Lecture 7 - Nickel Alloys Flashcards
What is chromium’s effect on nickel?
oxidation and hot corrosion resistance, solid-solution strengthening
What is molybdenum and tungsten’s effect on nickel?
solid solution strengthening, M6C carbides
What is aluminum and titanium’s effect on nickel?
forms gamma’ hardening precipitate; Al enhances oxidation resistance and Ti forms MC carbides
What is cobalt’s effect on nickel?
raises gamma’ solvus temperature
What is boron, zirconium, and hafnium’s effect on nickel?
improves rupture life through increased ductility
B forms borides
Hf forms MC carbides and promotes eutectic gamma-gamma’ formation in cast alloys
What is carbon’s effect on nickel?
forms MC, M7C3, M23C6, M6C carbides
What is niobium’s effect on nickel?
forms gamma’, Ni3Nb, hardening precipitate; forms delta orthorhombic Ni3Nb
What is tantalum’s effect on nickel?
solid solution strengthening; forms MC carbides, enhances oxidation resistance
What are the microstructures of manufactured Inconel alloys like?
complex and messy
Why is post-processing treatment necessary?
since it is difficult to control the phase fraction of as-built materials, the microstructure has poor properties and HIPing is needed to tailor material properties
Which properties are critical for Inconel alloys?
fatigue and creep at elevated temperatures (porosity is a big concern)
What do the macro and micro residual stresses affect for printing Inconel 718?
Type I - part dimensional accuracy
Type II - mechanical properties
What is the difference between Inconel 625 and 718?
625 - solid-solution matrix-stiffened face-centered-cubic-alloy
718 - age-hardenable austenitic material, strength dependent on precipitation of gamma prime during heat treatment, higher value, adds niobium
What are topologically close-packed phases?
phases formed by high levels of refractory elements to increase high temperature creep and rupture properties
undesirable brittle phases formed during heat treatment or service
appear as discs and are easy crack origins
What phases do TCP’s include?
sigma (Fe-cr, 50-50) the worst phase for ductility
mu
Laves
What is the Ni3Al?
gamma’, geometrically close-packed