Lewis Model Flashcards
Covalent bond
Electron pairs are shared equally between atoms
Polar covalent
Electron pairs share unequally giving a polar covalent bond
Ionic bonding
Electron(s) transferred from one atom to another
Who is Gilbert Lewis?
Developed the theory of covalent bonding
Lewis symbols
Simple way of showing valence electrons.
Simple use of electrons as dots or crosses
Chemical bend length
Chemical bonds are measured using electron diffraction techniques. The length of a chemical bond is not fixed
Lewis structure
Representation f the formation of covalent bonds using Lewis symbols
Advantages and
Disadvantages of Lewis Model
Adv: Provides a simple way to describe bonding
Prediction of bond order
Can be extended to predict molecular shape (VSEPR)
Disadv: Doesn’t explain how bonding occurs
Doesn’t always work - many molecules don’t follow the octet rule and yet are stable.
Hypervalency
Bonding in transition metal compounds
Doesn’t explain paramagnetism of oxygen
Electronegativity
The more electronegative, the more likely it will pull electrons towards it
Octet rule
Atoms gain, lose or share electrons until they are surrounded by eight electrons
No vacant orbitals: no reactivity
Exceptions to octet rule
- Molecules with odd numbers of electrons
- Reduced octets (i.e. less than 8 electrons)
- Expanded octets (i.e more than 8 electrons)
- Not followed usually by s- d- and f- block elements
Octet exception - Odd number
O=Cl=O ->
N=O -> 9electrons
O=N=O
Octet exception - reduced octet
Cl-Be-Cl ->Be has 4 electrons
BF3 ->B has 6 electrons
AlCl3 -> Al has 6 electrons
Octet exception - Expanded octet
SF6 -> S has 12 electrons
PCl5 -> P has 10 electrons
IF7 -> I has 14 electrons