Lecture 3 Flashcards

1
Q

When was the Kyoto Protocol negotiated?

A

1997

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2
Q

When was the Kyoto Protocol open for signature?

A

1998

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3
Q

When did the Kyoto Protocol come into force?

A

February 16, 2005

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4
Q

Under the Kyoto Protocol, industrialized countries will reduce their collective emissions of greenhouse gases by how much compared to the year 1990?

A

5.2%

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5
Q

The Kyoto Protocol reduces the expected emissions in 2010 by how much?

A

29%

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6
Q

The Kyoto Protocol’s goal is to reduce overall emissions over what five-year period?

A

2008-2012

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7
Q

What is the Kyoto’s Protocol reduction target for the European Union?

A

8%

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8
Q

What is the Kyoto’s Protocol reduction target for the US?

A

7%

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9
Q

What is the Kyoto’s Protocol reduction target for Japan?

A

6%

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10
Q

What is the Kyoto’s Protocol reduction target for Russia?

A

0%

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11
Q

What is the Kyoto’s Protocol reduction target for Australia?

A

Australia is permitted an 8% increase.

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12
Q

What is the Kyoto’s Protocol reduction target for Iceland?

A

Iceland is permitted an 10% increase.

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13
Q

What is the limit temperature rise as per the Paris Agreement?

A

2 degrees Celsius.

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14
Q

The Paris Agreement is the first universal what?

A

Climate agreement.

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15
Q

The Paris Agreement promises $100 billion a year in climate finance for which types of countries?

A

Developing nations.

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16
Q

As per the Paris Agreement, 186 countries submitted plans detailing the reduction of what type of pollution?

A

GHG emissions.

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17
Q

The Paris Agreement seeks carbon neutrality by what year?

A

2050

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18
Q

By which method is heat transferred from the sun to the earth?

A

Radiation.

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19
Q

The maximum rate at which heat can be radiated by a body at a given temperature is given by what equation?

A

The Stefan-Boltzmann equation:
Qmax = σAT^4

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20
Q

Describe the components of the Stefan-Boltzmann equation.

A

σ is the Stefan-Boltzmann constant (5.67 X 10^-8 W/m^2-K^4), A is the surface area of the body (m^2), and T is the absolute temperature of the body (K).

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21
Q

An object radiating at the maximum possible rate is known as what?

A

As a black body.

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22
Q

Define heat flux.

A

The rate of heat transfer per unit of surface area.

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23
Q

What is the relationship between heat flux and the maximum rate of radiation?

A

q = Qmax/A

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24
Q

Why doesn’t earth’s surface approximate a black body?

A

Because of the greenhouse effect.

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25
Q

What name is given to the fraction of incoming radiation that is reflected back off the object?

A

Albedo.

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26
Q

What does the albedo of a surface depend on?

A

Albedo depends on the properties of a surface.

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27
Q

What is the albedo of Earth’s surface currently estimated to be?

A

31%

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28
Q

If albedo is denoted by a, and the incoming radiation is denoted by S0, then what equation denotes the rate of energy absorbed (W/m^2)?

A

S0(1 - a).

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29
Q

Does earth’s estimated 31% albedo consider the effects of GHGs?

A

No.

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30
Q

The average surface temperature is 15°C. What would it be without greenhouse gases?

A

-19°C.

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31
Q

If ΔF is radiative forcing, write ΔF in terms of Δqout and Δqin.

A

Δqout - Δqin

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32
Q

What two phenomena may modify Earth’s ΔF?

A

Change in the solar input, or changes in Earth’s albedo.

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33
Q

Does positive radiative forcing increase or decrease the radiation absorbed by earth?

A

Increases.

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34
Q

Does negative radiative forcing increase or decrease the radiation absorbed by earth?

A

Decreases.

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35
Q

Radiative forcing increases linearly with increase in concentrations of GHGs.

A

False - there are diminishing returns, meaning the affect of new concentrations depend on the original concentration.

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36
Q

Which equation expresses the total radiative forcing from multiple greenhouse gases as an equivalent CO2 concentration?

A

Cequiv(ppmvCO2) = Co exp(ΔFtot/6.3), or ΔFtot = 6.3ln(Cequi/Co).

