Kinetics Flashcards
1
Q
Reaction rate ___ as the reactions proceeds
A
Decreases
2
Q
Rate Law
A
Rate = k[A]^n[B]^m
3
Q
The __ of reactions orders (exponents) is the ___ order of the reaction
A
Sum
Overall
4
Q
[A]f
A
Zero order
5
Q
ln[A]f
A
First order
6
Q
1/[A]f
A
Second order
7
Q
t(1/2)
A
.693/k
8
Q
Activation Energy
A
Difference in energy between the activated complex and reactants
9
Q
As the temperature of a reaction goes up, the overall fraction of particles with enough energy to overcome Ea ___
A
Goes up
10
Q
Relationship between the rate constant and temperature
A
K=Ae^(-Ea/RT)
11
Q
Arrhenius Two Point Form
A
ln(k2/k1)=(-Ea/R)(1/T2 - 1/T1)
12
Q
Intermediate
A
Formed then consumed
13
Q
“Valleys” in multi step reactions
A
Intermediates
14
Q
“Peaks” in multi step reactions
A
Transition states
15
Q
Overall rate is the ___ step in a multi step reaction
A
Slowest
