Lecture 1- Lecture 3 Flashcards
material science
study of structure property and processing relationship
structure
the way materials organize themselves. Arrangement of atoms in different way.
Think Graphite vs Diamond. Di(single vs polycrystal). Diamond has zinc blend structure, FCC while graphineis a layer structure with covalent bonds in plane and VanWals between planes
Note structure dictates properties.
property
the way materials respond to the surroundings, environment, external stimulus included mechanical, electrical, magnetic, thermal, optical, chemical etc
processing
the way to “fabricate” materials including the application of heat (heat treatment), mechanical force (hot work, cold work), ect. to affect their micro structure therefore same properties.
Give a classification of materials based on (solid phase)
1) homogeneoity of properties, 2) chemical make up (bond nature), 3)Whether they have long range ordering
Categorize materials based on homogeneoity of properties:
monolithic (uniform), composite (different phases not monolithic), hierarchical (most common in bio, cells tissues, bone),
characterize material based on chemical make up (bond nauture)
metals= combination of metallic elements, “sea of electrons” –> metallic bond, good electrical/ thermal conducting –> strong deformable”
ceramics= compound between metallic and non metallic element oxides, nitrides, carbides, “ionic bonding”, good insulators!
Polymers= based on H.C or non metallic element, chain like structures, covalent bond, Van Walls make them flexible and easy to deform
Glasses= lack of long range ordering; are in non-equlibrium strength, brittle mechanically.
semiconductor- special type, mostly covalent bonding, in between conductors and insulators, extremely sensitive to contaminates
liquid crystal= shares properties of both liquid and crystals, more strain stronger it gets
porous and cellular= not completely compact with low density; important for energy absorbing applications elastic –> collapse of pores –> densification
Characterize material based on long range ordering or not
crystalline metals- structured
quasicrystal - inbetween
non crystallline- not structured
define crystal structure=
lattice structure (mathematical term) + basis (can be atom, atom cluster, group atoms
lattice
highly periodic arrays of points in 3D space
Bravais Lattice
14 types –> organized into 7 crystal systems
`1). orientation and arrangement: appears exactly the same for the lattice point
2). All points in the lattice can be reached with a Translational vector, R=n2a1+n2a2+n3a, where a1,a2,a3 are non coplanar vectors and n1,n2,n3 are integers
Primitive cell.... Corner=? face=? edge center=? center=1?
1 lattice point/cell
corner =1/8
face= 1/2
edge center= 1/4
center=1
I=body Center
F= face center
c= base center
platisicity
motion of dislocation not necessarily from existing dislocations, FCC easiest for dislocations
BCC structure
nearest neighbor= coordination number = 8; close packing direction = <1 1 1>, relationship between cube edge length and atomic radius
Bcc
chromium, alpha iron, molybedum, tantalum, tungsten, (all high tempertaure)