kinetics Flashcards

1
Q

What must particles collide with for a reaction to occur?

A
  • sufficient energy to overcome the activation energy

- correct orientation (Stenc effect)

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2
Q

What are the 5 ways of increasing the rate of reaction?

A
  • temperature (increases kinetic energy of molecules)
  • pressure (increases number of gaseous molecules in a given volume)
  • concentration (increases the number of molecules in a given volume)
  • surface area (increases the area over which a reaction can occur)
  • catalyst (lowers the activation energy by providing an alternate pathway for a reaction)
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3
Q

What does the area under the maxwell boltzmann distribution represent?

A

total number of particles

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4
Q

What does the area to the right of activation energy in the maxwell boltzmann distribution represent?

A

corresponds to number of molecules with sufficient energy to overcome energy barrier + react

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5
Q

Why does the curve start at origin?

A

no particles have 0 energy

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6
Q

What is greater average energy or most probable?

A

average energy is slightly grater than most probable energy

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7
Q

What happens to the Maxwell Boltzmann distribution if temperature is increased?

A
  • area under the curve stays the same
  • curve gets broader and flatter due to a greater spread of values
  • shifts to higher energies/velocities
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8
Q

What happens to the Maxwell Boltzmann distribution if temperature is decreased?

A
  • area under the curve stays the same
  • curve gets narrower/more pointed due to smaller spread of values
  • shifts to lower energies/velocities
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9
Q

What happens to the Maxwell Boltzmann distribution if a catalyst is added?

A

lowers the activation energy by providing an alternative pathway for a reaction

lowering the activation energy results in more energy under the graph after Ea because more molecules have enough energy to react

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10
Q

What is an advantage of catalysts?

A

cheaper to speed up a reaction using a catalyst rather than higher temperature or pressure because reactions take place at lower temperatures which save energy and reduce CO2 output

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11
Q

What are the features of catalysts?

A

not used up in the reaction

remain chemically unchanged after a reaction has taken place

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