Laws Flashcards
Boyles Law
At constant temp., the volume occupied by a fixed amount of gas is inversely proportional to the applied (external) pressure.
PV= a constant
Pv1 Vv1 = Pv2 Vv2
Charles’s Law
At constant pressure, the volume occupied by a fixed amount of gas is directly proportional to its absolute temp.
V= constant x T
Vv1/Tv1 = Vv2/Tv2
Avogadro’s Law
The volume of a gas at constant temp. and pressure is directly proportional to the number of moles of the gas
V = constant x n
n= # of moles of the gas
Vv1/nv1 = Vv2/nv2
Ideal-Gas Law
combined laws, gas that exhibits linear relationships among V, P, T, and n.
V= RnT/P
PV=nRT
R= 0.0821 atm•L/mol•K
Dalton’s Law
The total pressure of a mixture of gases equals the sum of the pressures that each would exert if it were present alone.
Pvtotal= Pv1 + Pv2 + Pv3 +…
Pv1= (nv1/nv2)Pvt= Xv1Pvt
Density of Gases
D=m/v
D=MP/RT M=molecular weight
PV=nRT
The Molar Mass of a Gas
M=mRT/PV
R=0.0821 atm•L/mol•K
Graham’s Law
The rate of effusion of a gas is inversely proportional to the square root of its molar mass
Rate of effusion= amount of gas effused/unit time
r= n/t
rv1/rv2 = square root of Mv2/Mv1
Gay-Lussacs Law
Pv1Tv2=Pv2Tv1