lec 11: Greenhouse Gases Flashcards
what are the 3 main natural greenhouse gases?
- Carbon dioxide
- methane
- water vapor
How do 2 atoms gas molecules move? Name 2 of them.
They move by stretching
Oxygen
Nitrogen
How do >2 atoms gas molecules move?
stretching and bending
Why is it that some >2 atom gases molecules interact with infrared radiation and some don’t ?
For some molecules, the rate of the bending movement can fall into the wavelength range of infrared radiation
If they are interacting, energy is being absorbed!
How does infrared radiation and bending molecules interact?
infrared radiation causes bending vibrations to move more vigorously, they then absorb more kinetic energy, which they will later release when slowing down
(some to space = lost, some to earth = heat)
What is a chemoautotroph?
life that uses inorganic substances as electron donors or acceptors (exclude either carbon, oxygen or both)
what are 2 reactions where molecules other than carbon are the electron donor (O2 is the electron acceptor)?
- Nitrification
- sulphur oxidation (bacteria)
what are 4 Reactions where molecules other than oxygen are the electron acceptor?
- Denitrification
- Sulphate reduction
- Iron reduction
- methanogenesis
what are the 2 ways to compare greenhouse gases?
- Residence time
- global warming potential
What is residence time?
- the amount of time a greenhouse gas remains in the atmosphere reservoir
What is the global warming potential? (GWP)
- measure of the contribution of a gas on global warming, using CO2 as a standard
- For a given time period: how much infrared energy 1 ton of gas will absorb compared to 1 ton of CO2
- often measured out of 100 years
What are the 3 most impactful gases based on GWP, residence time, current atmospheric concentration and human influence
- CO2
- methane
- nitrous oxide
what is the natural source of methane?
-methanogens
- bacterial species
- found in areas lacking oxygen
- animals which ferment their food during digestion
What are the anthropocentric sources of methane?
- agriculture
- animal industry → cows
- crops (rice in particular)
- energy
- natural gas is mainly methane
- processing of petroleum releases methane
what is the biggest contributor to methane production and why?
the cattle industry because of
1. methanogenesis, which takes place during the digestion of foods in ruminant mammals (cows)
2. the huge biomass of cows globally results in a high impact
what is permafrost?
- Soil water which has remained frozen for a minimum of 2 continuous years
what is the positive feedback loop between melting permafrost and increasing atmospheric temperature
melting permafrost = more atmospheric GHG = increasing temperatures = melting permafrost
what is the natural source of nitrous oxide?
it is part of the nitrogen cycle
- produced by bacteria in the soil
- lightning breaking N3 bonds in the atmosphere
What are the anthropocentric sources of nitrous oxide?
- anthropocentric nitrious oxide
- produced as a byproduct of agriculture
- nitrogen fertilizer used for crops feed bacteria, which produce more nitrous oxide
- lesser contributor to greenhouse gases, but increasing
- produced as a byproduct of agriculture
How is nitrous oxide removed from the atmosphere
- removed from the atmosphere by bacteria, breakdown by UV radiation
What is the equation for residence time?
R.T = Excess particular gaz / net particular gas sink
What is the equation for energy transfer efficiency?