Lattice enthalpy Flashcards
define lattice enthalpy
enthalpy of formation of 1 mol. of an ionic lattice from gaseous ions
what does lattice enthalpy measure
the strength of ionic bonding in a giant ionic lattice
is LE exo/endothermic
exothermic
what does route 1 in the Born Haber cycle include
formation of gaseous atoms
formation of gaseous ions
lattice enthalpy
what does route 2 in the Born Haber cycle include
enthalpy formation directly to LE
define standard enthalpy of formation
the enthalpy change when 1 mol. of compound is formed from its elements under standard conditions and states
is enthalpy of formation exo/endothermic?
exothermic
define standard enthalpy change of atomisation
enthalpy change when 1 mol. of gaseous atoms are formed from its elements under standard conditions and states
is enthalpy change of atomisation endo/exothermic
endothermic
why is enthalpy change of atomisation endothermic
bonds are broken to form gaseous atoms
bond enthalpy of the bond is broken
define first ionisation energy
when 1 e- is removed from each atom in 1 mol. of gaseous atoms to form 1 mol. of gaseous 1+ ions
is first ionisation energy exo/endothermic
endothermic
why is first ionisation energy endothermic
energy needed to overcome attraction btwn -ve e- and +ve nucleus
define first e- affinity
when one e- is added to each atom in 1 mol. of gaseous atoms to form 1 mol. of gaseous 1- ions
is first e- affinity exo/endothermic
exothermic bcs e- added is attracted to nucleus