Lecture 1 Flashcards

1
Q

what promotes bonding?

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what types of bonds are there?

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what properties are inferred from bonding?

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

what is the atomic number Z?

A

protons/neutrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

are electron energy states continuous?

A

no, they have discrete energy states (so levels)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what is the quantum-mechanical principle

A

electrons have discrete energy states

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what energy level do electrons tend to occupy

A

the lowest available energy state

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

(picture of energy states– need to do)- electron energy states

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

when you form bonds, what electrons are important?

A

the lower ones are not, they are protected by the outer ones. the outer ones are more loosly bonds and they create bonds and can be moved

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

what are valence electrons

A

electrons in the outermost shell (the number)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

what shells are the most stable

A

filled shells

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

what electrons are the most available for bonding

A

valence electrons– they try to make bonds and interact

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

are most elements stable?

A

no

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

what is the pauli exclusion principle

A

there can’t be two electrons in the same energy state (w same spins)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

what to remember when identifying the valence electrons in

A

d is “higher” than s

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

what properties do valence electrons determine?

A

chemical
electrical
themal
optical

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

what side of the periodic table has electropositive elements

A

left (give up electrons)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

what side of the periodic table has electronegative elements

A

right (want electrons)

19
Q

are nonmetals on the right or left of the table

A

right

20
Q

what does a large electronegativity value suggest

A

large tendency to acquire electrons

21
Q

what is the highest value for electroneg

A

4.0 (on the right)

22
Q

what is the lowest value for electroneg

A

0.7 Fr

23
Q

what are the four primary bonds

A

ionic, covalent, mixed, and metallic

24
Q

what are secondary bonds

A

van der waals

25
Q

what does ionic bonding occur between

A

positive and negative ions (two elements with very different electronegativity)

26
Q

what does ionic bonding require

A

electron transfer

*and large dif in electroneg

27
Q

what do the metals and nonmetals do in ionic bonding

A

metals donate e
nonmetals accept e

28
Q

when you form any system, what does it mean in terms of energy?

A

it always takes the lowest possible energy state

29
Q

(picutre of the attraction thign for ionic bonding)

what does the bottom point show on the graph?

A

repulsive energy stays at the top because it’s always positive

the minimum of the curve responds to the steady state?

30
Q

what kind of energy does attractive have between charges

A

negative because it’s potential, coulomb force

31
Q

what’s the equation associated with energy attractive and repulsive

A

picture

32
Q

what kind of bonding happens in ceramics?

A

ionic

33
Q

what kind of elements covalent bond

A

ones with similar electroneg, they share the electrons

34
Q

what orbitals dominate bonding in covalent bonding?

A

s and p

35
Q

explain how methane covalent bonds?

A

add pic

36
Q

what is mixed bonding?

A

ionic-covalent mixed bonding

37
Q

what is an important measurement when looking at mixed bonding

A

% ionic character

38
Q

what are X sub A and X sub B

A

pauling electronegativities

39
Q

how does metallic bonding work

A

a delocalized electron cloud (sea of electrons)

40
Q

(slides on van der waals)

A
41
Q

slides from summary slide

A
42
Q

describe the energy and direction of ionic bonding

A

large bond energy and directional bonding energy

43
Q

what is the coefficient of thermal expansion of a material?

A

pictures of formulas

44
Q
A