L6 Alternative sweeteners and fat replacers Flashcards

1
Q

What is the definition of lipids?

A

A family of compounds soluble in organic compounds but not in water

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2
Q

What are the functions of lipids?

A

Source of high energy value
Contains fat-soluble vitamins and essential fatty acids.
Lipids combined with proteins are important constituents of the cell membranes and mitochondria of the cell.
Lipids are storage compounds, triglycerides serve as reserve energy of the body.

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3
Q

What are the sensory profiles of Lipids?

A
Appearance
Gloss, color, surface uniformity, crystallinity
Texture
Viscosity, elasticity, hardness
Flavor
Carriers of flavours
Mouthfeel
Creaminess, lubricity, thickness, mouth feel of the product
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4
Q

What are the issues with lipids?

A

Fats that are highly unsaturated, are not expected to be stable at room temperature thus producing early onset of rancidity and possible shelf-life issues. If shelflife is increased through the process of hydrogenation, saturation and production of trans fats as by-products happen, thus posing health concern to consumers. Thus fat replacers are used to replace fats

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5
Q

How does the degree of saturation affect melting point?

A

Gain this melting point is related to the degree of saturation in fats. Higher saturated fats have high melting points compared to unsaturated fats as shown in the example

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6
Q

What are the uses of omega 3 fatty acids?

A

Omega 3 fatty acids cannot be made by the body and must be gotten thru food.
Integral part of cell membranes and affect the function of cell receptors in these membranes.
Provide a starting point for making hormones
Bind to receptors that regulate genetic functions
Help prevent heart disease and stroke

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7
Q

How do fats exist in food?

A

Fats exist in emulsions in 2 phases continuous and dispersed. Continous is the one surrounding everything and dispersed is the one suspended.

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8
Q

Why are fat replacers needed and what is the challenges in replacing fats?

A

Consumer awareness on different types of fats and their impacts on health
The challenge is to produce low-fat/no-fat products with physical and sensory characteristics as close as possible to full-fat quality
Considerable changes in traditional recipes for food industries- another major challenge

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9
Q

What are some requirements of fat replacers?

A

Fat replacers need to
Provide a similar mouth feel to fat – thick, viscous, creamy
Provide bulk to the food
Heat stable so that it can be used for frying and baking
Not so easily digested as fats

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10
Q

What are the 3 categories of fat replacements and what are they made out of?

A

Carbohydrate-based
Starch and starch hydrolysis products
Fiber based (gums, gels, thickeners, bulking agents)

Protein-based
Specially processed proteins
Protein/fiber combinations

Lipid-based
Synthetic fat substitutes
Low-calorie fats
Emulsifiers

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11
Q

Explain the product Simplesse.

A

Made of microparticulated whey protein
Microparticulation:

process produces uniform microparticles averaging 1 mm in diameter, and prevents the formation of large protein agglomerates.

Microparticulated protein has been proven to be more digestible than other proteins.

Microparticles, in suspension, behave like a creamy fluid so give the same mouthfeel as fat

Less calories per g – approx 4 cal/g [cf fat – 9 cal/g]

Not so good for cooking so found more in salad creams, ice-cream

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12
Q

Explain the product Olestra.

A

Chemically similar to a triglyceride

It is part fatty acids and part sucrose

Fatty acids are so bulky that enzymes
Cannot penetrate to hydrolyse the sucrose-fatty acid bond

Olestra passes through gut undigested.
So effectively 0 cal/g

Heat stable so can be used in cooking

Side effects: abdominal cramping, loose stools and inhibits the absorption of certain vitamins and other nutrients.

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13
Q

Explain the product miracle whip.

A

One of the earliest low fat products using fat replacer

Introduced in 1930’s

Miracle Whip was formulated to provide about half the fat of conventional mayonnaise using a starch gel at about one tenth the level of the fat that it was replacing

Miracle Whip is made from water, soybean oil, high-fructose corn syrup, vinegar, modified corn starch, eggs, salt, natural flavor, mustard flour, potassium sorbate, spice, and dried garlic

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14
Q

Issues with sugar?

A

Our bodies are not designed to consume such large quantities of refined and pure carbohydrates.

Releasing large quantities of sugar into the bloodstream creates a shock to the system, and the body reacts by producing insulin.

This can put a strain on the pancreas and liver and over time lead to the development of diabetes.

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15
Q

What is the glycemic effect/index?

