key definitions Flashcards

Terms from specification must learn (42 cards)

1
Q

EL Fusion reaction

A

lighter nuclei join to heavier nuclei under conditions of high temperature and pressure

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2
Q

EL ionisation enthalpy

A

the amount of energy required to remove mole of e- from one mole of gaseous atoms

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3
Q

EL charge density

A

a measure of the concentration of charge on a cation (the smaller the 2+ ion the higher the charge density)

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4
Q

EL acid

A

the ability to transfer H+ ions to something else (proton donor)

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5
Q

EL base

A

substance that accepts the H+ (proton acceptor)

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6
Q

EL alkali

A

soluble base substance.

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7
Q

EL neutralisation

A

chemical reaction between an acid and a base to form a salt and water. The reaction results in a neutral solution, meaning that the concentration of hydrogen ions (H+) and hydroxide ions (OH-) is equal, leading to a pH of 7.

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8
Q

DF exothermic

A

bonds formed [MAKING] are stronger than bonds broken

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9
Q

DF endothermic

A

bonds formed are weaker than bonds broken [BREAKING]

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10
Q

DF enthalpy change of reaction

A

Enthalpy change of reaction is the heat change accompanying a chemical reaction at constant volume or constant pressure. It represents the amount of heat absorbed or evolved during the reaction and is denoted by ΔH.

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11
Q

DF enthalpy change of formation

A

one mole of a compound is formed from its constituent elements in their standard state

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12
Q

DF enthalpy change of combustion

A

for one mole of a substance reacting completely with oxygen under standard conditions ( 1 atm and 298k)

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13
Q

DF enthalpy change of neutralisation

A

when one mole of hydrogen ions react with one mole of hydroxide ions to form one mole of water under standard conditions

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14
Q

DF average bond enthalpy

A

the energy required to break a particular COVALENT bond in one mole of a molecule in the GASEOUS state.

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15
Q

DF catalyst

A

a substance which speeds up the rate of reaction but can be recovered chemically unchanged at the end, by providing an alternative pathway

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16
Q

DF Catalysis

A

the process of speeding up a chemical reaction by using a catalyst

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17
Q

DF catalyst poison

A

a substance that stops catalyst functioning properly

18
Q

DF heterogenous catalyst

A

catalyst and reactants in different physical states

19
Q

DF homogenous catalysts

A

catalysts and reactants are in the same physical state

20
Q

DF cracking

A

the breakdown of long chained saturated hydrocarbons to form a mixture of shorter chained alkanes and alkenes

21
Q

DF radical

A

atoms of molecules which have an unpaired e-

22
Q

DF aliphatic

A

hydrocarbons with a carbon atom joined together by straight/ branched chains WITHOUT containing benzene rings

23
Q

DF aromatic

A

compound that contains one or more benzene rings

24
Q

DF arene

25
DF saturated
hydrocarbon with single bonds only eg c-c propane
26
DF unsaturated
hydrocarbon containing carbon to carbon double bonds eg ethene c=c
27
DF functional group
the part of the organic molecule responsible for its chemical properties, molecules in this group react in a similar way eg COOH or OH
28
DF homologous series
a family of compounds with the same functional group, with similar chemical properties
29
DF addition reaction
two or more molecules react to form a single larger molecule
30
DF fractional distillation
the separation of components in a liquid mixture into fractions which differ in boiling point by means of distillation typically using a fractionating column
31
DF fractional distillation
separation by differences in boiling point
32
DF electrophile
a positive ion or a molecule with a partial positive charge, that will be attracted to a negatively charged region and react by accepting a lone pair of e- to form a covalent bond
33
DF carbocation
an ion with a positively charged carbon atom
34
ES Dynamic equilibrium
when the forward and back ward reaction are happening at the same rate in a closed system the concentration of reactants and products remain unchanged
35
ES Le Ch ateliers priceable
when a system is in dynamic equilibrium is subjected to change the position of equilibrium will shift to minimise change
36
OZ electronegativity
measure of the attraction of a bonded atom for the pair of bonded e- in a covalent bond
37
OZ activation enthalpy
minimum energy required for reactant particles to successfully collide and form products in a chemical reaction.
38
OZ substitution
a reaction in which one group on a molecule is replaced by another atom or group
39
OZ nucleophile
a molecule or negatively charged ion with a lone pair of e- that it can donate to a positively charged atom to form a covalent bond
40
OZ homolytic bond fission
when the covalent bond breaks evenly, and each of the bonded atoms takes one of the shared pair of electrons from the bond. Each atom now has a single unpaired electron - called a radical.
41
OZ heterolytic bond fission
the breaking of a bond whereby the covalently bonded pair of e- are taken by one of the atoms in the covalent bond
42
OZ Boltzmann distribution
the amount of energy contained by particles in a closed system as a distribution at a given temperature