Kinetics Flashcards
what is collision theory?
a reaction will occur when collisions between particles have sufficient energy
what is another term for sufficient energy?
activation energy - minimum amount of energy required for a reaction to take place
what is collision energy?
the energy of a particle when it collides
what is collision frequency?
number of collisions per unit time
what is rate of reaction?
time
what is the maxwell-boltzmann distribution?
theoretical model which plots number of molecules against kinetic energy
what is the effect of temperature on rate of reaction -
- increased kinetic energy
- more collisions
- more successful collisions
- higher rate of reaction
how would effect of temperature on rate of reaction be represented on maxwell-distribution graph?
why does small increase in temperature lead to large increase in rate?
- peak of curve lower and moves to right
- numberparticles have higher energy increases
- many more particles have energy higher than activation energy
- more kinetic energy
- more likely chance of successful collisions
- higher rate
what is the effect of concentration on rate of reaction?
- more particles in given volume
- more frequent collisions
- more successful collisions
- higher rate of reaction
what is a catalyst?
a substance that increases rate of reaction without being chemically unchanged
how does a catalyst work?
provides an alternative pathway of lowering activation energy