A

The Glycemic Index is an indication of how quickly a specified amount of food will cause a rise in blood sugar level.

Foods which are easy to digest generally have a high glycemic effect
(standard is pure glucose).

High glycemic foods – should be avoided by diabetics

The glycemic index (or GI) is a ranking of carbohydrates on a scale from 0 to 100 according to the extent to which they raise blood sugar (glucose) levels after eating. Foods with a high GI are those which are rapidly digested, absorbed and metabolised and result in marked fluctuations in blood sugar (glucose) levels. Low GI carbohydrates – the ones that produce smaller fluctuations in your blood glucose and insulin levels

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16
Q
What is the GI Scale for :
Glucose
White Wheat Bread
Whole Wheat/Whole Meal Bread
Specialty Grain Bread
White Rice Boiled
Brown Rice Boiled
Cornflakes
Muesli

and what is considered low,med,high GI.

A
Glucose 100
White Wheat Bread 75+-2
Whole Wheat/Whole Meal Bread 74+-2
Specialty Grain Bread 53+- 2
White Rice Boiled 73+-4
Brown Rice Boiled 68+-4
Cornflakes 93
Muesli 66

GI (based on glucose reference)
Low GI 0 to 55
Intermediate GI 56 to 69
High GI ≥ 70

17
Q

What is ideal for a sugar replacer?

A

Low calorie/no calorie –
Not metabolised in digestive tract – so does not enter circulation
Or much sweeter than sugar – so do not need to eat so much

Stable to heat – e.g. when used in cooking

No bitter after-taste

Do not cause tooth decay

Can be consumed by diabetics

18
Q

What are the 3 types of sugar substitutes?

A

Artificial sweeteners
Not metabolized by the body (no kcals)
Metabolized by the body
Natural sugar replacers

19
Q

Explain Saccharin.

A

Not metabolised by humans – so 0 calories –
but 200 to 700 times sweeter than sugar

Stable at high temperature

It has a zero glycemic index, contains no calories and is suitable for diabetics.

Developed in 1878 but found to cause cancer in lab rats

20
Q

Explain Acesulfame K.

A

Not metabolised by body 0 calories/g – 200x sweeter than sugar

Stable to heat

It is approx 200 times sweeter than sugar, though it has a slightly bitter
Aftertaste.

Zero glycemic index.

Usually mixed with other sweeteners to mix bitter aftertaste.

21
Q

Explain Sucralose. (Splenda)

A

Same as sucrose but 3 –OH groups replaced by Cl
Not metabolised by body 0 calories/g – 600x sweeter than sugar
It does not break down under heat and so is suitable for cooking and in
processed foods.
Number one artificial sweetener in the USA

22
Q

Explain Aspartame.

A

Dipeptide of aspartic acid and phenylalanine

Metabolised by body 4 calories/g – 180x sweeter than sugar
So less likely to eat large quantities of aspartame

Not sweet after heating

23
Q

Why does foods with aspartame state unsuitable for phenylketonurics?

A

A by-product of the metabolism of aspartame is phenylalanine and people with a genetic disorder called phenylketonuria (PKU) are unable to metabolize it.

People with a rare hereditary disease known as phenylketonuria (PKU) have a difficult time metabolizing phenylalanine, a component of aspartame and should control their intake of phenylalanine from all sources, including aspartame. Labels of aspartame-containing foods and beverages must include a statement that informs individuals with PKU that the product contains phenylalanine.

PKU is caused by lack of phenylalanine hydroxylase an enzyme which helps digest phenylalanine.

24
Q

Explain Stevia.

A

Extracted from a S. American plant Stevia rebaudiana
Sweet compounds Stevioside and Rebaudioside,

Not metabolised by body 0 calories/g – 300x sweeter than sugar
Heat stable

Zero glycemic index

Sold as dried and powdered leaves or as concentrated stevioside. Coca cola have a product called truvia, and pepsi have a product called purevia. Both of these are mixtures of rebaudioside

25
Q

Explain sugar alcohols and draw structure.

A

Sugar alcohols are less in sweetness compared to sucrose and these are energy providers but calorie production is less compared to sucrose.

Sorbitol 2.6cal/g
Xylitol 1.5-3cal/g

26
Q

Why is aspartame have a GI index of 0 but has 4 calories/g?

A

Aspartame breaks down into 2 amino acids which are not sugars thus don’t spike calories.