Le Chateliers Principle 4 Flashcards
K = product/reactant
How can a system be disturbed
Changing the reactant and product
Changing the pressure and volume
Changing the temperature
Adding inert gas
1. At constant volume
2. At constant temperature
Kc=[pcl3] [cl2] / [pcl5] qc= [pcl3][cl2] / [2pcl5]
When the reactant concentration is double
Means Kc /2
Because rate is decreases the reaction move in forward directions
Pcl5 —pcl3 + cl2
When cl2 is doubled
Reaction move in reverse direction
Pressure change karne se
Kc ki value me kabhi bhi change nhi aata
Bsss uski position change hoti hai
Jab tk h”amara temperature Constant hai tb tk Koi Change nhi Atta
Agr hum, volume decrease kare to pressure of system will increases
To decrease pressure reaction will shift toward the side where no of gaseous moles is less
When we add inert gas at constant volume in an equilibrium
Then there will be no change in kp and kc value
The addition of an inert gas at constant pressure
The equilibrium shift towards the greater no. Of moles
Mtlb ki inert gas Dayne se pressure decrease ho jata hai to ye shift ho jata hai towards more no. Of gaseous moles
Write the formula of vant Hoff equation
Ln [ K2/ K1 ] = delta H/R [ T2 -T1 /T1xT2 ]