lecture 4 Flashcards

1
Q

entropy always

A

increases with time

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2
Q

work can easily be transformed into

A

heat but heat cannot easily be transformed into work

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3
Q

what makes a process irreversible

A

heat is generated

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4
Q

entropy =

A

change in heat/temperature

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5
Q

why does generating heat make a process irreversible

A

heat to work is difficult work to heat is easy

it generates entropy

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6
Q

entropy is a property of a

A

substance

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7
Q

more reversable a process is

A

the lower the entropy increase will be

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8
Q

entropy is the arrow of time

A

entropy always increases no matter what you do if you decreases entropy in one place you are increasing it by a greater amount somewhere else

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9
Q

friction prevents

A

an reversible process exsisting

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10
Q

entropy decreases

A

when a system is cooled

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11
Q

entropy increasse

A

when heat is added to a system

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12
Q

change in entropy =

A

irreversibility change + change in heat/temp

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13
Q

There is an entropy increase associated

A

with heat transfer, and friction, but not with work.

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14
Q

for adiabatic process entropy increase =

A

0

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15
Q

for a reversable process

A

ds = dq/T

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16
Q

substituting change in dq = Tds into first law

A
Tds = du +pdv
ds = du/T + dpv/T
17
Q

change in enthalpy =

A

Tds - vdp

18
Q

entropy for solids and liquids

A
ds = du/T + pdv/T
dv = 0 and du =cvdT
ds = cv dT/T = cv lnT2/T1
19
Q

entropy for ideal gas

A

in the LBoT

20
Q

why for the given change in temperature for gas the entropy change greater than a solid

A

as extra component R =lnv2/v1

see LBoT for gas

21
Q

isentropic process is one where

A

entropy does not change

22
Q

draw the temperature entropy diagram for steam

A

see powerpoint

23
Q

draw the temperature entropy diagram for an ideal gas

A

see powerpoint

24
Q

if isentropic process describe the arrow of a pressure increase

A

straight arrow upwards

25
Q

if non isentropic process describe the arrow of a pressure increase

A

arrow will move to the right as entropy always increases

26
Q

compression

A

pressure increase (compressor)

27
Q

expansion

A

pressure decreases (turbine)

28
Q

isentropic process is

A

the most efficient

29
Q

efficiency =

A

what you want/what you pay for

30
Q

efficiency should always be

A

less than one