L7 - Uranium Flashcards

1
Q

What is the primary use of uranium?

A

As fuel for nuclear power generation.

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2
Q

What type of uranium is stable in reducing conditions?

A

Uranous (U⁴⁺), which is relatively insoluble

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3
Q

What type of uranium is stable in oxidizing conditions?

A

Uranic (U⁶⁺), which is soluble and forms stable aqueous complexes and minerals

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4
Q

What is the dominant process that concentrates uranium in granitic rocks?

A

Igneous processes associated with the lithophile behavior of uranium

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5
Q

Write the equation for radiometric dating

A

N=N0⋅e −λt , where N is measured radioactive nuclides, N0 is original nuclides, λ is the decay constant, and t is time.

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6
Q

What are the conditions required for uranium to sustain a nuclear chain reaction?

A

Enriched 235U (>3–4% for reactors, >90% for weapons) and a critical mass.

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7
Q

What are the main uranium minerals?

A

Uraninite (UIVO 2), Pitchblende (UIV 3 O8), Brannerite, Carnotite, and Autunite

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8
Q

Which countries are the top uranium producers as of 2021?

A

Kazakhstan (46%), Canada (10%), and Australia (8%).

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9
Q

Which country has the largest identified recoverable uranium resources?

A

Australia, with 28% of the world’s identified resources.

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10
Q

What are the main types of uranium deposits?

A

Magmatic, magmatic-hydrothermal, sedimentary, unconformity-related, placer, roll-front, and weathering deposits.

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11
Q

What are unconformity-related deposits?

A

Deposits at the boundary of Proterozoic sediments and basement rocks, with hydrothermal fluid circulation at redox fronts (e.g., Athabasca Basin).

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12
Q

What is a roll-front deposit?

A

A deposit formed by oxidizing groundwater interacting with reducing agents, precipitating uranium at a curved redox front.

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13
Q

Where are placer deposits commonly found?

A

In quartz-rich conglomerates like Witwatersrand (South Africa) and Eliot Lake (Canada).

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14
Q

Where is the natural nuclear reactor located?

A

Oklo, Gabon, in a Proterozoic sedimentary basin

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15
Q

What are the conditions for natural reactor criticality?

A

High 235U/ 238U ratio, >10–20% uranium concentration, minimum ore thickness >50 cm, and high water/rock ratios.

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16
Q

How long did chain reactions occur in the Oklo natural reactor?

A

Between 20,000 and 600,000 years

17
Q

What temperature range did the Oklo natural reactor maintain?

A

Core temperatures below 1,000°C with a gradient of 100°C/m

18
Q

What are the main methods of uranium mining?

A

Open-pit, underground mining, and in-situ leaching (ISL).

19
Q

What is the primary environmental hazard associated with uranium mining?

A

Radon gas exposure and radioactive dust.

20
Q

What are the environmental concerns with uranium tailings?

A

Radiation hazards, groundwater contamination, and ease of airborne dispersion in powdered form

21
Q

What is the enrichment level of uranium for reactor fuel?

A

3-4% 235U

22
Q

What is the enrichment level of uranium for weapons?

A

over 90% 235U

23
Q

what is yellowcake?

A

a concentrated uranium product (ammonium diuranate) containing 70-90% U3O8

24
Q

Why are uranium deposits associated with redox processes?

A

Uranium changes oxidation states, precipitating at redox fronts, concentrating the element.

25
Q

What geological processes helped form uranium-rich sandstone deposits?

A

Hydrothermal fluid circulation and the interaction of oxidizing and reducing conditions

26
Q

What insight do natural reactors provide about Earth’s history?

A

They demonstrate past conditions of uranium enrichment, changes in Earth’s atmosphere, and natural chain reaction physics