Lecture 1 Flashcards
Organic Chemistry
Study of carbon compounds except CO2, CO, carbides and carbonates.
Characteristics of carbon
small
can form strong covalent bonds with itself
can form bonds with 4 other atoms
it is moderately high in electronegativity (2.5)
it can form single, double and triple bonds
it form strong bonds with CHONS, some metals and halogens
Applications of organic chemistry
Manufacture of: solvents paints pharmaceuticals adhesives
Properties of organic molecules
covalent bonding
weak intermolecular forces so low melting and boiling points
non soluble in water because most are non polar
the few polar ones are soluble because the carbons are bonded to N/S/O so they are able to form hydrogen bonds with water.
Electronic Configuration
Ground state: 1s2 2s2 2p2
Excited state: 1s2 2s1 2p3
Hybridisation and bonds
Hybridisation is the combination of two or more atomic orbitals to form a new set of atomic orbitals called hybrid orbitals.
pi bonds are formed by side by side overlap
sigma bonds are formed by end to end overlap
Formation of different bonds
Single bonds: sp3, tetrahedral
double bonds: sp2, trigonal planar
triple bonds: sp, linear