L2 - The properties of water ; currents and tides Flashcards
What is the water molecule comprised of?
Oxygen atom which is weakly negatively charged. Hydrogen atom which are weakly positively charged. This makes water a polar molecule, but also creates electrical attractions (hydrogen bonds) between adjacent water molecules
What are the three states of water?
Liquid, solid (ice), gas (water vapour). The only known substance on earth to exist naturally in three states
Over what range is water a liquid?
A large temp range. Temperature reflects the average speed of molecules - the faster they move, the higher the temperature. Hydrogen bonds hold most of the molecules together in small groups, but these groups constantly break apart and re-form. When a molecule moves fast enough it breaks free of all the hydrogen bonds and escapes from the liquid phase into the gaseous phase (evaporation).
What is Ices characteristics?
Ice is less dense than water, sinking of cold, dense seawater is a key part of global water circulation. Hydrogen bonds lock the water molecules in a fixed, 3D lattice (a crystal). This means water freezes at a higher temperature than would be predicted
What is heat capacity in terms of water molecules?
These hydrogen bonds means water has one of the highest heat capacities of any known substance. Heat capacity is the amount of heat required to raise a substances temperature.
Aside from heat capacity what other things does water also have very high?
Latent heat of fusion (melting/freezing ; 334 kJ kg-1). Latent heat of vapourisation (evaporation/condensation ; 2,260 kJ kg-1)
What does the prevalence of Waters very high heat capacity, latent heat of fusion and evaporation mean?
Waters ability to absorb a lot of heat for a relatively small increase in temperature means the temperature of water is relatively stable compared with air temperature. Most marine animals are generally not subject to rapid changes in temperature. The global ocean absorbs huge amounts of solar energy and redistributes it around the planet.
What is the prevalence of water being a universal solvent?
Water can dissolve more things than any other natural substance. Especially salts, which dissociate into their component ions (e.g. Na+, Cl-) in water
What is the composition of water?
Cl-, Na+, SO42-, Mg2+, Ca2+, K+, HCO3-, Br-, H2BO3-, Sr2+, F-
What is salinity?
Total amount of dissolved salt in water. Traditionally measured as the amount of salt left behind after seawater evaporated (ppt). Today, salinity is measured via the conductivity of seawater (ions increase the conductivity). Salinity determined from conductivity measurements are technically unitless, but sometimes the term practical salinity units (psu) is used. (psu and ppt are numerically the same, however)
What is the rule of constant proportions?
Oceans are remarkably well mixed, salinity will change : oceanic water is generally ~35, salinity will change across estuaries, rockpools can experience fluctuations in salinity. But this is through the addition/removal of water, not ions
What is the relationship between salinity, temperature and density?
The temp and salinity of seawater determine its density, it gets denser as it gets saltier and colder. Ocean temp varies between -2 and +30. Temperatures below 0 are possible because salt water freezes at a colder temperature than pure water. Temp is the main controller of seawater density.
What are the most important gases in the ocean?
Oxgen, carbon dioxide, nitrogen. Ocean-atmosphere gas exchange
What is the prevalence of oxygen in the ocean?
200ml O2 L-1 air, 0.04 - 12 ml O2 L-1 water (5,000 to 17-times less than in air). O2 decreases as temp or salinity increases. Amount of O2 is strongly affected by photosynthesis and respiration. Seawater is far more susceptible to oxygen depletion by respiration
What is the prevalence of Carbon in the ocean?
CO2 is far more soluble than O2 because it reacts chemically when it dissolves (the carbonate/bicarbonate buffer system). CO2 is >80% of dissolved gas in the ocean. Ocean stores >50 times more CO2 than the atmosphere
What is light transmission in oceans?
Light in water is attenuated through absorption and scattering. Intensity declines with depth, shorter wavelengths transmitted better so red light absorbed first, blue/green absorbed last. No sunlight at all below ~1000m
What is water transparency?
Otherwise referred to as turbidity, strongly affected by suspended and dissolved material. Can be greatly affected by plankton. Coastal waters often contain a lot of terrestrially-derived material and appear greenish. Oceanic water is blue
What increases with depth and in what way?
Hydrostatic pressure increases linearly with depth. 1atm at surface.
Where do the strongest ocean currents occur?
At the surface, where they are caused by wind. Surface currents are, therefore, ultimately driven by heat energy from the sun. Surface currents and winds are also influenced by the coriolis effect.
What is the Coriolis effect?
The Coriolis effect deflects large-scale motion like winds and currents to the right in the Northern Hemisphere and to the left in the Southern Hemisphere.
What is wind driven by?
The winds in our atmosphere are driven by heat energy from the sun. Trade winds (between 30 N/S and equator) are the steadiest winds on earth.
What is the Ekman Transport?
Instead of moving in the same direction as the wind, water at the surface moves at an angle of 45 to the wind (Coriolis effect). Each layer down is deviated a little further (R in N hemisphere, L in S) = Elkman spiral. Effect decreases with depth ; dissapears after a few hundred of metres. Net water movement is 90 to the wind direction.
What does the Coriolis effect mean for equatorial currents?
It means that equatorial currents move parallel to the equator. Water is very good at transporting heat
What do wind-driven surface currents combine into?
They combine into huge, more or less circular systems called gyres. Warm western currents carry vast amounts of solar heat from the equator to higher latitudes. Cold currents flow in the opposite direction on the eastern sides. Ocean currents thus act like a giant thermostat, warming the poles, cooling the tropics, and regulating the climate of our planet