Lecture 7: Ionic Bonding Flashcards

1
Q

What is a chemical bond?

A

An attractive force that holds two or more atoms together

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What are the four types of chemical bonds?

A
  • Ionic
  • Covalent
  • Dative
  • Metallic
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What do most atoms adjust their valence shells to?

A

8 e-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Which atoms do not obey the 8 e- rule?

A

Transition metals using their d-orbitals (they use the 18 e- rule)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

How will a proton act on another proton?

A

They will repel

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

How will an electron act on a proton?

A

They will attract

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

How will a neutron act on an electron?

A

It will not

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

How is the force acting on each particle linked to the size of the charge?

(HINT: Columb’s Law)

A

They are proportional

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

How is the force acting on each particle linked to the distance between them?

(HINT: Coulomb’s Law)

A

Inverse square

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is electronegativity?

A

The ability of an atom to attract electrons in a chemical bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What factors affect electronegativity?

A
  • The charge of the nucleus
  • Atomic radius
  • Screening (shielding)
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Which element is most electronegative?

Why?

A

Fluorine

Small atomic radius, high nuclear charge

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Explain ionic bonds

A

Bonds between metals and non-metals

Metals donate electrons

Non-metals gain electrons

This forms oppositely-charged ions

The ions then attract each other

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Describe the properties of an ionic bond (4+1)

A
  • Non-directional
  • The compound will dissolve and dissociate in polar solvents
  • (the separated ions are solvated)
  • The bonds can be broken by melting
  • The compounds have no overall charge
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Which factors favour ionic bonding? (6)

A
  • Low IE of the metal
  • High EA of the non-metal
  • Small non-metal
  • Low anion charge
  • Large electronegativity difference between the ions
  • High lattice energy
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Which characteristics give an ion more polarising power?

A
  • Smaller atomic radius
  • Higher charge
17
Q

What are Fajan’s Rules?

A

An ionic compound is more likely to show covalent character if the cation is very polarising or the anion is very polarisable

18
Q

Name the following ions:

  • NH4+
  • CN-
  • CO32-
  • MnO4-
  • C2O42-
  • SO42-
A
  • Ammonium
  • Cyanide
  • Carbonate
  • Permanganate
  • Oxalate
  • Sulphate
19
Q

Give the formulae for the following ions:

  • Peroxide
  • Hydroxide
  • Acetate
  • Nitrate
  • Carbonate
  • Phosphate
  • Dichromate
A
  • O22-
  • HO-
  • CH3CO2-
  • NO3-
  • CO32-
  • PO43-
  • Cr2O72-