Lab Tech Flashcards

1
Q

The following will cause drift errors in an analytical balance EXCEPT
A. Balance door is open.
B. Balance is not levelled
C. Air currents are present in the laboratory.
D. Temperature of the balance and the sample to be weighed is the same.

A

D

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2
Q

Objects cannot be weighed when hot or warm. But if you were to take a sample out and wait for it to cool it would pick up moisture so it should be placed in a/an/at
A. oven
B. desiccator
C. room temp
D. fume hood

A

B

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3
Q

It is the nominal volume of water (or mercury) contained, or delivered by an article of volumetric glassware, at its reference temperature.
A. accuracy
B. calibration
C. capacity
D. measurand

A

C

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4
Q

A student is tasked to measure 12 mL of a liquid as precisely as possible. Which measuring device should be selected for this task?
A. 25 mL beaker
B. 25 mL graduated cylinder
C. 25 mL conical flask
D. 25 mL volumetric flask

A

B

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5
Q

Which of the following is TRUE about TC pipets?
A. TC means “to carry”.
B. It commonly does not have a colored band.
C. It is used if the liquid left in the pipet is already accounted.
D. None of the above.

A

D

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6
Q

A student needs to transfer his precipitant from the beaker to the filter paper. Which of the following would be the best procedure in order to ensure a quantitative transfer of the precipitate?
A. Most of the supernatant liquid is decanted then bulk of precipitate is transferred to filter paper through a stirring rod, then the beaker is washed with large volumes of wash solution.
B. Most of the supernatant liquid decanted first, then bulk of the precipitate is transferred through a stirring rod. The beaker is washed several times with small volumes of wash solution.
C. Solution is shaken, then immediately filtered; beaker is washed with big volumes of wash solution.
D. None of the above.

A

A

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7
Q

To determine the density of a liquid, which of the follewing should be used?
A. graduated cylinder
B. volumetric flask
C. pycnometer
D. pipette

A

C

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8
Q

Which is TRUE for a 19/22 stopper?
A. radius =19 mm, height = 22 mm
B. radius = 22 mm, height = 19 mm
C. diameter = 19 mm, height = 22 mm
D. diameter = 22 mm, height = 19 mm

A

C

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9
Q

Which technique is recommended for determining the odor of an unknown liquid in the laboratory?
A. Hold a test tube of the liquid under the nose and inhale the vapor.
B. Transfer a few drops of the liquid to the bench top and inhale the vapor from there.
C. Use a dropper to collect a small quantity of the vapor and squirt this under the nose while inhaling.
D. Use a hand to fan some of the vapor from the test tube to the nose and inhale.

A

D

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10
Q

The size of the sample taken for analysis depends on the ________
A. concentration of analyte
B. equipment to be used
C. specific chemical tests
D. all of the above

A

D

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11
Q

Possible sources of contamination during sample preparation include
A. reagents
B. glassware from previous experiment
C. equipment from previous experiment
D. all of the above

A

D

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12
Q

Which of the following can cause errors during the sample preparation?
I. Loss of sample during weighing or dissolution.
Il. Contamination by impurities in reagents and in the environment.
Ill. Changes in mass due to varying humidity and temperature.
IV. Obtaining nonhomogeneous sample from the bulk.
A. I and II only
B. I, III, and IV
C. I, II, and III
D. I, II, IlI, and IV

A

D

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13
Q

Method of passing the sample through a metal or plastic mesh of a uniform cross-sectional area to separate particles into uniform sizes.
A. sieving
B. milling
C. pulverizing
D. macerating

A

A

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14
Q

Which of the following can remove a fairly large amount of water from a sample that contains thermally labile material?
A. hotplate
B. freeze dryer
C. convection oven
D. microwave equipment

A

B

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15
Q

Sample preparation technique used prior to instrumental analysis of metals.
A. sieving
B. clean-up
C. acid digestion
D. liquid-liquid extraction

A

C

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16
Q

Which of the following should NOT be used during dry ashing?
A. Zirconium
C. Porcelain
B. Platinum
D. Glass

A

D

17
Q

In an experiment to determine the percentage of water in a solid hydrate by heating, what is the best indication that all the water has been removed?
A. The solid melts.
B. The solid changes color.
C. Water vapor no longer appears.
D. Successive weighings give the same mass.

A

D

18
Q

Which of the following statement(s) is(are) TRUE?
I. Dry ashing is primarily for proximate composition and for some types of specific mineral analyses.
Il. Wet ashing is done as a preparation for the analysis of certain minerals.
IlI. Microwave systems are now available for both dry and wet ashing to speed the processes.
A. I only
B. II only
C. I and Il only
D. I, Il, and Ill

A

C?

19
Q

In the decomposition and dissolution of solids during sample preparation, which of the following is expensive and often the last resort?
A. fusion technique
B. simple dissolution
C. acid treatment using oxidation
D. dissolution using ultrasound and solvent

A

A

20
Q

All of the following are properties of an organic solvent for extraction EXCEPT
A. dissolve the desired substance
B. react with the desired substance
C. not react or be miscible with water
D. has a low boiling point so it can be easily removed at a later purification step

A

B

21
Q

This is done during liquid-liquid extraction to release the pressure build-up inside the separatory funnel during shaking.
A. stirring
B. venting
C. drawing
D. salting out

A

B

22
Q

Which of the following should NOT be done when an emulsion is formed during extraction?
A. stirring the emulsion gently using a stirring rod
B. adding sal crystals to the mixture and then string it gently
C. adding a salt solution to the mixture and then stirring it gently
D. shaking the separatory funnel containing the mixture very vigorously

A

D

23
Q

In liquid-liquid extraction, it is often necessary to determine the aqueous and organic layers. To test the layers, a drop of water can be added to the top layer. If the drop of water dissolves in the top layer, then the top layer is
A. organic
B. aqueous
C. denser
D. nonaqueous

A

B

24
Q

This is used to remove trace amounts of water in organic solutions. This can be added to the AIr‹ pooled organic layers before removal of the organic solvent.
A. drying agent
B. boiling stone
C. seed crystal
D. none of the above

A

A

25
Q

A 5-g organic solid is dissolved in 100 mL of distilled water. What is the best way to recover most of the organic solid?
A. Single extraction using 150 mL ether.
B. Single extraction using 150 mL acetic acid.
C. Multiple extraction using three 50-mL portions of ether.
D. Multiple extraction using three 50-mL portions of acetic acid.

A

C

26
Q

Which of the following is/are considered in purification using crystallization?
I. Polarity
II. Solubility
III. Vapor pressure
A. I only
B. II only
C. I and Il only
D. I, II, and III

A

D

27
Q

Which of the following funnels should be used to filter hot mother liquor during recrystallization?
A. Hirsch funnel
B. Büchner funnel
C. long stem funnel
D. short stem funnel

A

D

28
Q

In crystallization, crystal phases can be interconverted by varying
A. temperature
B. pressure
C. viscosity
D. size

A

A

29
Q

All of the following statements are TRUE, EXCEPT
A. Two different pure substances have similar melting points.
B. An impure sample of a substance has a wider melting point range.
C. Melting point serves as an index of purity of a solid crystalline substance.
D. Every pure solid crystalline substance has a characteristic and unique melting point.

A

A