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37
Q

What is the climate sensitivity factor (γ)?

A

γ is the ratio of the final temperature change (Δte) to the change in radiative forcing ΔFrad.

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38
Q

Write the equation of the climate sensitivity factor γ.

A

γ = Δte / ΔFrad.

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39
Q

What is earth’s climate sensitivity factor, based on empirical correlations?

A

γ= 0.65 °C/W-m^2

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40
Q

Most of the energy used throughout the world is in the form of what?

A

Fossil fuels.

41
Q

What’s the atomic weight of carbon, and molecular weight of CO2?

A

Atomic weight of 12, and molecular weight of 44.

42
Q

Every 24 grams of carbon in fuel produces how much CO2?

A

88g

43
Q

How many mass units of CO2 per mass unit of C?

A

3.667

44
Q

What is the equation for the mass of CO2 emitted, given the mass fraction of carbon and the mass of the fuel burned?

A

Mass of CO2 emitted = mass fraction of carbon x Mass of fuel burned.

45
Q

What term (and what units) are used to denote the quantity of energy per unit of fuel mass?

A

The heating value (kJ/g or kJ/mol).

46
Q

What equation expresses the carbon content of a fuel in relation to the fuel energy content?

A

Carbon intensity = Fraction of C in fuel / Fuel heating value.

47
Q

What is gross domestic product (GDP) used for?

A

As a measure of economic well-being of a country, expressed on a per capita basis.

48
Q

What equation gives the CO2 emissions per year of a country, in part using the GDP per capita?

A

CO2 emissions per year = (Population per year) x ( GDP per capita) x ( Energy use per GDP) x (CO2 emissions per unit energy).

49
Q

What term is used to refer to metals found in low concentrations in the environment?

A

Trace metals.

50
Q

Calcium, copper, iron, magnesium, phosphorus, potassium, sodium, and zinc are all essential for our nutrition.

A

True.

51
Q

All metals, whether essential or nonessential, become toxic at sufficiently large concentrations.

A

True.

52
Q

Lead, Mercury, Arsenic, Cadmium, Nickel and phosphorous are all nonessential metals.

A

False - phosphorus is considered essential.

53
Q

Which nonessential metal causes learning and behavioral disorders?

A

Lead.

54
Q

Which nonessential metal causes problems in motor coordination?

A

Lead.

55
Q

Which nonessential metal attacks the kidneys, the reproductive system, and the hematopoietic system (responsible for making blood)?

A

Lead.

56
Q

What two nonessential metals have been linked to respiratory cancer and are known to cause skin disease?

A

Nickel and chromium.

57
Q

Which nonessential metal impairs functioning of the kidneys, but doesn’t affect the reproductive system?

A

Cadmium.

58
Q

Which nonessential metal can damage the nervous system and the brain?

A

Mercury.

59
Q

What 3 trace metals are found in significant amounts in the atmosphere over land, specifically from soil/dust?

A

Silicon, aluminum, and iron.

60
Q

Air over the oceans contains high levels of which trace metal?

A

Sodium.

61
Q

What two sources contribute to the trace metals found in surface waters and groundwater?

A

From the soil and biota.

62
Q

Airborne levels of what two trace metals increase hundreds to thousands of times above natural levels near smelters?

A

Cadmium & zinc.

63
Q

Water draining from what human structure have greatly increased concentrations of metals?

A

Mines.

64
Q

Food stored where may become contaminated with metal far above the levels found naturally?

A

In improperly prepared metal containers.

65
Q

What are the four primary trace metal exposure routes?

A

Air, drinking water, food, and soil/dust.

66
Q

What formula gives the mass of a trace metal absorbed by the body per unit time?

A

Ai = Ci * Ui * fi, where Ci is the concentration of the trace metal, Ui is the uptake rate, and fi is the fraction of trace metal absorbed by the bloodstream.

67
Q

Trace metals in the air come in what two forms?

A

Gases or particles.

68
Q

Name a volatile metal that is mostly found in the vapor phase (gas form).

A

Mercury.

69
Q

Most airborne metals are in a gas form.

A

False - most airborne metals are predominantly associated with solid particles.

