Lab 4. Tensile Test Plastic Flashcards

1
Q

polymer is

A

an organic substance composed of molecules with large molecular mass composed of repeating structural units……

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2
Q

what is a polymer connected by

A

covalent bonds… may contain hundreds or thousands of repeat units

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3
Q

what is small definition of polymer.

A

many chains.

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4
Q

name two forces that hold polymer chains together

A

covalent molecules and van-der-waals

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5
Q

Difference between monomer and repeat units

A

A monomer is a single molecule, a polymer is a long chain of monomers, repeating units are a simplified method of drawing a polymer, whose chain may extend for a long time.

Show example

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6
Q

name some natural polymers

A

proteins, enzymes, starches, and cellulose

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7
Q

where are natural polymers important

A

biological and physiological processes in plants and animals

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8
Q

plastics

A

are materials that have some structural rigidity under load, and are used for general-purpose applications

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9
Q

elastomers-

A

polymer which contributes to rubber, fibers, adhesives, films and foams

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10
Q

name some plastics

A

polyethylene, polypropylene, polystyrene, fluorocarbons, epoxies,

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11
Q

what are the two types of polymers/plastics

A

thermoplastics and thermosetting

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12
Q

qualities of thermoplastics

A

high molecular weight, soften or liquid when heated, harden when cool, process is reversible regardless of repeated cycles

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13
Q

qualities of thermosettings

A

(polymers that cure, through the addition of energy/heat to a stronger forms by a cross-linkage process)

harden or solidify when heated

irreversible process (thermoset materials cannot be easily melted and re-shaped after i is cured

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14
Q

crosslinkage of thermoplastic

A

little to none

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15
Q

crosslinkage of thermoset

A

alot network

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16
Q

what are factors the influence properties of polymers/plastics

A

Molecular weight
degree of polymerization
molecular structure

17
Q

linear polymers

A

van der waals bonding between chains.

18
Q

branched polymers

A

chain packing efficiency is reduced compared to linear polymers lower density

19
Q

cross-linked polymers

A

chains are connected by covalent bonds. often achieved by adding atoms or molecules that form covalen links between chains. many rubbers have this strucuture

20
Q

network polymers

A

3D networks made from trifunctional mers.

21
Q

give in the direction of increasing strength, the type of crosslinkage

A

linear, branched, crosslinked, network

22
Q

how are amorphous plastics bonds

A

they have no strong bonds between molecular chains

23
Q

how are bondings with crystalline plastics

A

they have strong bonds between molecular chains

24
Q

an amorphous/semi crystalline plastic will exhibit….

A

a glass transition temperature TvG

25
Q

below glass transition temperature molecules have….

A

little relative mobility

26
Q

above glass transition temperature molecules have….

A

great mobility

27
Q

what is the glass transition temperature usually around

A

.5-.8 of the melting temperature….

28
Q

glass transition temperature-

A

often define the maximum service temperature of plastics and control very important processing parameters

29
Q

like metals,….

A

plastics yeild at the end of the elastic region

plastics also start necking

30
Q

what happens during necking?

A

the molecule chains stretch from agglomerated polymers to aligned polymers

31
Q

plastics can endure….

A

significant strain after the onset of necking

32
Q

brittle deformation

A

does not cause to much molecular stretches and plastic region during the failure. it is usually seen in thermosetting and glassy polymers

33
Q

plastic deformation

A

is defined by the interaction between crystalline and amorphous regions, and it is partially reversible

34
Q

crazes

A

are regions of very localized plastic deformation, which lead to the the formation of small and interconnected microvoids

35
Q

as the tensile stress enlarges a craze, the stress introduced…

A

will be distributed over an increasing volume which means that force peaks are avoided.

36
Q

.what are some advantages of plastics

A

good electrical insulation
good thermal insulation

high specific strength..strength/weight per unit volume

can be recycled

low density
application in composite materials

37
Q

disadvantages of plastics

A

low toughness
less resistance to abrasion

can produce hazaradous fumes when burned

in general, cannot be used in high temperature applications

although special utlra high temperature resistant plastic is available.