Lecture 10: Ceramics Flashcards
what are some of the applications dental ceramics are used for?
inlays
onlays
single all ceramic crowns
short span all ceramic bridges
support for metal crowns and bridges
artificial denture teeth
orthodontic brackets
implants
what are ceramics composed of and what do they form?
- metal oxygen atoms with ionic bonds like zirconium and aluminum
- arrays in a 3-D crystalline lattice
what are the different types of ceramics?
glassy
glass dominated
crystalline
crystalline dominated
what are glassy ceramics used for?
glass dominated? crystalline? crystalline dominated?
esthetics and veneers
better esthetics/strength
strongest, opaque, any dental restoration
improved strength, more opaque, cores for anterior posterior crowns, inlays/onlays
what are the common compounds in the crystal phase?
leucite
fluroapatite
spinel
zirconia
alumina
lithium disilicate
lithium silicate/phosphate
what are the common compounds in the glassy phase?
silica (quartz, silicone oxide)
how are ceramics manufactured?
stacking (glass infusion)
pressing (HOT)
milling (CAD/CAM)
additive manufacturing (3D printing)
slip casting
each type of ceramic requires ______
a specific method of manufacturing
what are the matrix and fillers of resin-ceramic materials and why are they made ?
matrix: BisGMA, UDMA, TEGDMA
fillers: Zr-si, silica, zirconia, alumina
** resin ceramics are easier to fabricate, have properties closer to dentin, easier to repair, load bearing eg veneers
what are the mechanical properties of ceramics?
- high compressive strengths and moduli
- low tensile strengths and elongation
- stiff and brittle relatively to alloys and polymers
the hardness of ceramics is?
substantially higher than enamel and wear can be minimized if restoration surface is smooth
what is the coefficient of thermal expansion (CTE)?
measure of how much material expands per unit length if heated 1 C
why is the CTE important?
it is important for thermal compatibility due to ceramic being bonded to another material which can cause failure
proper CTE matching is required because?
not all alloys are compatible with all ceramics (prevent failure)
the glass phase allows what to pass through? crystalline phase?
- allows light to pass through
- reflects the light (absorbs and reflects)
the value is the most critical for what?
color matching (amount of lightness or darkness)
what are the parts of the porcelain fused metal?
- opaque porcline: masks darkness of oxidized metal
- gingival and incisal ceramics: overlap gives natural tooth color
what are the characteristics of the bonding of ceramics and alloys?
- alloys have oxide layer
- bond results in chemisorption by diffusion (covalent bond) between ceramic and oxide layer
- roughness increases strength
what are some causes of ceramic-alloy bonding failure?
- inadequate oxide layer
- high thermal residue stress
- secondary caries, tooth failure, periodontal disease
what is the advantage of all ceramic restorations?
- better esthetics
- no dark color to mask
- entirely glass dominated ceramics
what are the layers of all ceramic restorations?
- core (replaces alloy)
- veneering ceramic