Lab Techniques- DAT Orgo Flashcards
Br2/CCl4
Test for:
Negative:
Positive:
Br2/CCl4
Test for: Alkenes & Alkynes
Negative: BROWN
Positive: COLORLESS
KMnO4
Baeyer Test
Test for:
Negative:
Positive:
KMnO4
Baeyer Test
Test for: Alkene, Alkyne, Aldehyde, Phenol
Negative: Purple
Positive: BROWN
Acyl Chloride test
Test for:
Negative:
Positive:
Acyl Chloride test
Test for: Alcohols, 1 and 2 Amines
Negative: NR
Positive: Evolution of Heat and HCL gas/ precipitate
Lucas Test
ZnCl2
Test for:
Negative:
Positive:
Lucas Test
ZnCl2
Test for: 2 and 3 Alchols Negative: NR Positive: Cloudy Second Layer or Emulsion 2-3 min = 3 OH 5-10 min = 2 OH
Jones Test
Cr2O7^-2
Test for:
Negative:
Positive:
Jones Test
Cr2O7^-2
Test for: 1 and 2 OH and Aldehydes
Negative: Orange
Positive: Blue/Green
2,4 DNP
Test for:
Negative:
Positive:
2,4 DNP
Test for: Aldehydes + Ketones
Negative: NR
Positive: Precipitate (solid)
Tollen’s Test
Ag(NO3)2+
Test for:
Negative:
Positive:
Tollen’s Test
Ag(NO3)2+
Test for: Aldehydes
Negative: NR
Positive: Silver Mirror
Sodium Bicarbonate
NaHCO3
Test for:
Negative:
Positive:
Sodium Bicarbonate
NaHCO3
Test for: Carboylic Acids
Negative: NR
Positive: Evolution of CO2 gas
What does NMR determine?
NMR determines the structure of a compound
What does IR determine?
Recognizes functional groups
Reducing Sugars (Benedict’s Test)
All aldoses and most ketoses, and hemi-acetals/hemi-ketals are _____.
All acetals/ketals are _________.
Reducing Sugars (Benedict’s Test)
All aldoses and most ketoses, and hemi-acetals/hemi-ketals are REDUCING
All acetals/ketals are NON-REDUCING SUGARS
Monosaccharides include: (3 items)
Glucoes, Fructose, Galatose
Oligosaccharides include:
Sucrose( Glu + Fru)
Lactose(Glu + Gal)
Polysaccharides include:
Starch, glycogen, cellulose, chitlin, etc.
Atoms next to “O” or “N” would be more to the left(_____),
Then those next to O=C is (_________)
- DOWNFIELD
2. UPFIELD