Key Concepts of Chemistry Flashcards

1
Q

What was John Dalton’s theory (1803)?

A

He published his own three-part atomic theory:
1. All substances are made of atoms. Atoms are small particles that cannot be created, divided, or destroyed.
2. Atoms of the same element are exactly alike, and atoms of different elements are different.
3. Atoms join with other atoms to make new substances.
Much of Dalton’s theory was correct, but some of it was later proven incorrect and revised as scientists learned more about atoms.

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2
Q

What was J.J Thomson’s model (1897)?

A

Used a cathode-ray tube to conduct an experiment
This discovery identified an error in Dalton’s atomic theory. Atoms can be divided into smaller parts.
Because the beam moved away from the negatively charged plate and toward the positively charged plate, Thomson knew that the particles must have a negative charge.
Thomson proposed a model of an atom called the “plum-pudding” model, in which negative electrons are scattered throughout soft blobs of positively charged material.

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3
Q

What was Ernest Rutherford’s model (1909) ?

A

Rutherford developed a new model which said that most of the atom’s mass is found in a region in the centre called the nucleus.
In Rutherford’s model the atom is mostly empty space, and the electrons travel in random paths around the nucleus.

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4
Q

What was Ernest Rutherford’s experiment?

A

He shot a beam of positively charged particles into a sheet of gold foil.
Most of the particles did continue in a straight line (as you would expect from plum pudding model). However, some of the particles were deflected to the sides a bit, and a few bounced straight back.

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5
Q

What is the relative charge and relative mass of protons, neutrons and electrons?

A

Particle: Relative Charge: Relative Mass
Protons: +1: 1
Neutrons: 0: 1
Electrons: -1: 1/1836

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6
Q

Why do atoms contain equal number of protons and electrons?

A

Atoms are neutral and the charges on a proton are +1 and on an electron are -1, therefore amount of protons = amount of electrons, so that the charges cancel.

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7
Q

Describe the term “isotope”

A

Atoms of the same element that have the same number of protons but different number of neutrons.

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8
Q

How did Mendeleev arrange the elements, known at that time, in the periodic table?

A

He ordered his table in order of atomic mass, and left gaps for elements that he thought had not been discovered yet.

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9
Q

How did Mendeleev use his table to predict the existence and properties of some elements not then discovered?

A

Mendeleev realised elements with similar properties belonged in the same groups in the periodic table and so was able to leave gaps and place the discovered elements where they fit best. Elements with properties predicted by Mendeleev were later discovered and filled the gap.

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10
Q

What is the meaning of atomic number of an element in terms of position in the periodic table and number of protons in the nucleus?

A

Elements are arranged in order of atomic (proton) number (bottom number) and so that elements with similar properties are in columns, known as groups.
Elements in the same group have the same amount of electrons in their outer shell, which gives them similar chemical properties.

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11
Q

What does the endings –ide and –ate in the names of compounds mean?

A

These endings are used for the negatively charged ions in a compound.
-ide means the compound contains 2 elements.
-ate means the compound contains at least 3 elements, one of which is oxygen

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12
Q

Describe the term “ionic bonding”

A

Transfer of electrons between a metal and non-metal.

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13
Q

Why do ionic compounds have a high melting point?

A

They have a lattice held together by strong electrostatic forces of attraction between oppositely charged ions. Therefore, lots of energy is needed to break these bonds.

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14
Q

Can ionic compounds conduct electricity?

A

Ionic compounds can conduct electricity when molten or in solution, but not as solids as ions aren’t free to move.

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15
Q

Describe the term “covalent bonding”

A

A sharing of a pair of electrons between non metals.

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16
Q

Do covalent compounds have a high melting point?

A

Covalent/Giant Covalent: Strong covalent bonds which requires a lot of energy to break them and therefore having a very high melting point.
Simple Covalent: Intermolecular forces are weak between the molecules and little energy is needed to overcome these forces and so therefore having a low melting point.

17
Q

Can covalent compounds conduct electricity?

A

Both: Poor electrical conductivity as this structure is not usually charged and so no free electrons can carry electrical current.

18
Q

Do metals have a high melting point?

A

High melting point as the lattice is held together by strong electrostatic forces of attraction between positively charged ions and delocalised electrons and therefore requires a lot of energy to break these bonds.

19
Q

Can metals conduct electricity?

A

Electrons are delocalised, free to move and can transfer an electrical current easily. Therefore, it has excellent conductivity.

20
Q

Why are metals malleable?

A

The layers of atoms in metals can slide over each other, so metals can be bent and shaped.

21
Q

Why does diamond not conduct electricity?

A

In diamond (right), each carbon is joined to 4 other carbons covalently.

22
Q

What are some diamond uses? (1)

A

Cutting tools – very hard, due to its rigid structure.

23
Q

Why is graphite soft and slippery?

A

In graphite, each carbon is covalently bonded to 3 other carbons, forming layers of hexagonal rings, which have no covalent bonds between the layers. The layers can slide over each other due to no covalent bonds between the layers, but weak intermolecular forces.
Meaning that graphite is soft and slippery.

24
Q

Why can graphite conduct electricity?

A

One electron from each carbon atom is delocalised. This makes graphite like metals, because of its delocalised electrons. It can conduct electricity – unlike diamond.

25
Q

What are some graphite uses? (2)

A
  1. Electrodes – graphite can conduct electricity – unlike Diamond.
  2. Lubricant – weak intermolecular forces and no covalent bonds between the layers, therefore it is soft and slippery.
26
Q

Does graphene have a high melting point?

A

Does graphene have a high melting point?

27
Q

Can graphene conduct electricity?

A

It has one free electron and so graphene has delocalised electrons and so conducts electricity.

28
Q

Does fullerene have a high melting point?

A

They have weak intermolecular forces so require little energy to break them meaning they have a low melting point.

29
Q

Can fullerene conduct electricity?

A

Fullerene only conducts electricity across the surface of the molecule and as there is little movement of electrons between molecules, fullerene is a poor conductor of electricity.

30
Q

What are carbon nanotubes?

A

Cylindrical fullerenes with very high length to diameter ratios.

31
Q

How does the bonding and structure of carbon nanotubes link to its properties?

A

Their properties make them useful for nanotechnology, electronics and materials. Examples of uses as lubricants, to deliver drugs in the body and catalysts. Nanotubes can be used for reinforcing materials, for example tennis rackets.

32
Q

What is the law of conservation of mass?

A

No atoms are lost or made during a chemical reaction so the mass of the products = mass of the reactants.

33
Q

How does the law of conservation of mass apply to a closed system - a precipitation reaction in a closed flask?

A

With a precipitation reaction – precipitate that forms is insoluble and is a solid, as all the reactants and products remain in the sealed reaction container then it is easy to show that the total mass is unchanged.

34
Q

How does the law of conservation of mass apply to an enclosed system - a reaction in an open flask that takes in or gives out a gas?

A

Does not hold for a reaction in an open flask that takes in or gives out a gas, since mass will change from what it was at the start of the reaction as some mass is lost when the gas is given off.

35
Q

Explain why, in a reaction, the mass of product formed is controlled by the mass of the reactant which is not in excess? (2)

A
  1. In a chemical reaction with 2 or more reactants, you will often use one in excess to ensure that all the other reactant is used. The reactant that is used up / not in excess is called the limiting reactant since it limits the amount of products.
  2. If a limiting reagent is used, the amount reactant in excess that reacts is limited to the exact amount that reacts with the amount of limiting reagent you have, so you need to use the moles/mass of the limiting reagent for any calculations.