last minute exam 1 thingz Flashcards
_____ forms only Zaitsev products
E1
____ forms Zaitsev and Hoffman products
E2
____ must be anti peri planar to eliminate
E2
reaction with PBr3
-turns primary/secondary alcohols to bromo-alkanes
reaction with PBr3 is beneficial because…
it has less rearrangements than H-Bra
which oxidizing agents oxidize primary alcohols into an aldehyde?
PCC and HOCl (sometimes NaOCl)
which oxidizing agent turns primary alcohols into aldehydes AND THEN carboxylic acids ?
H2CrO4
examples of alkyl sulfonates and their purpose
Ts-Cl and Ms-Cl
they turn alcohols into sulfonate esters, which are good leaving groups
reaction of alcohols with ___ turn primary and secondary alcohols into alkyl chlorides
SOCl2
reaction with SOCl2 requires a…
base such as pyridine or triethylamine
nucleophilic substitution of ethers: Sn1 or Sn2?
will do Sn1 unless it has to form a primary carbocation
IUPAC: ethers
replace “yl” ending of subsistent nameI with “oxy”
IUPAC: epoxides
name as an alkane, with “epoxy” prefix to indicate the carbon to which oxygen is attached
glycols are cleaved by oxidation with…
Periodic acid, HIO4
