Lecture 1 Flashcards

-Atomic number+ Atomic Mass -Isotopes -Lewis Structure - Octet rule -Covalent and Ionic Bonding

1
Q

Arrangement of elements in the periodic table is based on ……

A

Reactivity which is determined by valence electrons

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2
Q

What is the atomic number?

A

Number of protons in the nucleus- in neutral atoms is same as number of electrons.

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3
Q

What is the mass number

A

Number of protons and neutrons (nucleons) in the nucleus

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4
Q

What property is determined by mass number?

A

Physical properties

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5
Q

What property is determined by electrons?

A

Chemical reactivity

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6
Q

Why is mass number not a whole number?

A

Elements vary in number of neutrons (isotopes) abundance is calculated

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7
Q

Define isotope

A

Atoms with same number of protons different number of neutrons

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8
Q

What are the 3 isotopes of H?

A

Protium H
Deuterium 2H
Tritium 3H

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9
Q

Which isomer of hydrogen is reactive?

A

Tritium

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10
Q

Define Radioisotope

A

Radioactive isotope it breaks down

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11
Q

Why do radioisotopes breakdown

A

Due to unstable nuclei
Unstable ratio of protons: neutrons

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12
Q

Define Half Life

A

Time taken for activity of a radioactive substance to 1/2 as a result of radioactive decay

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13
Q

What is it meant by “half life of tritium is 12.32yrs”?

A

Half of tritium will degrade in 12.32 yrs

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14
Q

How to calculate molecular mass

A

Sum of atomic masses in a molecule

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15
Q

Why is CDCL3 used as NMR solvent and not CHCl3?

A
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16
Q

What is the difference of C14 with the other isotopes?

A

-Radioactive form (unstable nuclei)
- trace amounts

17
Q

Uses of C14

A

Carbon dating

18
Q

Explain carbon dating
Why is c14 suitable?

A
19
Q

What does degenerate mean?

A

Orbitals have same energy level

20
Q

Rules for writing electronic configurations

A
  • Max 2e in each orbital
  • e have opposite spins
  • e fill empty degenerate orbitals before start pairing
21
Q

Why e don’t repel each other in orbitals?

A

e have opposite spins so produce opposite magnetic fields so e attract each other

22
Q

What does the lewis symbol represent?

A

Represents valence electrons as dots

23
Q

Valence electron means

A

Electrons in the outermost shell

24
Q

Can group number be used to calculate valency

A

Group number= valency number

25
Q

What does the Octet rule state?

A

Atoms gain/ lose e to obtain noble gas electronic configuration( usually 8e)
So they get a stable full shell

26
Q

Why are noble gases unreactive?

A

Have full, stable electronic shell- octet rule met

27
Q

Medical uses of Xenon

A
28
Q

What is ionic bonding?
Which type of atoms form ionic bond?
Property of ionically bonded structures

A

Electrostatic force of attraction b/w cation and anion creat solid crystal structures with high mp and bp

29
Q

What is covalent bonding?
Which type of atoms form covalent compounds?
Structure of covalent compounds

A

Sharing pair of e b/w 2 non metals
Molecules with low mp and bp are produced