KEY TERMS Flashcards

1
Q

acid dissociation constant

A

the equilibrium constant that shows the extent of dissociation of a weak acid

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2
Q

acid-base pair

A

a pair of two species that transform into each other by gain to loss of a proton

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3
Q

activation energy

A

the minimum energy required to start a reaction by the breaking of bonds

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4
Q

alicyclic

A

containing carbon atoms joined by a ring that is not aromatic

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5
Q

aliphatic

A

containing carbon atoms joined in straight or branched chains

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6
Q

alkali

A

a type of base that dissolves in water forming hydroxide ions

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7
Q

acid

A

a species that releases H+ ions in aqueous solution

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8
Q

alkyl group

A

a side chain formed by removing a hydrogen atom from an alkane parent chain

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9
Q

aromatic

A

containing one or more benzene rings

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10
Q

atomic number

A

the number of protons in the nucleus of an atom

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11
Q

atomic orbital

A

the region around the nucleus that can hold up to 2 elections with opposite spins

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12
Q

average bond enthalpy

A

the average enthalpy change that takes place when breaking by homiletic fission 1 mol of a given type of bond in the molecules of a gaseous species

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13
Q

Avogadro constant

A

the number of atoms per mole of the carbon-12 isotope (6.02 x 10^23)

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14
Q

base

A

a compound that neutralises an acid to form a salt

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15
Q

binary compound

A

a compound containing 2 elements

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16
Q

bond dissociation enthalpy

A

the enthalpy change when 1 mol of a given bond in the molecules of a gaseous species is broken by homiletic fission

17
Q

carbocation

A

an ion that contains a positively charged carbon ion

18
Q

chain reaction

A

a reaction in which the propogation steps release new radicals which continue the reaction

19
Q

chiral carbon

A

a carbon atom attached to 4 different atoms or groups of atom

20
Q

cis-trans isomerism

A

type of E/Z isomerism where there are 2 non-hydrogen groups and 2 hydrogen groups around a C-C double bond

21
Q

cis isomer (Z)

A

H atoms on each carbon on the same side

22
Q

trans isomer (E)

A

H atoms on each carbon on different sides

23
Q

collision theory

A

2 particles must collide for a reaction to occur - correct orientation and have sufficient energy to overcome activation energy for the reaction

24
Q

complex ion

A

a transition metal ion bonded to ligands by coordinate bonds (dative covalent bonds)

25
Q

conjugate acid

A

a species that releases a proton to form a conjugate base

26
Q

conjugate base

A

a species that accepts a proton to form a conjugate acid

27
Q

coordinate bond (dative covalent bond)

A

shared pair of electrons in which the bonded pair has been provided by one of the bonding atoms only

28
Q

coordination number

A

total number or coordinate bonds formed between a central metal ion and ligands

29
Q

covalent bond

A

strong electrostatic attraction between a shared pair of electrons and the nuke of the bonded atoms