L5 - rate eqns Flashcards
whata approx when soft collisions dominate
adiabatic or wuasi static approx
For large beta what happenes
Any oscillations of the atomic probabilitya re well damped
population rate eqns
drho11/dt and same for 22
R12 meaning
R12 = R21
avsorption and stimulated emission rate
info on R12 params and shape
Lorentzian profile proportinal to |E0|^2 so proportioanl to I of light
If Detuning less the R21 More
R12 definition
Sigma Phi
Sigma depend on v ( freq of incident excitation light)
Sigma
Absorption cross section
Sig dep on detuning
Phi
Photon flux
Associatied with the light field E0
units: Photons per (area time)
Proportional to light intensity (I is macroscopic measuremnet)
Energy of a photon
E = h v(n)
Density of atoms in a state
N1 = N rho11
N2 = N rho22
these are the density of atoms ina given level
Gamma meaning
Inelastic collision energy transition probability
Compare inelastic collisions vs spontatnoues emission
Gamma_12, Gamma_21 «_space;A21
inelatic have little influence comapred to spont emission
so N1 + N2 = NT tends to remain constnat
Steady state we cna assume
Constant photon flux Phi
N2 population
case: NO flux
Phi = 0
N2 = N2(0) exp(-A21 t)
All atoms end up in GS
spont emission dominates ( inelastic collision Gamma not really large enough)
No stimulated processes (due to sigma Phi) i.e. R12,R21
N2 population:
Case: Low flux
Weak excitiation
R21 = sigma Phi != 0 but R21 «_space;A21
So more e- lost from N2 due to spont emission than is brought up by the stimulated absorption
if N2(0) then
N2(t) = constant [1 - exp(-A21t)]
same decaying exp reaches max 1 (t = 0)= > N2 = 0 initially
when t large exp -> and N2 is at a max => SATURATION
N2 population:
Case: Low flux behavrious in graph
Initally asymptotic approach (concave down)
N2 population:
Case: High flux
Strong excitiation
R21 = sigma Phi»_space;A21
stimulated rate»_space; spont emission rate
N2 (t) -> N/2 —– SATURATION
Why high flux not good enough
N - > N/2 saturation
Require population inversion for gain not population equalisation
N2 population:
Case: High flux - Power broadening
Strong excitiation
Assume statead state and exp factor»_space;1
N2(t=infty)/N = lorentzian profile
profile widens with larger X ( larger E0)
So N2(infty)/N becomes broader and taller as E0 flux increases