Lesson 1, 2: History, Molecular Origin Flashcards
Macromolecule (long molecules) built of small covalently bonded units called monomers
Polymer
Monomers in greek word is ___ means ____
“mer”, part
Small units repeated throughout the macromolecule chain
Monomers
The macromolecules are bonded together by ___ or ___
weak Van der Waals and hydrogen (secondary bonds), or additional covalent cross-links
Most polymers are ___ and formed from ___
Organic, hydrocarbon molecules
Each C atoms has ___ electrons that participate in covalent bonding, each H has ___ bonding electron
4, 1
A single covalent bond exists when ____
Each of the 2 bonding atoms contribute one electron
Double and triple bonds between 2 carbon atoms
Involve the sharing of 2 and 3 pairs of electrons
Molecules that have double, and triple covalent bonds are termed
Unsaturated
Unsaturated means
Each carbon us not bonded to maximum (4) other atoms
For saturated hydrocarbon
All bonds are single ones, and no new atoms may be joined w/o the removal of others
Molecule that combines with other mol of the same/different type to form polymer
Monomer
Oligomer is
Low molecular weight polymer, contains atleast 2 monomer units
Oligomer of polyethylene
Hexatriacontane
Specifies the length of polymer molecule
Degree of polymerization
In DOP, n means
Number of repeating units strung together in the polymer chain (mol)
A ___ degree of polymerization is normally reqd for a matl to develop useful properties
High
Dimensionless quantity given by the sum of the atomic weights in the mol formula
Molecular weight
Relation between DOP and MW of the same macromolecule is…
M=(DP)Mo
Mo= formula weight of the repeating units
Classification of Polymers
Based on origin
Based on polymer structure
Based on polymerization mechanism
According to thermal processing behavior
Based on preparative technique
Classification of polymer Based on origin
Natural vs synthetic polymers
Wood, rubber, cotton, leather, wool, silk, protein, enzymes, starches, cellulose is an example of
Natural polymers
Fibers , elastomers, plastics, adhesives
Synthetic polymers
Classification based on polymer structure
A. Linear, Branched or cross-linked, network vs functionality
B. AMORPHOUS OR CRYSTALLINE
C. HOMOPOLYMER OR COPOLYMER
D. FIBERS, PLASTICS, OR ELASTOMERS
Interlinking capacity, or the number of sites it has available for bonding with other mol under specific pply conditions
Functionality
A molecules can be classified as ___, ___, and ___ depending on whether it has one, two, or greater thwn two sites available
Monofunctional, bifunctional, and polyfunctional
Repeat units are joined together end to end in single chains.
Linear polymers
These long chain are flexible and can be flexible mass spaghetti
Linear polymers
Common examples of LP
PE, PVC, PS, and Polyamides
___ are generally more rigid
Linear polymers
Branched polymers
Have side chains or branches growing out from the main chain
The side chains or
branches are made of the same repeating units as the
main polymer chains (T or F)
T
In ___ adjacent linear
chains are joined one to another at
various positions by covalent bonds
crosslinked polymers
✓Crosslinks tend to be ___ in
nature
permanent
✓Common examples of Cross-linked polymers
Bakelite,
melamine, epoxies, bulk molding
compounds, rubber, and various
adhesives
✓Multifunctional monomers forming
three or more active covalent bonds
make three dimensional networks
and are termed
Network polymers
✓These materials have distinctive
mechanical and thermal properties
network polymers
Network polymers that have distinctive
mechanical and thermal properties
epoxies, polyurethanes, and
phenol-formaldehyde
material
exhibits organized and tightly packed molecular
chains
Crystalline polymers
have good strength &
wear, and good chemical resistance, but they typically lack in impact resistance
crystalline polymer
✓Examples of crystalline polymers include
polyethylene, polyacrylonitrile, poly(ethylene
terephthalate), and polytetrafluoroethylene.
polymers that have no
crystalline regions and no uniformly packed molecules.
✓Amorphous polymers
Amorphous polymers are polymers that are
composed of amorphous regions where molecules
are ____ arranged.
randomly
✓Natural rubber latex and styrene-butadiene rubber
(SBR are hood examples of
amorphous polymers
✓The ____ is a measure of the degree of order or
orientation in a crystal
degree of crystallinity
The DOC ranges from 0 to 100%, where 0% represents
an ____, and 100% represents a perfectly ____.
amorphous material, crystalline
material
✓When all of the repeating units along a chain are of
the same type, the resulting polymer is
Homopolymer
✓The purpose of homopolymers is ____
to produce a
polymer that has increased mechanical properties.
These enhanced mechanical properties in homopolymer include
_____
tensile strength, stiffness, impact resistance, and
short-term creep resistance.
✓The types of homopolymers include
polyvinyl
chloride, polyethylene, polypropylene,
polycarbonate, polyester, nylon 6, nylon 11,
polytetrafluoroethylene, and styrene.
A ___ is a polymer made up of more
than one type of monomer unit.
copolymer
polymerizing
two or more types of monomer together in
a process
Copolymerization
Copolymers produced in copolymerization are
sometimes also referred to as
biopolymers
✓The purpose of creating a copolymer is ____
to
manufacture a polymer with more desirable
properties.
typically experience
a lower crystallinity, higher glass transition temperature, and improved solubility.
Copolymers
In structure of polymers, Representing two different mers by A and B, what is this
ABBABBBAABBAABAAABBA
random copolymer
There are three other copolymer structures
alternating, block, and graft copolymer structures
In the ____, the two mers alternate in a regular fashion along the polymer chain
ABABABABABAB
alternating copolymer
____ is a linear polymer with one or more long uninterrupted sequences of each mer in the chain -AAAAAAAAAABBBBBBBBBB
block copolymer
A ____ is a branched copolymer with a backbone of one type of mer and
one or more side chains of another mer :
AAAAAAAAAA
B
B
B
B
graft copolymer
linear polymers with high
symmetry and high intermolecular forces that result usually from the presence of polar groups.
Fibers
characterized by high modulus, high tensile strength, and moderate extensibilities
Fibers
Examples of fibers are
Polyester, Nylon, Spandex, Kevlar, Rayon, Acetate, Acrylic, Lastex, Polypropylene
molecules with irregular structure, weak intermolecular attractive forces, and very flexible polymer chains.
Elastomers