Kinetics Flashcards

1
Q

What is the rate of reaction

A

The change of concentration of a reactant or product with respect to time

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2
Q

What is the order of reaction with respect to a reactant

A

The power to which the reactant is raised to in the rate equation

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3
Q

What is the overall order of reaction

A

The sun of the powers to which the concentration terms are raised to in the rate equation

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4
Q

What is the rate constant

A

The proportionality constant which links the rate of the reaction to the concentrations in the rate equation

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5
Q

What is the rate determining step

A

The slowest step in the mechanism of a reaction

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6
Q

What can increase the rate of a reaction

A

Increase temp = Increase rate
Increase surface area = Increase rate (solid)
Increase concentration = Increase rate (liquid)
Increase pressure = Increase rate (gases)
Introduce catalyst = Increase rate

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7
Q

What is a homogeneous catalyst

A

Catalyst in the same physical state as reactants

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8
Q

What is a heterogenous catalyst

A

Reactants and catalyst in different physical state

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9
Q

What are the four experimental methods for determining rate

A

Titration
Colorimeter
Gas volume
Conductivity

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10
Q

What allows for titration to be used to find rate

A

If one of the reactants is I2, Fe2+,H2O2 or an acid/base

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11
Q

How would you preform a titration to find the rate

A

A sample would be taken at set time intervals and the reactions stopped by quenching and then the sample would be titrated with a suitable standard solution and indicator.

Then a concentration against time graph would be plotted and a tangent drawn

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