Lecture 2 - Carbohydrate structure Flashcards
Basic formula carbohydrate
(CH2O)n
3 uses of carbohydrates
- Energy storage,
- structure,
- recognition and adhesion of cells and tissues
Sugars in the body are: D-isomers or L-isomers
D-isomers
6-membered rings
pyranoses
5-membered rings
Furanoses
Anomers
isomers that differ at a new asymmetric carbon atom formed on ring closure
Epimers
Isomers that differ at one of several asymmetric carbon atoms
diastereoisomers
isomers that are not mirrorimages
enantiomers
nonsuperimposable mirror images
Carbohydrate storage molecule in plants
Starch = amylose and amylopectin
Amylose glycosidic bonds
alpha-1,4
Carbohydrate storage molecule in animals
Glycogen
a-anomers
hydroxyl group attached to C-1 on opposite side of the ring as C-6
b-anomers
hydroxyl group attached to C-1 on same side of the ring as C-6
Difference amylose and amylopectin
unbranched and branched