Lecture 6: Phases And Heat Capacities Flashcards
1
Q
Heat capacity (C)
A
- C=q/T=heat added to a system/temperature
- Types of heat capacities
2a. Constant volume heat capacity (Cv): U=q
2b. Constant pressure heat capacity (Cp): U=q+w
2
Q
Specific heat capacity
A
- Equation: q=MC△T
3
Q
Specific heat of water
A
4 KJ/(kg*K)
4
Q
Calorimeter
A
- Relies on heat capacity to measure heat of a reaction
5
Q
Bomb calorimeter
A
- Measures heat of combustion
6
Q
Phase diagrams
A
- Represents the phases of a substance at different pressures and temperatures
1a. Triple point: point where substance is at eqm with all phases
1b. Critical temperature
7
Q
Phase change: heat curve
A
- Heat of fusion: melting
- Heat of vaporization: boiling
8
Q
Extra
A
9
Q
4 colligative properties of a solution
A
- Vapor pressure lowering: adding nonvolatile solute
- Boiling point elevation: adding nonvolatile solute
2a. △T=kmi
2b. Vant Hoffman factor (i): number of particles which a single solute will dissociate into - Freezing point depression: occurs when impurities are added
3a. △T=kmi - Osmotic pressure: pressure distance
4a. Osmotic pressure=n=iMRT