Lattice enthalpy Flashcards

1
Q

define lattice enthalpy

A

enthalpy of formation of 1 mol. of an ionic lattice from gaseous ions

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2
Q

what does lattice enthalpy measure

A

the strength of ionic bonding in a giant ionic lattice

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3
Q

is LE exo/endothermic

A

exothermic

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4
Q

what does route 1 in the Born Haber cycle include

A

formation of gaseous atoms

formation of gaseous ions

lattice enthalpy

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5
Q

what does route 2 in the Born Haber cycle include

A

enthalpy formation directly to LE

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6
Q

define standard enthalpy of formation

A

the enthalpy change when 1 mol. of compound is formed from its elements under standard conditions and states

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7
Q

is enthalpy of formation exo/endothermic?

A

exothermic

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8
Q

define standard enthalpy change of atomisation

A

enthalpy change when 1 mol. of gaseous atoms are formed from its elements under standard conditions and states

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9
Q

is enthalpy change of atomisation endo/exothermic

A

endothermic

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10
Q

why is enthalpy change of atomisation endothermic

A

bonds are broken to form gaseous atoms

bond enthalpy of the bond is broken

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11
Q

define first ionisation energy

A

when 1 e- is removed from each atom in 1 mol. of gaseous atoms to form 1 mol. of gaseous 1+ ions

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12
Q

is first ionisation energy exo/endothermic

A

endothermic

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13
Q

why is first ionisation energy endothermic

A

energy needed to overcome attraction btwn -ve e- and +ve nucleus

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14
Q

define first e- affinity

A

when one e- is added to each atom in 1 mol. of gaseous atoms to form 1 mol. of gaseous 1- ions

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15
Q

is first e- affinity exo/endothermic

A

exothermic bcs e- added is attracted to nucleus

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