Ligands Flashcards

1
Q

Covalent type X ligands

A

Have an unpaired electron

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2
Q

Covalent type L ligand

A

Have lone pairs

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3
Q

ionic type X ligand

A

Consider as X-, donates 2 electrons to metal centre

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4
Q

ionic type L ligand

A

Consider as 2 electron donors

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5
Q

X2 ligand

A

Divalent species with 2 unpaired electrons, forms double bond with metal centre

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6
Q

Denticity

A

Number of donor atoms that bond to metal centre

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7
Q

Bridging ligands

A

Type X ligands sometimes have extra lone pair that can form another co-ordinate bond

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8
Q

Ambidentate

A

More than one donor atom but ligand only co-ordinates through one donor atom at a time

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9
Q

Nature of ligands

A

Halide donors and oxygen donors are weak
Nitrogen donors and carbon donors are strong

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