Ligand 6

Question 1

Monodentate ligands

Answer 1

Spectrochemical series ligand

Question 2

Bidentate ligand

Answer 2

En
Glycine
DMG
acacia
bcac
Pn
TN
Bn

Question 3

Sigma donar ligand on the basis of mot

Answer 3

Only 1 lp in homo

Question 4

Lecture 3

Question 5

Ligand if of two types
1. Sigma bond = H2O,NH3,RNH2,ROH,R-,H-
2. SIGMA + PI BOND = IT IS OF TWO TYPES
a. Pi donar = NH2-,OH-,RNH2-RO-
b. Pi acceptor = it is of two types

Answer 5

. Sigma * acceptor= PR3,PX3,PPH3,SR2,SH2,H2
. PI*acceptor = CO,NO+,CN-,C=C,C≡C

Question 6

Factors affection splitting

Answer 6

1. Higher oxidation state of metal split more
   2.5d>4d>3d
   3 no of ligand oh>td
   4.strength of ligand