70
Q

What property of a particle form airborne metal affects its behavior, potential health risks, and environmental impact?

A

Aerodynamic diameter.

71
Q

Particles with an aerodynamic diameter of 1μm will be carried by winds in a manner similar to that of a perfect sphere of diameter 1 μm and with what density?

A

A density equal to that of water - 1 g/cm^3.

72
Q

Particles with a high density will have an aerodynamic diameter greater or less than their physical diameter?

A

Greater.

73
Q

The size distribution, or aerodynamic diameter of airborne trace metal particles depend on what?

A

How the particles were formed.

74
Q

Particle mass in the range 0.02-0.05 μm aerodynamic diameter are referred to as what?

A

As being in the nuclei mode.

75
Q

What do particles in the nuclei mode do at high concentrations?

A

They collide to form larger particles.

76
Q

What is known about airborne trace metal particles in accumulation mode?

A

These particles have reached a stable size.

77
Q

If spherical particles are 0.5 μm in diameter, how many are needed to form a particle in accumulation mode, if accumulation mode for this particle implies a diameter of 1.0 μm?

A

8

78
Q

The fraction of the trace metal entering the body via inhalation that is eventually absorbed into the bloodstream is the result of what two factors?

A

The rate of deposition in the lower lung and the absorption factor of the metal from the lower lung into the bloodstream.

79
Q

Name two major factors that influence the rate of deposition in the lower lung (pulmonary region) of airborne trace metal particles.

A

Particle size and breathing rate.

80
Q

We sometimes assume that all metal reaching the lower lung is absorbed into the bloodstream. In this case, what is fair (the fraction of trace metal absorbed by the bloodstream)?

A

fair is then equal to the rate of deposition in the lower lung.

81
Q

According to the U.S. Environmental Protection Agency, what is the fraction of lead absorbed from inhalation?

A

0.3

82
Q

What two forms do trace metals take in water?

A

Dissolved or undissolved (suspended particles).

83
Q

Name 4 major sources of trace metals in drinking water.

A

Runoff from agricultural lands containing fertilizers/pesticides, metals from industries, contaminated rain, and
Construction activities.

84
Q

Pipes made of lead add significant amounts of lead to the drinking water when used in water distribution systems.

A

True.

85
Q

Human exposure to trace metals in drinking water occurs uniquely through drinking the water directly.

A

False - also through drinking beverages and eating foods made with water containing trace metals.

86
Q

The absorption of trace metals from drinking water (fwater) depends on the absorption of a trace metal through the walls of what two organs?

A

The stomach and small intestines.

87
Q

What is the absorption of lead in water (fwater)?

A

0.5

88
Q

Name 3 major sources of trace metals in foods.

A

Airborne trace metals that deposit onto food grown outdoors, soldered cans containing food, and metal-containing dust in food processing areas.

89
Q

The absorption of trace metals from food (ffood) depends on the absorption of a trace metal through the walls of what two organs?

A

The stomach and small intestines.

90
Q

How can you obtain ffood, given fwater of a trace material?

A

ffood = fwater.

91
Q

Define dust.

A

Settled airborne particles, often indoors, generally due to human activity.

92
Q

Define soil.

A

Soil is outdoor grounded particles, generally assumed to be natural with contamination due to human activity.

93
Q

Trace metals are found in soils near what type of source of pollution?

A

Stationary sources, such as smelters or heavily travelled roads.

94
Q

When are small amounts of dust ingested by humans?

A

When food that is handled with fingers is ingested.

95
Q

How does the absorption of trace metals from dust/soil (fdust) compare to that of food and water?

A

fdust is less than ffood/fwater, since trace metals associated with soil/dust are likely to be less soluble than metals in food and water.

96
Q

When determining the absorption of a trace metal from all exposure routes, we must multiply together they absorption factors (fi).

A

False - we must compute net absorption for each route separately, and then add these quantities up.

97
Q

Define the dose (Dtotal) of a trace metal.

A

To total amount of that trace metal absorbed up until the present.

98
Q

When does the following formula hold true, where Atotal is the total absorption rate from all exposure routes and T is the time of exposure?
Dtotal = Atotal x T

A

As long as the absorption rate, Atotal, is constant over time.