPROVE fluidity characteristics.

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5
Q

What are the 2 essential fatty acids that plants provide that humans cannot synthesize?

A

Linoleic acid and alpha-linolenic acid

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6
Q

____ becomes essential if Linoleic acid is deficient in the diet

A

Arachidonic acid

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7
Q

Why is Linoleic acid considered an essential fatty acid?

A

It is a precursor for other shorter w-6 FA

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8
Q

Arachnoid is considered an essential fatty acid because

A

it is a substrate for prostaglandin synthesis

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9
Q

Why is alpha-linolenic acid considered an essential fatty acid?

A

It is a precursor for w-3 fatty acids: it is important for growth and development

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10
Q

Fatty acids with chain lengths with 4-10 carbons are found in significant quantities in ____

A

milk

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11
Q

Short and Medium chain length fatty acids contain ___ carbons

A

4-10

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12
Q

Long chain fatty acids contain ____

A

16-22

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13
Q

Very long chain Fatty Acids contain

A

> 22

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14
Q

There are two forms of fatty acids:

A

unesterified and esterified fatty acids

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15
Q

The free fatty acids are called

A

unesterified

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16
Q

The fatty acyl esters are called

A

esterified

17
Q

Free fatty acids are used as structural components of membrane lipids such as

A

phospholipids; glycolipids and sphingolipids

18
Q

Name the 4 uses for fatty acids:

A
  1. structural components of membrane lipids
  2. Conjugation to proteins for membrane anchoring properties
  3. Oxidized to provide energy
  4. Precursors for hormone-like prostaglandins
19
Q

___ are the precursors used to form more complex molecules (such as TAG)

A

Fatty acyl esters

20
Q

Fatty acyl esters are stored in

A

adipose tissue as TAG

21
Q

Fatty acyl esters serve as the

A

major energy reserve for the body

22
Q

90% of plasma fatty acids are ____ contained in lipoprotein particles.

A

Fatty acid esters

23
Q

Name the lipoprotein particles

A

TAG, cholesteryl esters, phospholipids

24
Q

Most tissues can take up ______

A

Free Fatty Acids

25
Q

Give two examples of point of origin of fatty acids

A

from TAG in adipose tissue

from circulating lipoproteins

26
Q

______ is important for de novo synthesis

A

Palmitic acid (16:0)

27
Q

Name the acids that are common in milk.

A

Butyric Acid and Capric Acid

28
Q

Name the acids that are synthesized within the brain tissue

A

Lignoceric Acid and Nervonic

29
Q

De Novo synthesis of palmitic acid is produced in the

A

cytosol

30
Q

______ are predominantly hydrophobic and must be in association with protein for circulation solubility

A

LCFA