Lesson 2 - Enthalpy change Flashcards
Physical Change and example
Change in its conditions that does not change its chemical properties
Ex.) Melting, Shredding, Boiling, Chopping
Enthalpy of solution
When one substance dissoles in water
For a solute to dissolve in a solvent (3 things)
- Interactions between molecules of the solute are broken to make room for solvent molecules
- Interactions between molecules of solvent are broken to make room for solute molecules
- Interactions form between solute and solvent molecules
ΔHsolution =
ΔHsolution = ΔHsolute+ΔHsolvent+ΔHmix
Enthalpy of phase change
When a substance changes phases
What does the subscript symbol nought represent?
Nought represents standard conditions (1 mol at SATP)
Some processes are equal but opposite, say examples
ΔHmelting = -ΔHfreezing
ΔHvaporization = -ΔHcondensation
ΔHsublimation = -Δdeposition
Endothermic = Exothermic
Heating curve
Shows the amount of heat added as temperature changes
A linear increase of a heating curve
Shows that the temperature of the substance is increasing within a phase, and temperature is calculated by Q=mcΔT
A straight line on a heating curve
Between phases, where the intermolecular forces are being broken therefore heat is added with no change in temperature. This is the enthalpy part of the diagram
Chemical change and example
A change of materials into another, new materials with different properties and one or more than one new substances are formed
Ex.) Burning wood, frying eggs, combustion of propane
Nuclear change and example
A process such as fission, fusion or radioactive decay where the structure of an atomic nucleus is altered through release of energy or mass or by being broken apart
Ex.) Splitting of the uranium-235 nucleus when it is bombarded with neutrons.
Some radioactive nuclei emit B…
Beta particles, identical to electrons
Some radioactive nuclei emit A…
Alpha particles, identical to helium (2 protons and 2 neutrons)
E=
E=mc^2
In a nuclear change, why is the the total mass of all products smaller than the original nucleus?
The missing mass is converted into energy through Einstein’s equation E=mc^2
Alpha decay
When a nucleus emits an alpha particle, the resulting nucleus has two less proton and two less neutron. Thus mass number is reduced by four and its atom number is reduced by two.
Beta decay (B- particle)
When a nucleus emits a B- particle, a neutron becomes a proton and a electron. The resulting nucleus has one less neutron and one more proton. The electron gets released
Beta decay (B+ particle)
When a nucleus emits a B+ particle, a proton becomes a proton and a positron. The resulting nucleus has one less proton and one more neutron. The positron gets released.
Gamma radiation
Intense radiation given off from a radioactive decay. It carries no mass and is purely energy.
Nuclear fission
Process where a heavier nucleus splits off into multiple, smaller, lighter nuclei. It can result in various combinations of new elements
Nuclear fusion
Process where two very small nuclei combine to form a larger nuclei.