kinetics Flashcards
straight line going downwards
if a straight line is obtained, the reaction is zero order with respect to [A]
curve
if a curve is obtained, determine the half lives to check if the reaction is first order
- if half lives are (approximately) constant, the reaction is first order with respect to [A]
effect of catalyst on rate of reaction
-providing an alternative reaction mechanism of lower activation energy
-number of particles having kinetic energy ≥ Ea’ increases
-catalyst is regenerated
-frequency of effective collisions between particles increases. rate of reaction increases
effect of temperature on rate of reaction
- when temperature increases, the molecules increase in kinetic energy
- the number of molecules with kinetic energy ≥ activation energy Ea
- frequency of effective collisions between particles increases and hence the reaction rate increases
order of reaction
half life definition
half life is the time taken for the original concentration ( or amount) of a reactant to be halved